Results 211 to 220 of about 8,590,019 (336)

π‐Extended Salphen Scaffolds Enable CO2 Electroreduction and Singlet Oxygen Generation

Chemistry – A European Journal, EarlyView.
New family of π‐extended salen ligands bearing phenylene bridge and tunable phenyl‐based substituents, and their corresponding boron difluoride complexes. Thanks to the extended π‐delocalization over the molecule, the ligands themselves show promising results in electrochemical CO2 reduction to CO, while the complexes act as efficient photosensitizers ...
Vincenzo Langellotti, André Korzun, Morgan J. McKee, Massimo Melchiorre, Taegeun Jo, J. Felipe Estrada‐Ruiz, Gregor Schnakenburg, Stefano Crespi, Francesco Ruffo, Nikolay Kornienko, Alessandro Bismuto   +10 more
wiley   +1 more source

New Insights into Poly(Dichlorophosphazene) Synthesis via Me3Si─N═PCl3 Polymerization: An Experimental and Theoretical Study

Chemistry – A European Journal, EarlyView.
Poly(dichlorophosphazene) synthesis via Me3Si─N═PCl3 polymerization was reinvestigated using quantum chemical calculations and experiments. A cationic initiator (Ph3PCl2) enables ambient‐temperature polymerization through chloride‐catalyzed cationic pathways involving dissociation, nucleophilic chloride attack, and chain‐propagating species formation ...
Cornelius Knuth, Paul Strasser, Carmen Hoth, Joerg Harloff, Thomas Eickner, Ian Teasdale, Axel Schulz   +6 more
wiley   +1 more source

Finite Time Blow-Up for the Hypodissipative Navier Stokes Equations with a Force in L t 1 C x 1 , ϵ ∩ L t ∞ L x 2 . [PDF]

Arch Ration Mech Anal
Córdoba D, Martínez-Zoroa L, Zheng F.
europepmc   +1 more source

Substituent‐Dependent SERS Kinetics of Citrate‐Stabilized Gold Nanoparticles: Balancing Hotspot Formation and Colloidal Flocculation

Chemistry – A European Journal, EarlyView.
Reporter chemistry controls the operational window of liquid‐phase SERS. Para‐substituted benzenethiols induce distinct AuNPs colloidal regimes, ranging from delayed but stable hotspot formation to rapid flocculation‐dominated signal decay. The balance between SERS‐active‐state formation and colloidal loss defines whether a reporter provides reliable ...
Irene Calderon Gonzalez, Miguel A. Correa Duarte, Ramon A. Alvarez‐Puebla   +2 more
wiley   +1 more source

Solvatoalignment index and solvent-dependent behavior of asymmetric discotic liquid crystals: effect of polarity and alkyl chain length. [PDF]

Sci Rep
Kian R, Ranjkesh A, Taheri B, Varshney SK, Ebrahimpour N, Zakerhamidi MS.   +5 more
europepmc   +1 more source

Benzo[c][1,2,5]Thiadiazole Linkers Enhance the Effectiveness of Cavity‐Containing Supramolecular Photocatalysts

Chemistry – A European Journal, EarlyView.
Seven novel supramolecular photosensitizers based on benzo[c][1,2,5]thiadiazole (BTZ) tethered to calix[4]arene (C[4]) scaffolds are reported with facile, scalable, and selective syntheses. Their abilities to produce singlet oxygen have been tested through the photo‐oxidation of α‐terpinene.
Leonardo Amicosante, Dominic Taylor, Cameron L. Campbell, Daniel M. Lambden, Georgina M. Rosair, Filipe Vilela, Scott J. Dalgarno   +6 more
wiley   +1 more source

Ultrastructural analysis of human uncinate fasciculus with coherent anti-Stokes Raman spectroscopy. [PDF]

Biophotonics Discov
Perlman K, Noël VP, Collin A, Major J, Mardenli M, Jerczynski S, Davoli MA, Cohen-Adad J, Côté D, Mechawar N.   +9 more
europepmc   +1 more source

Bis(2‐Adamantyl)Magnesium: Synthesis, Structure, and Applications of a Versatile and Shelf‐Stable 2‐Adamantyl Anion Equivalent

Chemistry – A European Journal, EarlyView.
At last, the long‐sought bis(2‐adamantyl)magnesium reagent has been prepared in high yield as a stable tetrahydrofuran/dioxane adduct and fully characterized by x‐ray crystallography. This potent nucleophile outperforms the corresponding Grignard in transmetallation and carbonyl addition reactions, opening new avenues in adamantyl organometallic and ...
Matthew V. DaCosta, Fioralba Taullaj, Jack H. Lin, Ulrich Fekl   +3 more
wiley   +1 more source

Solvent-induced photophysical properties and stability of clonazepam and Chlordiazepoxide. [PDF]

Sci Rep
Kian R, Zakerhamidi MS, Merajin ZA.
europepmc   +1 more source

Accurate Molecular Size Determination by Diffusion Ordered NMR Spectroscopy Based on an Improved Diffusion Model

Chemistry – A European Journal, EarlyView.
A semi‐empirical Stokes‐Einstein‐based model for describing the diffusion of organic, organometallic and coordination compounds is developed for the interpretation of diffusion constants obtained by diffusion‐ordered NMR spectroscopy (DOSY). This model uses the molecular volume as a descriptor and shows a high accuracy, enabling application to ...
Christian Urbank, Lisa Vondung
wiley   +1 more source