Visible-Light-Driven Reductive Carboarylation of Styrenes with CO2 and Aryl Halides.
Journal of the American Chemical Society, 2019 The first example of visible-light-driven reductive carboarylation of styrenes with CO2 and aryl halides in a regioselective manner has been achieved. A broad range of aryl iodides and bromides were compatible with this reaction.
Hao Wang +3 more
semanticscholar +1 more source
Photocatalytic Fluoro Sulfoximidations of Styrenes
Angewandte Chemie, 2020 Reactions of difluoroiodotoluene with NH‐sulfoximines provide new hypervalent iodine(III) reagents, which photocatalytically transfer a fluoro and a sulfoximidoyl group onto styrenes with high regioselectivity.
Chenyang Wang +3 more
semanticscholar +1 more source
Formal [4 + 1] Cycloadditions of β,β-Diaryl-Substituted ortho-(Alkynyl)styrenes through Gold(I)-Catalyzed Cycloisomerization Reactions [PDF]
, 2016 Gold(I)-catalyzed cycloisomerization of β,β-diaryl-o-(alkynyl)- styrenes at 80 °C selectively yields dihydroindeno[2,1-a]indenes in a transformation that encompasses a formal [4 + 1] cycloaddition and takes place through a cascade 5-endo-cyclization ...
Fernández Rodríguez, Manuel A. +4 more
core +1 more source
Palladium-catalyzed regio- and enantioselective migratory allylic C(sp3)-H functionalization
Nature Communications, 2021 Alkene isomerizations and asymmetric C–H functionalizations have been independently studied, but their combination in one protocol is uncommon. Here the authors show a palladium-catalyzed method to iteratively “walk” a terminal alkene along a carbon ...
Ye-Wei Chen +4 more
doaj +1 more source
1,3-Dien-5-ynes: Versatile Building Blocks for the Synthesis of Carbo- and Heterocycles [PDF]
, 2016 1,3-Dien-5-ynes have been extensively used as starting materials for the synthesis of a wide number of different carbo- and heterocycles. The aim of this review is to give an overview of their utility in organic synthesis, highlighting the variety of ...
Aguilar, Enrique +3 more
core +1 more source
Halocyclization of o-(Alkynyl)styrenes. Synthesis of 3-Halo-1H-indenes [PDF]
, 2010 Junta de Castilla y Leon (BU021A09 and GR-172), Ministerio de Educacion y Ciencia (MEC), FEDER (CTQ2007-61436/BQU and CTQ2009-09949/BQU), MEC (FPU grant), Juan de la Cierva, Ramon y Cajal and "Young Foreign Researchers" (SB2009-0186 ...
Fernández Rodríguez, Manuel A. +5 more
core +1 more source
Rhodium/phospholane-phosphite catalysts give unusually high regioselectivity in the enantioselective hydroformylation of vinyl arenes [PDF]
, 2014 Using the phospholane-phosphite ligand, BOBPHOS, almost perfect regioselectivities and high enantioselectivities (up to 92% ee) are observed in Rh catalysed enantioselective hydroformylation of vinyl arenes.
Clarke, Matthew L. +3 more
core +1 more source
Iodoarene-Catalyzed Cyclizations of Unsaturated Amides [PDF]
, 2015 The cyclization of N-alkenylamides catalyzed by iodoarenes under oxidative conditions is presented. Five-, six-, and seven-membered rings with a range of substitutions can be prepared by this route.
Ali Alhalib +30 more
core +1 more source
Molecules, 2023 Palladium-catalyzed C-H activation reactions have attracted the attention of organic researchers due to their unique high selectivity, broad functional group tolerance, and high efficiency, and they are widely used in natural products and asymmetric ...
Zeng Zhao +5 more
doaj +1 more source
Blends of styrene-butadiene-styrene triblock copolymer with random styrene-maleic anhydride copolymers [PDF]
Macromolecular Chemistry and Physics, 2002 Blends of styrene-butadiene-styrene triblock copolymer (SBS) with random styrene-maleic anhydride copolymers (PS-co-MA), having different MA content, were prepared in a Brabender Plastigraph mixer. The presence of polystyrene (PS) blocks in the SBS copolymer and the high styrene content (93 and 86 wt.-%, respectively) in the two kinds of used PS-co-MA ...
PICCHIONI F. +4 more
openaire +5 more sources