Results 21 to 30 of about 6,792 (286)

Blends of styrene-butadiene-styrene triblock copolymer with random styrene-maleic anhydride copolymers [PDF]

open access: yesMacromolecular Chemistry and Physics, 2002
Blends of styrene-butadiene-styrene triblock copolymer (SBS) with random styrene-maleic anhydride copolymers (PS-co-MA), having different MA content, were prepared in a Brabender Plastigraph mixer. The presence of polystyrene (PS) blocks in the SBS copolymer and the high styrene content (93 and 86 wt.-%, respectively) in the two kinds of used PS-co-MA ...
PICCHIONI F.   +4 more
openaire   +5 more sources

Torsional Barriers for Planar versus Twisted Singlet Styrenes

open access: yes, 2016
Kinetic modeling of the temperature-dependent lifetimes of styrene and several methyl-substituted styrenes has been used to obtain the torsional barriers for singlet-state CC rotation.
Frederick D. Lewis (1278270)   +1 more
core   +2 more sources

Dipolar Cycloaddition Reactions with Quinazolinones: A New Route for the Synthesis of Several Annelated Pyrrolo- and Pyridazinoquinazoline Derivatives

open access: yesMolecules, 2003
The novel 2-aryl-3a,4,12,12a-tetrahydropyrrolo[3',4':4,3]-pyridazino[6,1-b]-quinazoline-1,3,6-triones (6a–d), 2-aryl-10-oxopyridazino[6,1-b]-quinazoline-3-thio-carboxamides (10a–d) and 2-aryl-3-nitro-1,2,3,4-tetrahydro-pyridazino[6,1-b ...
Hatem M. Gaber, Sami S. Ghabrial
doaj   +1 more source

Organocatalytic atroposelective synthesis of axially chiral styrenes

open access: yesNature Communications, 2017
Many methods exist for the atroposelective synthesis of axially chiral biaryls, but axially chiral styrenes are much less explored. Here the authors report an organocatalytic procedure for the synthesis of configurationally stable, axially chiral ...
Sheng-Cai Zheng   +5 more
doaj   +1 more source

Nickel(0)-Catalyzed Linear-Selective Hydroarylation of Unactivated Alkenes and Styrenes with Arylboron Acids [PDF]

open access: yes, 2018
Herein, we realized the first linear-selective hydroarylation of unactivated alkenes and styrenes with organoboronic acids by introducing directing groupon alkenes.
Li-Jun, Xiao   +3 more
core   +2 more sources

Palladium-catalyzed regio- and enantioselective migratory allylic C(sp3)-H functionalization

open access: yesNature Communications, 2021
Alkene isomerizations and asymmetric C–H functionalizations have been independently studied, but their combination in one protocol is uncommon. Here the authors show a palladium-catalyzed method to iteratively “walk” a terminal alkene along a carbon ...
Ye-Wei Chen   +4 more
doaj   +1 more source

Hydroxy- and Hydro-Perfluoroalkylation of Styrenes by Controlling the Quenching Cycle of Eosin Y

open access: yesMolecules, 2023
Fluoroalkyl compounds are widely used, underscoring a pressing need for the development of methods for their synthesis. However, reports on perfluoroalkylation to styrenes have been sparse.
Haruko Shibata   +4 more
doaj   +1 more source

Mechanochemical Piezoelectric Catalysis: Advancing the Hydrogenation of Alkenes. [PDF]

open access: yesAdv Sci (Weinh)
This study presents mechanochemical piezoelectric catalysis for alkene hydrogenation, eliminating the need for transition metals, H2, and solvents. The method effectively hydrogenates diverse activated and unactivated alkenes and shows potential for modifying bioactive molecules in pharmaceuticals.
Ai Z   +5 more
europepmc   +2 more sources

Ketones from aldehydes via alkyl C(sp3)−H functionalization under photoredox cooperative NHC/palladium catalysis

open access: yesNature Communications, 2023
Direct synthesis of ketones from aldehydes features high atom- and step-economy. Yet, the coupling of aldehydes with unactivated alkyl C(sp3)-H remains challenging.
Hai-Ying Wang   +4 more
doaj   +1 more source

Reactions of 3-aryl-1-(trifluoromethyl)prop-2-yn-1-iminium salts with 1,3-dienes and styrenes

open access: yesBeilstein Journal of Organic Chemistry, 2020
3-Aryl-1-(trifluoromethyl)prop-2-yn-1-iminium triflate salts represent a novel, highly reactive class of acetylenic iminium salts. Herein we present several reactions which are based on the electron-poor acetylenic bond and on the high electrophilicity ...
Thomas Schneider   +3 more
doaj   +1 more source

Home - About - Disclaimer - Privacy