Results 71 to 80 of about 134,654 (299)

Expanding the palette of phenanthridinium cations [PDF]

open access: yes, 2014
5,6-Disubstituted phenanthridinium cations have a range of redox, fluorescence and biological properties. Some properties rely on phenanthridiniums intercalating into DNA, but the use of these cations as exomarkers for the reactive oxygen species (ROS ...
Acevedo   +114 more
core   +4 more sources

Furan‐Substituted Phosphine‐Oxide as an Efficient Interfacial Modifier for Wide‐Bandgap Perovskite Solar Cells

open access: yesAdvanced Functional Materials, EarlyView.
We report phosphine‐oxide interlayers for wide‐bandgap perovskite solar cells, in which tuned P = O Lewis basicity enables selective passivation of buried NiOx/perovskite interfaces and introduces interfacial dipoles that strengthen the built‐in field.
JeeHee Hong   +6 more
wiley   +1 more source

Effect of sodium hydroxide pretreatment of NiOx cathodes on the performance of squaraine-sensitized p-type dye-sensitized solar cells [PDF]

open access: yes, 2018
Squaraines are full-organic dyes employed as sensitizers in ptype dye-sensitized solar cells (p-DSSC). Their absorption spectrum shows a wide tunability that ranges from visible to NIR.
Barolo, Claudia   +5 more
core   +1 more source

Cross‐Layer Molecular Design for Coherent Interface Passivation in Rigid and Flexible Perovskite Solar Cells

open access: yesAdvanced Functional Materials, EarlyView.
A cross‐layer passivation strategy employing molecularly designed thiazol‐5‐ylmethanamine hydrochloride (TMACl) enables coherent defect regulation at the SnO2/perovskite interface, stabilizes both layers, promotes phase‐pure α‐FAPbI3 formation, and enhances charge extraction, delivering PCEs of 26.44% in rigid and 24.72% in flexible perovskite solar ...
Fan Shen   +16 more
wiley   +1 more source

Substituent effects on the solvent power of the haloolefin HCFO-1233 yd.(Z)

open access: yesResults in Chemistry
The solvent power of the hydrochlorofluoroolefin HCFO-1233 yd.(Z) is investigated using electron-withdrawing and electron-donating substituents on the “parent” (Z)-1-X-2,3,3-trifluoropropene, where X = NH2, OH, CH3O, CH3, F, H, Cl, COOH, CF3, CN, and NO2.
A. Fan   +3 more
doaj   +1 more source

Substituent Effect in Benzene Dication

open access: yesPhysical Chemistry Chemical Physics, 2014
It was recently postulated that the benzene ring and its 4n + 2 π-electron analogues are resistant to the substituent effect due to the fact that such systems tend to retain their delocalized character. Therefore, the 4n π-electron dicationic form of benzene should appear to be less resistant to the substituent effect, as compared with its parent ...
Palusiak, Marcin   +3 more
openaire   +2 more sources

The substituent effect on benzene dications

open access: yesPhys. Chem. Chem. Phys., 2014
It was shown that the substituent effect in the dicationic benzene ring, which is a 4nπ-electron system, can be numerically quantified and then further interpreted.
Palusiak, Marcin   +3 more
openaire   +5 more sources

How the Carrier Mobility and Seebeck Coefficient of Doped Semiconducting Polymers Are Controlled by Counterion Interactions and Mesoscale Order

open access: yesAdvanced Functional Materials, EarlyView.
Conventional doping of P3HT with F4TCNQ results in poor charge transport. However, when F4TCNQ is exchanged with LiTFSI, the transport characteristics are greatly enhanced. We find the increase in charge transport is directly related to an increase in the mesoscale ordering of P3HT, resulting in longer and better‐connected transport pathways.
Quynh M. Duong   +9 more
wiley   +1 more source

Thioether-catalysed tandem synthesis of furans and cyclic ethers or lactones [PDF]

open access: yes, 2017
Acyclic conjugated ynenediones tethered to an alcohol or carboxylic acid are converted into furanyl-substituted cyclic ethers or lactones in a single step by treatment with the tetrahydrothiophene.
Clark, J. Stephen, Klaus, Verena
core   +1 more source

Dynamic Proton Activity Regulation via Brønsted Bases Enables Durable and High‐Energy‐Density Zn||MnO2 Batteries

open access: yesAdvanced Functional Materials, EarlyView.
Our study demonstrates Brønsted base‐mediated proton transfer for HOAc dissociation regulation in weakly acidic electrolytes, where imidazole achieves optimal dynamic proton equilibrium‐simultaneously stabilizing Zn anodes and enabling efficient Mn2+/MnO2 conversion.
Wenli Xin   +7 more
wiley   +1 more source

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