Results 51 to 60 of about 67,257 (300)

Substituent Effects on the Cooperativity of Halogen Bonding

The Journal of Physical Chemistry A, 2013
DFT calculations (B97-1) with the 6-31+G(d,p)-LanL2DZdp basis set were used to analyze the intermolecular interactions in 4-Z-Py···XCN···XCN triads (Z = H, F, OH, OCH3, CH3, NH2, NO2, and CN; Py = pyridine; and X = Cl and Br) that are connected by halogen-bond interactions. To understand the properties of the systems better, the corresponding dyads are
Solimannejad, Mohammad, Malekani, M., Alkorta, Ibon   +2 more
openaire   +3 more sources

Engineered AuNPs/fMWCNT Nanocomposite Electrodes for High‐Sensitivity Methylglyoxal Sensing in Saliva and Sweat for Non‐Invasive Diabetes Monitoring

Advanced Healthcare Materials, EarlyView.
An AuNPs/fMWCNT nanocomposite‐modified screen‐printed carbon electrode was engineered via sequential electrodeposition and integrated into a 3D‐printed microfluidic platform for ultrasensitive methylglyoxal detection. The non‐invasive sensing platform enables rapid analysis in saliva and sweat, highlighting strong potential for wearable point‐of‐care ...
Ahadul Amin Soshi, Md Younus Ali, Dadbeh Pazuki, Matiar M.R. Howlader   +3 more
wiley   +1 more source

Effect of Substituents in Mussel‐inspired Surface Primers on their Oxidation and Priming Efficiency

ChemistryOpen, 2021
Marine mussels contain an abundant catechol moiety, 3,4‐dihydroxyphenylalanine (DOPA), in their interfacial foot proteins. DOPA contributes to both surface adhesion and bridging between the surface and overhead proteins (surface priming) by taking ...
Dr. Karuppasamy Ganesh, Jaewon Jung, Jun Woo Park, Prof. Dr. Byeong‐Su Kim, Prof. Dr. Sungbaek Seo   +4 more
doaj   +1 more source

Spiro‐Phenothiazine Hole‐Transporting Materials: Unlocking Stability and Scalability in Perovskite Solar Cells

Advanced Materials, EarlyView.
Fluorene‐functionalized spiro‐phenothiazine (PTZ‐Fl) exhibits strong Li+ affinity and thermal stability, enabling a PCE of 25.75% in small‐area cells and 22.07% in 25 cm2 modules. Under ISOS‐L3 conditions, PTZ‐Flbased devices retain over 80% efficiency after 1000 hours, demonstrating superior stability and scalability compared to spiro‐OMeTAD for next ...
Javier Urieta‐Mora, Seung Ju Choi, Jaeki Jeong, Silvia Orecchio, Inés García‐Benito, Manuel Pérez‐Escribano, Joaquín Calbo, Likai Zheng, Minseop Byun, Seyeong Song, Gi‐Hwan Kim, Shaik M. Zakeeruddin, Seog‐Young Yoon, Yimhyun Jo, Agustín Molina‐Ontoria, Enrique Ortí, Nazario Martín, Michael Grätzel   +17 more
wiley   +1 more source

Electronic effect of substituent of quinones on their catalytic performance in hydrocarbons oxidation

, 2008
Quinones with electron-withdrawing F, Cl or Br groups and N-hydroxyphthalimide (NHPI) were used as catalysts in selective oxidation of hydrocarbons with molecular oxygen as oxidant.
Zhou, Lipeng, Lipeng Zhou, Xu, Jie, Zhang, Wei, Chen, Yong, Su, Yunlai, Yang, Xiaomei   +6 more
core   +1 more source

Stepwise On‐Surface Synthesis and Transformations of Two‐Dimensional Covalent Organic Frameworks by Controlled Thermal Stimuli

Advanced Materials, EarlyView.
The seminal transformation of a 2D‐COF (SURFCOF‐IMDEA1) into a 2D porous COF (SURFCOF‐IMDEA2) on Au(111) by a sequential C‐C coupling and ladderization triggered by thermal annealing steps at increasing temperatures is reported. Abstract The development of covalent organic frameworks (COFs) is currently a primary objective in materials science, taking ...
Ana Barragán, Elena Pérez‐Elvira, Diego J. Vicent, Marco Lozano, Diego Soler‐Polo, Koen Lauwaet, José M. Gallego, Rodolfo Miranda, José I. Urgel, Pavel Jelínek, Nazario Martín, David Écija   +11 more
wiley   +1 more source

Substituent Effect on Triplet State Aromaticity of Benzene

, 2020
Density functional theory calculations have been performed to explore the substituent effect on benzene’s structure and aromaticity upon excitation to the first triplet excited state (T1).
Marija Baranac-Stojanović (1447213), Marija Baranac-Stojanović   +1 more
core   +2 more sources

Synthesis, structure and solvatochromic properties of 3-cyano-4,6-diphenyl-5-(3- and 4-substituted phenylazo)-2-pyridones [PDF]

Journal of the Serbian Chemical Society, 2010
A series of some new pyridone arylazo dyes was synthesized from the corresponding diazonium salts and 3-cyano-4,6-diphenyl-2-pyridone using the classical reaction for the synthesis of the azo compounds.
NINA TODOROVIĆ, GORDANA S. UŠĆUMLIĆ, NATAŠA V. VALENTIĆ, DUŠAN Ž. MIJIN, ALEKSANDAR D. MARINKOVIĆ, ADEL S. ALIMMARI   +5 more
doaj  

A ring‐controlled fluorescent platform for visualizing polymer degradation

Aggregate, 2023
The creation of a new photoluminescent platform to study their photo physics and further applications is important in the fields of chemistry, material, physics, etc.
Tianhong Wu, Wenhai Bian, Chunhui Wang, Jie Qiu, Xiaolong Sun, Xuhong Qian   +5 more
doaj   +1 more source

Radiation Effects on Polyacetylenes Having Substituents [PDF]

Polymer Journal, 1985
Effects of γ-ray irradiation on high molecular weight polyacetylenes with various substituents were studied in air and in vacuum. The molecular weights of polymers from aliphatic disubstituted acetylenes (2-octyne and 2-decyne) remarkably reduced with irradiation in air.
Higashimura, T., Tang, Benzhong, Masuda, T., Yamaoka, H., Matsuyama, T.   +4 more
openaire   +1 more source