Results 61 to 70 of about 44,548 (215)
Coherent photodissociation reactions: Observation by a novel picosecond polarization technique [PDF]
In this communication, we wish to report on a novel picosecond polarization method for measuring the degree of rotational coherence that is preserved in photodissociation reactions.
Baskin, J. S., Semmes, D., Zewail, A. H.
core +1 more source
In situ phenoxide formation at the benzene terminus triggers room‐temperature conversion of thia[6]helicene S,S‐dioxides to coronene. The solubility contrast drives product precipitation, enabling isolation by simple filtration. This pericyclic annulation between the helical termini provides direct access to coronene‐type planar architectures ...
Kaito Seino, Takashi Murase
wiley +1 more source
Picosecond-jet spectroscopy and photochemistry. Energy redistribution and its impact on coherence, isomerization, dissociation and solvation [PDF]
The development of the picosecond-jet technique is presented. The applications of the technique to the studies of coherence (quantum beats), photodissociation, isomerization and partial solvation of molecules in supersonic-jet beams are detailed with ...
Zewail, Ahmed H.
core
Theory of nonlinear optical properties of phenyl-substituted polyacetylenes
In this paper we present a theoretical study of the third-order nonlinear optical properties of poly(diphenyl)polyacetylene (PDPA) pertaining to the third-harmonic-generation (THG) process.
A. Chakrabarti +25 more
core +1 more source
Metal-free syn-dioxygenation of alkenes [PDF]
Reactions employing inexpensive reagents from sustainable sources and with low toxicity are becoming increasingly desirable from an academic and industrial perspective.
Ashikari +60 more
core +1 more source
Energy Landscapes in Chemical Reactions and Transport
Kinetics/dynamics of chemical reactivity and transport of chemical species in a solid are both determined by the energy landscape in which they take place. Discussing common grounds but also distinct differences may help in advancing the understanding in both fields.
Karl‐Michael Weitzel
wiley +1 more source
By imitating the scaffold of lithocholic acid (LCA), a natural steroidal compound displaying Protein Tyrosine Phosphatase 1B (PTP1B) inhibitory activity, a series of stilbene derivatives containing phenyl-substituted isoxazoles were designed and ...
Haibing He +6 more
doaj +1 more source
A Practical Synthesis of Bridged Diarylacetylenes [PDF]
An efficient and practical synthesis of bridged diarylacetylenes in multigram quantities has been successfully carried out using high-yielding (classical) synthetic methods and readily available starting materials.
Brody, Daniel M. +3 more
core +1 more source
The expression of stlA in Photorhabdus luminescens is controlled by nutrient limitation [PDF]
Photorhabdus is a genus of Gram-negative entomopathogenic bacteria that also maintain a mutualistic association with nematodes from the family Heterorhabditis.
Bode, Helge Björn +3 more
core +3 more sources
Recent Developments in the Field of Air‐Stable Nickel(0) Precatalysts for Cross‐Coupling Reactions
The development of bench‐stable Ni(0) sources aims to replace air‐sensitive [Ni(COD)2] (cod = cycloocta‐1,5‐diene) with easy‐to‐handle alternatives. Through a targeted ligand design, using electron‐deficient dienes, carbenes, and fluorophosphines, researchers have achieved air‐ and moisture‐tolerant complexes that show high catalytic activity in cross ...
Franziska Flecken, Schirin Hanf
wiley +1 more source

