Results 131 to 140 of about 9,364,265 (259)

Protein‐Nanoarchitectures for Low‐Field Intracellular Electro‐Immunomodulation

open access: yesAdvanced Functional Materials, EarlyView.
DHQ‐SDH‐mediated binding of AuNPs drives the formation of interconnected, chain‐like nanoarchitectures with enhanced electrical conductivity. These conductive assemblies undergo macrophage uptake and enable low‐field electrical stimulation, promoting M1‐to‐M2 phenotypic switching with decreased iNOS and increased CD206 expression. Such protein‐mediated
Viktoriya Pakharenko   +7 more
wiley   +1 more source

Design strategies for optimized molecular p-dopants: decoupling electronic and geometric effects

open access: yesJPhys Materials
The design of efficient molecular p-dopants for organic semiconductors relies on maximizing their electron affinity to generate holes in the semiconductor host. The formation of ground-state charge transfer complexes, detrimental to the doping efficiency,
Melissa Berteau-Rainville   +4 more
doaj   +1 more source

Estudo teórico dos efeitos eletrônico e estérico da etapa de desidratação do norcanfor e norcanfor substituído [PDF]

open access: yes, 1998
Dissertação (Mestrado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e ...
Duvoisin Júnior, Sérgio
core  

Steric and Electronic Effects on Arylphosphonate Elimination from Organopalladium Complexes

open access: yes, 2016
To study the effects of electronic and steric manipulation of metal-bound aryl fragments on arylphosphonate formation, model organopalladium complexes have been prepared and investigated.
Mark C. Kohler (2178444)   +2 more
core   +1 more source

Nitride MXenes Beyond Carbides: Bridging the Gap Between Computational Prediction and Experimental Realization

open access: yesAdvanced Functional Materials, EarlyView.
Nitride MXenes remain constrained by a persistent gap between computational prediction and experimental realization. This Review identifies the thermodynamic, kinetic, and chemical barriers limiting their synthesis, critically evaluates emerging fabrication routes, and proposes a multidimensional computational‐experimental framework to accelerate the ...
Naresh Varnakavi, Masoud Soroush
wiley   +1 more source

Steric effects: The problem of their quantitative assessment and manifestation in the reactivity of hetero-organic compounds [PDF]

open access: yes, 1991
Literature data on the methods of quantitatively assessing steric effects and their manifestation in the reactivity of various organoelement compounds is systematised.
Galkin V., Cherkasov R., Sayakhov R.
core  

Structure‐Property Relationships in Catecholamine Coatings for Broad Surface Functionalization

open access: yesAdvanced Functional Materials, EarlyView.
Inspired by mussel adhesive proteins (MAPs), six catecholamine molecules with different molecular structure were systematically characterized and compared based on their ability to form homogeneous, reactive coatings. Highlighting candidates capable of balancing coating properties of interest, their successful use as primer layers for organic and ...
Caroline F. Harms   +5 more
wiley   +1 more source

Directed synthesis of N1/N3-histidine modified by 2-hydroxyethylthioethyl and identification in sulfur mustard-exposed plasma

open access: yesCommunications Chemistry
Sulfur mustard (HD) alkylates biomolecules such as proteins, generating specific biomarkers. This study employs steric hindrance, electronic effects, and solvent effects through an occupancy-removal strategy to synthesize regioisomers [N1-HETE]-His and ...
Long Wen   +8 more
doaj   +1 more source

Steric effects: The problem of their quantitative assessment and manifestation in the reactivity of hetero-organic compounds

open access: yes, 2020
Literature data on the methods of quantitatively assessing steric effects and their manifestation in the reactivity of various organoelement compounds is systematised.
Galkin V., Cherkasov R., Sayakhov R.
core  

Bioinspired Hydrogels with Broadly Programmable Mechanics for Soft‐Tissue Interfaces

open access: yesAdvanced Functional Materials, EarlyView.
Sea cucumber‐inspired gelatin hydrogels are formed by directional freezing and mechanically programmed through subsequent ionic treatment. Multiscale characterization and modeling link ion‐regulated chain interactions to directional load transfer within the aligned hierarchical architecture.
Youchao Teng   +20 more
wiley   +1 more source

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