Advanced Materials, EarlyView.A “ship‐in‐a‐bottle” strategy is used to grow oligomers inside of a MOF by crosslinking alkylamines with epoxides within the pores of Cr‐BDC. When tested in postcombustion carbon capture applications, the composites show excellent performance with high CO2 adsorption capacity, exceptional CO2/N2 selectivity, and enhanced stability over 100 adsorption ...
Jordi Espín +7 more
wiley +1 more source
Advancing from MOFs and COFs to Functional Macroscopic Porous Constructs
Advanced Materials, EarlyView.This review study investigates the recent progress and methodologies for manufacturing metal–organic framework (MOF) or covalent–organic framework (COF)‐based 3D structured macroscopic porous constructs with high structural integrity, providing the possibility to control their porosity across dimensions.
Seyyed Alireza Hashemi +8 more
wiley +1 more source
Structural Control of Photoconductivity in a Flexible Titanium‐Organic Framework
Advanced Materials, EarlyView.The concept of flexibility is extended to titanium frameworks and use it to gain control over charge transport. MUV‐35 is a flexible doubly interpenetrated framework that can shrink spontaneously its volume by ≈40% to afford a photoconductive, porous state that is thermodynamically favored by non‐covalent interactions. Abstract The soft nature of Metal‐
Clara Chinchilla‐Garzón +6 more
wiley +1 more source
Unraveling Lewis base substitution in <i>ansa</i>-type frustrated Lewis pairs: how N → P replacement redefines adduct stability and H<sub>2</sub> activation. [PDF]
RSC AdvBarrales-Martínez C +3 more
europepmc +1 more source
Covalent Organic Frameworks for Photocatalysis
Advanced Materials, EarlyView.This review provides an overview of recent advances in covalent organic frameworks (COFs) for photocatalysis, focusing on sustainable energy applications like water splitting, hydrogen peroxide generation, and CO2 and N2 reduction. It discusses design principles, structure‐function relationships, challenges in COF photocatalysis, and strategies to ...
Bikash Mishra +6 more
wiley +1 more source
Structural effects of arsine ligands on C-H difunctionalization of thiophene. [PDF]
Chem SciSumida A +4 more
europepmc +1 more source
Supramolecular Chemistry in Metal–Organic Framework Materials
Advanced Materials, EarlyView.This review highlights synergies between reticular chemistry and supramolecular chemistry. The role of supramolecular interactions in determining framework…guest interactions and attempts to understand dynamic behavior in metal–organic frameworks (MOFs), particularly emphasizing the development of crystal sponges, studying reactions in frameworks and ...
Eugenia Miguel‐Casañ +3 more
wiley +1 more source
Correction: Electrochromic sensing platform based on steric hindrance effects for CEA detection
, 2016 Qingfeng Zhai +4 more
openalex +2 more sources
State‐of‐the‐Art, Insights, and Perspectives for MOFs‐Nanocomposites and MOF‐Derived (Nano)Materials
Advanced Materials, EarlyView.Different approaches to MOF‐NP composite formation, such as ship‐in‐a‐bottle, bottle‐around‐the‐ship and in situ one‐step synthesis, are used. Owing to synergistic effects, the advantageous features of the components of the composites are beneficially combined, and their individual drawbacks are mitigated.
Stefanos Mourdikoudis +6 more
wiley +1 more source
Macrocyclic NHC Ligands in Hoveyda-Type Ru Alkene Metathesis Catalysts: Only Sterics? [PDF]
Inorg ChemBrotons-Rufes A +3 more
europepmc +1 more source