Results 51 to 60 of about 124,244 (129)

Flavonoids: Hemisynthesis, Reactivity, Characterization and Free Radical Scavenging Activity

open access: yesMolecules, 2007
Phenolic compounds form one of the main classes of secondary metabolites. They display a large range of structures and they are responsible for the major organoleptic characteristics of plant-derived-foods and beverages, particularly color and taste ...
Paul Henri Ducrot   +2 more
doaj   +1 more source

The experimental gas-phase structures of 1,3,5-trisilylbenzene and hexasilylbenzene and the theoretical structures of all benzenes with three or more silyl substituents [PDF]

open access: yes, 2005
The structures of 1,3,5-trisilylbenzene and hexasilylbenzene in the gas phase have been determined by electron diffraction, and that of 1,3,5-trisilylbenzene by X-ray crystallography.
Binkley   +40 more
core   +1 more source

Design of Allosteric Stimulators of the Hsp90 ATPase as New Anticancer Leads [PDF]

open access: yes, 2017
Allosteric compounds that stimulate Hsp90 adenosine triphosphatase (ATPase) activity were rationally designed, showing anticancer potencies in the low micromolar to nanomolar range.
Agard, Da   +10 more
core   +1 more source

Insights into the relationship between structure and properties of Spirobichroman-based polyimides: Effects of substituents on molecular structure and gas separation

open access: yesMaterials & Design, 2020
Four spirobichroman-based polyimides (6FDA-F, 6FDA-O, 6FDA-P, and 6FDA-M) were successfully obtained via polyreaction between diamines of different substituents (-H, -OCH3, -N, and -CH3) and 4,4′-(hexafluoroisopropylidene)-diphthalic anhydride (6FDA ...
Shuli Wang   +6 more
doaj   +1 more source

Electronics and Chemistry: Varying Single Molecule Junction Conductance Using Chemical Substituents

open access: yes, 2007
We measure the low bias conductance of a series of substituted benzene diamine molecules while breaking a gold point contact in a solution of the molecules.
Hybertsen, Mark S.   +5 more
core   +1 more source

Interference enhanced thermoelectricity in quinoid type structures

open access: yes, 2015
Quantum interference (QI) effects in molecular junctions may be used to obtain large thermoelectric responses. We study the electrical conductance G and the thermoelec- tric response of a series of molecules featuring a quinoid core using density ...
Seldenthuis, J. S.   +4 more
core   +2 more sources

Characterization of a Reductively-Activated Elimination Pathway Relevant to the Biological Chemistry of the Kinamycins and Lomaiviticins [PDF]

open access: yes, 2012
The lomaiviticins (1 and 2) and kinamycins (3–5) are bacterial metabolites with potent antimicrobial and antiproliferative activities. Herein we establish that 1–5 are capable of generating electrophilic acylfulvene intermediates (6) under mildly ...
Ding, Weidong   +4 more
core   +3 more sources

Optimization of diarylazines as anti-HIV agents with dramatically [PDF]

open access: yes, 2013
Non-nucleoside inhibitors of HIV-1 reverse transcriptase are reported that have ca. 100-fold greater solubility than the structurally related drugs etravirine and rilpivirine, while retaining high anti-viral activity.
Anderson, Karen S.   +4 more
core   +1 more source

Synthesis, Spectroscopy and Electrochemistry in Relation to DFT Computed Energies of Ferrocene- and Ruthenocene-Containing β-Diketonato Iridium(III) Heteroleptic Complexes. Structure of [(2-Pyridylphenyl)2Ir(RcCOCHCOCH3]

open access: yesMolecules, 2019
A series of new ferrocene- and ruthenocene-containing iridium(III) heteroleptic complexes of the type [(ppy)2Ir(RCOCHCOR′)], with ppy = 2-pyridylphenyl, R = Fc = FeII(η5-C5H4)(η5-C5H5) and R′ = CH3 (1) or Fc (2), as well as R = Rc =
Blenerhassitt E. Buitendach   +4 more
doaj   +1 more source

Dissociative Electron Transfer to N‐(Arylthio)phthalimides: Factors Affecting the Formation and Dissociation of Radical Anions

open access: yesChemElectroChem
A series of chemically and biologically relevant N‐(arylthio)phthalimides is synthesized and its electrochemical reduction investigated. The results of the electrochemical study are analysed through application of Savéant's dissociative electron transfer
Michael A. Saley   +2 more
doaj   +1 more source

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