Results 41 to 50 of about 127,650 (334)

Mechanistic Studies Lead to Dramatically Improved Reaction Conditions for the Cu-Catalyzed Asymmetric Hydroamination of Olefins [PDF]

open access: yes, 2015
Enantioselective copper(I) hydride (CuH)-catalyzed hydroamination has undergone significant development over the past several years. To gain a general understanding of the factors governing these reactions, kinetic and spectroscopic studies were ...
Bandar, Jeffrey   +2 more
core   +3 more sources

Quinazolin-4(3H)-ones: A Tangible Synthesis Protocol via an Oxidative Olefin Bond Cleavage Using Metal-Catalyst Free Conditions

open access: yesApplied Sciences, 2020
An efficient and selective oxidative procedure for the synthesis of quinazolinones from readily available o-aminobenzamides and styrenes was developed.
Muhammad Sharif
doaj   +1 more source

Random copolymer blends of styrene, para-fluoro styrene and ortho-fluoro styrene [PDF]

open access: yesPolymer, 1993
This study completes the investigation of the phase behaviour of polymer blends involving styrene (S), ortho-fluoro styrene (oFS) and para-fluoro styrene (pFS). As before, due to the proximity of the glass transition temperatures of most blends investigated, the miscibility or immiscibility is established using the alternative thermal analysis method ...
OUDHUIS, AACM, TENBRINKE, G, KARASZ, FE
openaire   +2 more sources

tert-Butyl 5-methoxy-3-pentylindole-1-carboxylate [PDF]

open access: yes, 2004
he molecule of the title compound, C₁₉H₂₇NO₃, is essentially planar, with all non-H atoms within 0.2 Å of the nine-membered indole plane, except for the three tert-butyl C atoms.
Coleman, Claire M.   +2 more
core   +1 more source

Reactions of 3-aryl-1-(trifluoromethyl)prop-2-yn-1-iminium salts with 1,3-dienes and styrenes

open access: yesBeilstein Journal of Organic Chemistry, 2020
3-Aryl-1-(trifluoromethyl)prop-2-yn-1-iminium triflate salts represent a novel, highly reactive class of acetylenic iminium salts. Herein we present several reactions which are based on the electron-poor acetylenic bond and on the high electrophilicity ...
Thomas Schneider   +3 more
doaj   +1 more source

Straightforward Synthesis of Dihydrobenzo[a]fluorenes through Au(I)-Catalyzed Formal [3 + 3] Cycloadditions [PDF]

open access: yes, 2012
Dihydrobenzo[a]fluorene derivatives have been prepared by a formal intramolecular [3 + 3] cycloaddition of o-alkynylstyrenes bearing a secondary alkyl group at the β-position of the styrene moiety.
Fernández Rodríguez, Manuel A.   +4 more
core   +1 more source

Copper-Catalyzed Regioselective Ortho C-H Cyanation of Vinylarenes [PDF]

open access: yes, 2014
A copper-based catalytic technique for the regioselective ortho C-H cyanation of vinylarenes has been developed. This method provides an effective means for the selective functionalization of vinylarene derivatives.
Albrecht   +50 more
core   +1 more source

Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation

open access: yesNature Communications, 2018
Hydrosilylation of alkenes poses substantial challenges in terms of regioselectivity. Here, the authors report iron complexes with 1,10-phenantroline ligand scaffolds which  display benzylic selectivity in the hydrosilylation of internal alkenes and ...
Meng-Yang Hu   +7 more
doaj   +1 more source

A Morphological Study of Dynamically Vulcanized Styrene-Ethylene-Butylene-Styrene/Styrene-Butylene-Styrene/MethylVinylSilicon Rubber Thermoplastic Elastomer

open access: yesPolymers, 2022
In this work, we prepared thermoplastic silicone rubber (TPSiV) by dynamically vulcanizing different relative proportions of methyl vinyl silicone rubber (MVSR), styrene ethylene butene styrene block copolymer (SEBS), and styrene butadiene styrene block copolymer (SBS).
Zhao, Chunxu, Chen, Xiaohan, Chen, Xian
openaire   +2 more sources

(9R,10R,10aR)-9-(2-Bromo-phen-yl)-10-nitro-6-phenyl-10,10a-dihydro-9H-benzo[c]chromene-8-carbaldehyde [PDF]

open access: yes, 2011
The title compound, C26H18BrNO4, features a functionalized chromene. The cyclo­hexene ring adopts a sofa conformation and has the nitro group and the bromo­phenyl ring in an axial position. The ten atoms of the chromene moiety lie close to a common plane
Dufour, Jeremy   +2 more
core   +1 more source

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