Results 151 to 160 of about 134,654 (299)

Electrochemical Modulation of Laser‐Induced Covalent Functionalization of Graphene

open access: yesAdvanced Science, EarlyView.
Photoelectrochemical functionalization of graphene introduces the electrochemical potential as an additional parameter for the laser‐induced covalent modification of graphene. Tuning of the potential allows for amplification or suppression of the functionalization reaction with constant laser parameters, which enables in situ Raman analysis of ...
Tamara Nagel   +7 more
wiley   +1 more source

Bacterial reaction centers with modified tetrapyrrole chromophores [PDF]

open access: yes, 1993
Deisenhofer, J.   +2 more
core   +1 more source

Substituent effects in triarylphosphines

open access: yes, 2012
M.Sc. The main objective of the work presented in this dissertation was to investigate the application of the phosphorus atom as a probe to evaluate stereo-electronic effects in arylphosphines. Traditionally, electronic effects are described as having inductive or resonance origins.
openaire   +1 more source

Substituent Effects in Thiophenes

open access: yesCroatica Chemica Acta, 1995
He I and He II photoelectron spectra (UPS) of 2-acetyl and 2-cyano thiophene have been measured. The electronic strucutre of the title compounds and, in particular, the effect of substituents on the thiophene % orbitals is discussed on the basis of band widths, He I/He II intensities and semi-empirical MO calculations.
openaire   +1 more source

Atroposelective Construction of Axially Chiral Tetraarylethenes Via NHC‐Catalyzed Desymmetrization

open access: yesAdvanced Science, EarlyView.
We report the first NHC‐catalyzed atroposelective synthesis of axially chiral TAEs via oxidative desymmetrization of prochiral TAE dialdehydes. This catalytic strategy operates under mild conditions and accommodates a broad range of phenolic and nitrogen nucleophiles, delivering diverse axially chiral TAEs in good yields and up to 99% ee.
Yang‐Ze Zheng   +6 more
wiley   +1 more source

Metabolism‐Based Biomarkers for Rapid Phenotypic Antibiotic Susceptibility Testing

open access: yesAdvanced Science, EarlyView.
Metabolic differences emerging after antibiotic exposure provide rapid phenotypic signals of susceptibility and resistance. This review summarizes metabolic biomarkers for rapid phenotypic AST, associated with nutrient uptake, respiratory activity, metabolic reprogramming, and enzymatic function. ABSTRACT The accelerating global crisis of antimicrobial
Sha Yu   +7 more
wiley   +1 more source

A Catalytic Osmium Redox Couple Collapses Cancer Redox Balance

open access: yesAdvanced Science, EarlyView.
A stable Os(III)/Os(IV) redox couple is developed to disrupt the tumor cell redox balance by concurrently catalyzing ROS generation and GSH depletion. Osmium‐treated cells exhibit multiple cell death pathways, including apoptosis, ferroptosis, and immunogenic cell death.
Wan‐Qiong Huang   +9 more
wiley   +1 more source

Integrating the Substituent Effect into the Wade-Mingos Rules for Dicarboranes. [PDF]

open access: yesAngew Chem Int Ed Engl
Wang SS   +6 more
europepmc   +1 more source

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