Results 1 to 10 of about 10,794,162 (307)

Discrete mathematical structures in the analysis and synthesis of passive and active vibration isolating devices

open access: yesTrudy Odesskogo Politehničeskogo Universiteta, 2023
The article deals with discrete mathematical structures used for the analysis and synthesis of passive and active vibration isolation devices. It is shown that approaches of discrete mathematics in the form of kinematic graphs and their further ...
Любов Віталіївна Бовнегра   +4 more
doaj   +5 more sources

Automatic Structural Synthesis of Planetary Geared Mechanisms ‎using Graph Theory [PDF]

open access: yesJournal of Applied and Computational Mechanics, 2023
Graphs are an effective tool for planetary gear trains (PGTs) synthesis and for the enumeration of all possible PGTs for transmission systems. In the past fifty years, considerable effort has been devoted to the synthesis of PGTs.
Hind A. Nafeh   +2 more
doaj   +1 more source

Low heat generation from organic zinc as a curing activator in rubber and rubber composites under large strain

open access: yesNano Select, 2022
ZnO is a conventional activator in sulfur curing systems, but its excessive release can cause adverse effects to the human body and the environment. Using organic zinc instead of zinc oxide not only decreases the amount of zinc but also disperses the ...
Liming Wang   +5 more
doaj   +1 more source

Easy access to medium-sized lactones through metal carbene migratory insertion enabled 1,4-palladium shift

open access: yesNature Communications, 2020
Transannular construction of medium-sized lactones is entropically unfavoured. Herein, the authors describe a strategy for valuable medium-sized lactone synthesis from available benzaldehydes by selective C-H bond functionalization via palladium carbene ...
Yinghua Yu   +5 more
doaj   +1 more source

Access to enantioenriched compounds bearing challenging tetrasubstituted stereocenters via kinetic resolution of auxiliary adjacent alcohols

open access: yesNature Communications, 2021
A large number of enantiopure substances, such as those with tetrasubstituted carbon centres bearing several similar substituents, are inaccessible due to the incapability of chiral catalysts/ligands to recognize those substrates.
Shengtong Niu   +7 more
doaj   +1 more source

(R)-Baclofen [(R)-4-amino-3-(4-chlorophenyl)butanoic acid]

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2022
This article provides the first single-crystal XRD-based structure of enantiopure (R)-baclofen (form C), C10H12ClNO2, without any co-crystallized substances.
Feodor Belov   +2 more
doaj   +1 more source

Differentiation between enamines and tautomerizable imines in the oxidation reaction with TEMPO

open access: yesNature Communications, 2018
Tautomerization of imines into enamines is the basis of their similar reactivity; however, minor structural changes may lead to different outcomes. Here, the authors show that the reaction of cyclohexanone and amines in presence of TEMPO affords either α-
Xiaoming Jie   +5 more
doaj   +1 more source

SYNTHESIS OF LOCAL AREA NETWORK STRUCTURE IN UNCERTAIN CONDITIONS OF INITIAL INFORMATION

open access: yesВісник Національного технічного університету "ХПÌ": Системний аналіз, управління та інформаційні технології, 2019
The problem of taking into account the uncertainty of the initial information is identified in the tasks of the structure synthesis of local area networks.
Oryna Oleksiivna Mishchenko   +3 more
doaj   +1 more source

Synthesis of difluoromethylated allenes through trifunctionalization of 1,3-enynes

open access: yesNature Communications, 2020
Fluorinated or fluoroalkylated allenes are versatile building blocks for medicinal and material chemistry. Here, the authors show a regioselective trifunctionalization of 1,3-enynes proceeding through double C-F bond formation and concomitant ...
Munira Taj Muhammad   +9 more
doaj   +1 more source

Radical azidation as a means of constructing C(sp3)-N3 bonds

open access: yesGreen Synthesis and Catalysis, 2020
The azido group is found in large numbers of natural products, drugs, biochemicals and materials and to date, many elegant and useful methods for the synthesis of organic azides and their transformations have been documented. In this review, we provide a
Liang Ge   +3 more
doaj   +1 more source

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