Results 251 to 260 of about 11,627,235 (359)

Au(I)‐Catalyzed Regiodivergent Hydroarylation of Allenes for the Synthesis of Tetrahydrodiazepines or Tetrahydrodiazonines

Advanced Synthesis &Catalysis, EarlyView.
Abstract Allenes tethered to pyrroles undergo Au(I)‐catalyzed hydroarylation leading to tetrahydrodiazepines or tetrahydrodiazonines. The regioselectivity of the reaction is governed by both the substitution pattern of the allene and the nature of the Au(I) ligand. Hence, alkyl‐gem‐disubstituted allenes preferentially lead to tetrahydrodiazepines via 7‐
Pengyu Zhou, Pascal Retailleau, Vincent Gandon, Arnaud Voituriez, Xavier Guinchard   +4 more
wiley   +1 more source

Steric effects on excimer formation for photoluminescent smectic liquid-crystalline materials

, 2013
Shogo Yamane, Yoshimitsu Sagara, Takashi Kato   +2 more
openalex   +2 more sources

Synthesis of Unnatural Amino Acids via β‐Aminoaldehyde C–H Arylation using HAT‐Metallaphotoredox Catalysis

Advanced Synthesis &Catalysis, EarlyView.
Abstract Unnatural amino acids play a crucial role in advancing protein engineering and drug development. In this study, we present the synthesis of a series of γ‐aryl‐keto‐α‐amino acids through the direct C−H arylation of readily accessible β‐aminoaldehydes and aryl bromides, promoted by hydrogen atom transfer combined with metallaphotoredox catalysis.
Mariana dos S. Dupim, Bruno M. da S. Santos, Lívia C. R. M. da Frota, Fernanda G. Finelli   +3 more
wiley   +1 more source

Photoinduced Catalytic Alkylation of Active Methine Compounds with Nonactivated Alkenes Using Yttrium Triflate as a Lewis Acid Catalyst

Advanced Synthesis &Catalysis, EarlyView.
Abstract Photoinduced catalytic alkylation reactions of active methine compounds with nonactivated alkenes have been developed using an organophotocatalyst, a metal Lewis acid, an arylthiol, and an amine base catalyst system. The alkylation reactions proceeded smoothly under ambient conditions with blue light irradiation, affording the desired products
Yasuhiro Yamashita, Rentaro Enokijima, Yoshihiro Ogasawara, Tomoya Hisada, Shū Kobayashi   +4 more
wiley   +1 more source

Double‐Sided Control of Product Type Preference in the Visible‐Light Initiated Reaction of 1,3‐Dicarbonyl Compounds with Alkenes

Advanced Synthesis &Catalysis, EarlyView.
Abstract The demonstrated light‐initiated addition of radicals formed on an active methylene group to styrene derivatives exhibits a product selectivity influenced by the presence of a protic solvent. Under protic conditions, the predominant products are branched compounds with the alkene moiety attached to the methylene group.
Małgorzata Pałyga, Jan Rzepiela, Sebastian Baś   +2 more
wiley   +1 more source

Theoretical Investigation of Steric and Electronic Effects of meso-Phenyl on Co-Porphyrin Catalyzed Activation of Dioxygen

, 2014
Nian Liu, Wei Deng, Guo‐Fang Jiang, Can‐Cheng Guo   +3 more
openalex   +1 more source

Tunable Preparation of β‐Substituted Alkenoate Esters via Radical Alkenylation of C(sp3)–H Bonds with Allenoates

Advanced Synthesis &Catalysis, EarlyView.
Abstract A photocatalytic strategy for the radical alkenylation of aliphatic C(sp3)–H bonds with 2,3‐allenoate esters is described. The protocol takes place upon irradiation of the reaction mixture in the presence of the decatungstate anion, which triggers C−H cleavage in the chosen aliphatic substrates.
Alexandra Jorea, Roberto Chessa, Davide Ravelli   +2 more
wiley   +1 more source

Heterogeneously Catalyzed Cascade Oxidative Coupling/Dearomative Spirocyclization of Diarylamines: Facile Access to Spiroacridines

Advanced Synthesis &Catalysis, EarlyView.
Abstract Spirocyclic compounds, particularly spirocyclohexadienones, are important in pharmaceuticals due to their biological activity. In this study, we develop a catalytic cascade oxidative spirocyclization of diarylamines for the rapid access to highly functionalized spirocyclohexadienones. Using commercially available recyclable heterogeneous metal
Kenji Matsumoto, Naho Sato, Yoshinori Kobayashi, Kanako Date, Yasuko Okamoto, Touya Kariya, Tsukasa Hirokane, Masahiro Yoshida   +7 more
wiley   +1 more source

Chitosan, Gelatine, and Cellulose Based Hydrogels for the Removal of Potentially Toxic Elements from Aquaculture Water: A Comparative Study

Advanced Sustainable Systems, EarlyView.
Hydrogels made of chemically modified biopolymers are easy to prepare and cost‐effective, they have proven to be effective materials for the simultaneous removal of seven potentially toxic elements (PTEs) from ultrapure and real water samples. The cellulose‐based one seems the best for single treatments while the gelatine‐based one seems the most ...
Monica Rigoletto, Rossella Sesia, Silvia Berto, Paola Calza, Marco Sangermano, Enzo Laurenti, Mery Malandrino   +6 more
wiley   +1 more source

Insights into the Dynamics and Binding Mechanisms of the Alkhumra Virus NS2B/NS3 Protease: A Molecular Dynamics Study

Advanced Theory and Simulations, EarlyView.
The ΔRMSF$\Delta {\rm RMSF}$ analysis reveals significant flexibility differences between free NS3 and the NS2B/NS3 complex, with notable deviations in specific regions. Key residues driving NS2B binding are identified, and the protonation state of catalytic serine affects oxyanion hole formation.
Jurica Novak, Shivananda Kandagalla, Ramesh Sistla   +2 more
wiley   +1 more source