Results 131 to 140 of about 127,504 (265)

Linker‐Engineered Dimeric Acceptors Afford Efficient Organic Photocatalytic Hydrogen Evolution via Tailored Nanomorphology for Long‐Lived Charge Accumulation

Advanced Materials, EarlyView.
We developed a new series of monomeric (MY) and dimeric acceptors incorporating unfused (DY1) and fused (DY2) linkers, which establish a controlled self‐aggregation trend of MY > DY2 > DY1. The DY2‐based system yields a bulk‐heterojunction nanoparticle morphology that appears to balance phase separation and interfacial accessibility, consistent with ...
Jin‐Woo Lee, Cheng Sun, Yang Song, Guanru Dong, Keren Ai, Stanley Alfred Cazaly, Flurin Eisner, Bumjoon J. Kim, Zeinab Hamid, Iain McCulloch, Yun‐Hi Kim, James R. Durrant   +11 more
wiley   +1 more source

London dispersion forces and steric effects within nanocomposites tune interaction energies and chain conformation. [PDF]

Commun Chem
Zhang B, Zarić SD, Zrilić SS, Gofman I, Heck B, Reiter G.   +5 more
europepmc   +1 more source

Steric Coordination Modulated Iodine Chemistry With Four‐Electron Conversion for Zinc‐Iodine Batteries

Advanced Materials, EarlyView.
A dual‐additive electrolyte strategy is developed to address the hydrolysis of I+ in the aqueous electrolytes. The steric‐hindrance effect of TES− effectively shields I+ from nucleophilic attacks by hydroxyl groups, facilitating the reversible I−/I0/I+ conversion with four‐electron transfer.
Shuai Wang, Haoran Wang, Yujue Yang, Yuanyuan Gao, Yaopeng Wu, Junze Zhang, Jingxin Zhao, Yuejiao Chen, Bingang Xu   +8 more
wiley   +1 more source

Oppositely Charged Single Enzyme Nanogels Form Versatile Coacervates for Efficient Enzyme Cascade Catalysis

Advanced Materials, EarlyView.
Oppositely charged single enzyme nanogels (SENs) phase‐separate into bi‐enzymatic coacervate microdroplets, acting as both scaffold and functional units. By tuning SEN ratios, these coacervates create specific microenvironments that enable selective small‐molecule enrichment and efficient intermediate diffusion.
Andoni Rodriguez‐Abetxuko, Nadia A. Erkamp, Neshat Moslehi, Yannick H. A. Leurs, Lars Paffen, Işil Yeşil Gür, Jana Stojanović, Hugo Brasselet, Laura van der Weel, Ulf Hanefeld, Ilja K. Voets, Jan C. M. van Hest   +11 more
wiley   +1 more source

Steric effects on the sydnones reactivity. New sydnones and pyrazoles

ARKIVOC, 2002
Florea Dumitrascu, Carmen Irena Mitan, Denisa Dumitrescu, Constantin Draghici, Miron Teodor Caproiu   +4 more
doaj   +1 more source

Molecular-Scale Visualization of Steric Effects of Ligand Binding to Reconstructed Au(111) Surfaces. [PDF]

J Am Chem Soc
Bi L, Jamnuch S, Chen A, Do A, Balto KP, Wang Z, Zhu Q, Wang Y, Zhang Y, Tao AR, Pascal TA, Figueroa JS, Li S.   +12 more
europepmc   +1 more source

Efficient Osmotic Energy Conversion Enabled by Self‐Standing COF Membranes With Varied Sulfonic Acid Group Density

Advanced Materials, EarlyView.
Self‐standing, strong sulfonated covalent organic framework membranes with varied ionic‐group density are developed for osmotic energy conversion. Optimized charge‐governed nanochannels enable highly selective ion transport, delivering a power density of 24.53 W m−2 under seawater/freshwater salinity gradients.
Xi Ma, Xiaoxiao Cheng, Tamara Fischer, Jürgen Senker, Qi Sun, Seema Agarwal   +5 more
wiley   +1 more source

Steric Effects on the Photovoltaic Performance of Panchromatic Ruthenium Sensitizers for Dye-Sensitized Solar Cells. [PDF]

ACS Appl Mater Interfaces
Chen CY, Lin TY, Chiu CF, Lee MM, Li WL, Chen MY, Hung TH, Zhang ZJ, Tsai HG, Sun SS, Wu CG.   +10 more
europepmc   +1 more source

Conductive Additives for Next‐Generation Batteries: Emphasizing the Potential of Bio‐Derived 3D Carbon Architectures at Electrode–Electrolyte Interfaces

Advanced Materials Interfaces, EarlyView.
3D conductive frameworks can maintain continuous electron transport, mechanical stability, and interfacial integrity, helping next‐generation batteries operate more efficiently. This Review examines their relevance to Si anodes, all‐solid‐state batteries, and dry‐processed electrodes, and highlights bio‐derived carbons as sustainable, structurally ...
SeoYoung Ha, Inseo Ko, Jongyoung Choi, Weon Ho Shin, Sung Cik Mun, Jong Ho Won   +5 more
wiley   +1 more source

Unraveling Meso-Substituent Steric Effects on the Mechanism of Hydrogen Evolution Reaction in Ni^II Porphyrin Hydrides Using DFT Method. [PDF]

Molecules
Li X, Feng A, Zu Y, Liu P.
europepmc   +1 more source