Results 21 to 30 of about 3,323 (237)

Palladium-catalyzed regio- and enantioselective migratory allylic C(sp3)-H functionalization

open access: yesNature Communications, 2021
Alkene isomerizations and asymmetric C–H functionalizations have been independently studied, but their combination in one protocol is uncommon. Here the authors show a palladium-catalyzed method to iteratively “walk” a terminal alkene along a carbon ...
Ye-Wei Chen   +4 more
doaj   +1 more source

Kinetic Resolution of β-Alkyl Phenylethylamine Derivatives through Palladium-Catalyzed, Nosylamide-Directed C−H Olefination

open access: yesMolecules, 2023
Palladium-catalyzed C-H activation reactions have attracted the attention of organic researchers due to their unique high selectivity, broad functional group tolerance, and high efficiency, and they are widely used in natural products and asymmetric ...
Zeng Zhao   +5 more
doaj   +1 more source

Blends of styrene-butadiene-styrene triblock copolymer with random styrene-maleic anhydride copolymers [PDF]

open access: yesMacromolecular Chemistry and Physics, 2002
Blends of styrene-butadiene-styrene triblock copolymer (SBS) with random styrene-maleic anhydride copolymers (PS-co-MA), having different MA content, were prepared in a Brabender Plastigraph mixer. The presence of polystyrene (PS) blocks in the SBS copolymer and the high styrene content (93 and 86 wt.-%, respectively) in the two kinds of used PS-co-MA ...
PICCHIONI F.   +4 more
openaire   +5 more sources

Quinazolin-4(3H)-ones: A Tangible Synthesis Protocol via an Oxidative Olefin Bond Cleavage Using Metal-Catalyst Free Conditions

open access: yesApplied Sciences, 2020
An efficient and selective oxidative procedure for the synthesis of quinazolinones from readily available o-aminobenzamides and styrenes was developed.
Muhammad Sharif
doaj   +1 more source

Random copolymer blends of styrene, para-fluoro styrene and ortho-fluoro styrene [PDF]

open access: yesPolymer, 1993
This study completes the investigation of the phase behaviour of polymer blends involving styrene (S), ortho-fluoro styrene (oFS) and para-fluoro styrene (pFS). As before, due to the proximity of the glass transition temperatures of most blends investigated, the miscibility or immiscibility is established using the alternative thermal analysis method ...
OUDHUIS, AACM, TENBRINKE, G, KARASZ, FE
openaire   +2 more sources

Reactions of 3-aryl-1-(trifluoromethyl)prop-2-yn-1-iminium salts with 1,3-dienes and styrenes

open access: yesBeilstein Journal of Organic Chemistry, 2020
3-Aryl-1-(trifluoromethyl)prop-2-yn-1-iminium triflate salts represent a novel, highly reactive class of acetylenic iminium salts. Herein we present several reactions which are based on the electron-poor acetylenic bond and on the high electrophilicity ...
Thomas Schneider   +3 more
doaj   +1 more source

Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation

open access: yesNature Communications, 2018
Hydrosilylation of alkenes poses substantial challenges in terms of regioselectivity. Here, the authors report iron complexes with 1,10-phenantroline ligand scaffolds which  display benzylic selectivity in the hydrosilylation of internal alkenes and ...
Meng-Yang Hu   +7 more
doaj   +1 more source

A Morphological Study of Dynamically Vulcanized Styrene-Ethylene-Butylene-Styrene/Styrene-Butylene-Styrene/MethylVinylSilicon Rubber Thermoplastic Elastomer

open access: yesPolymers, 2022
In this work, we prepared thermoplastic silicone rubber (TPSiV) by dynamically vulcanizing different relative proportions of methyl vinyl silicone rubber (MVSR), styrene ethylene butene styrene block copolymer (SEBS), and styrene butadiene styrene block copolymer (SBS).
Zhao, Chunxu, Chen, Xiaohan, Chen, Xian
openaire   +2 more sources

Impact of Textile Architecture on the Electromechanical Behavior of Conductive Carbon: Silicone Composite Strain Sensors

open access: yesAdvanced Engineering Materials, EarlyView.
A stretchable carbon composite is integrated by stencil printing onto two different types of textile, with different yarn morphologies. The impact of the knit structure and coating direction on the performance of the sensor composite is evaluated and used to derive a model estimating nominal resistance at a given strain near the percolation threshold ...
Gabriela Ananieva   +2 more
wiley   +1 more source

What Do Large Language Models Know About Materials?

open access: yesAdvanced Engineering Materials, EarlyView.
If large language models (LLMs) are to be used inside the material discovery and engineering process, they must be benchmarked for the accurateness of intrinsic material knowledge. The current work introduces 1) a reasoning process through the processing–structure–property–performance chain and 2) a tool for benchmarking knowledge of LLMs concerning ...
Adrian Ehrenhofer   +2 more
wiley   +1 more source

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