Results 131 to 140 of about 4,042 (165)
Some of the next articles are maybe not open access.

M(NH2SO3)2 (M=Sr, Ba): Two Deep‐Ultraviolet Transparent Sulfamates Exhibiting Strong Second Harmonic Generation Responses and Moderate Birefringence

Angewandte Chemie - International Edition, 2021
Over the last few decades, the development of each new nonlinear optical (NLO)-active functional unit has led to the discoveries of a series of excellent NLO materials. In the present work, based on first-principles studies, we identified a novel deep-UV (
Guangsai Yang, Min Luo, Guang Peng
exaly   +2 more sources

Nickel-Catalyzed Cross-Coupling of Ammonia or Primary Alkylamines with (Hetero)aryl Sulfamates, Carbamates, or Pivalates

open access: yesSynlett, 2017
A catalyst system capable of effecting the cross-coupling of ammonia or primary alkylamines with (hetero)aryl sulfamates, carbamates, or pivalates is reported for the first time.
Mark Stradiotto, Preston M Macqueen
exaly   +3 more sources

Synthesis of N-Acyl Sulfamates from Fluorosulfates and Amides.

open access: yesJournal of Organic Chemistry, 2019
A novel synthetic strategy toward  N-acyl sulfamates was developed. Interestingly, fluorosulfates, a new emerging class of electrophiles, were used to construct the sulfamate core.
Philippe Gilles   +5 more
semanticscholar   +2 more sources

Efficient and one-pot synthesis of novel sulfamates from carboxylic acids

open access: yesTetrahedron, 2019
Effective synthesis of novel sulfamates from various carboxylic acids has been developed in the presence of chlorosulfonyl isocyanate (CSI) in mild conditions.
Ufuk Atmaca
semanticscholar   +2 more sources

Catalytic Sulfamoylation of Alcohols with Activated Aryl Sulfamates.

open access: yesOrganic Letters, 2019
We report a new catalytic method for alcohol sulfamoylation that deploys electron-deficient aryl sulfamates as activated group transfer reagents. The reaction utilizes the simple organic base N-methylimidazole, proceeds under mild conditions, and ...
P. Rapp   +4 more
semanticscholar   +2 more sources

Deep-Ultraviolet Transparent Mixed Metal Sulfamates with Enhanced Nonlinear Optical Properties and Birefringence.

Angewandte Chemie, 2023
Enhancing anisotropy through the controlled arrangement of anionic groups is essential for improving the nonlinear optical (NLO) performance of non-π-conjugated NLO materials.
Xuefei Wang   +5 more
semanticscholar   +1 more source

M(NH2SO3)2·xH2O (M = Ca, Pb, x = 0, 1, 4): Effect of Hydrogen Bonding on Structural Transformations and Second Harmonic Generation of Metal Sulfamates.

Inorganic Chemistry, 2022
Nonlinear optical (NLO) crystals are very important for laser technology, but the performances of available NLO crystals are still insufficient for increasing demand.
Dan-Yang Dou   +3 more
semanticscholar   +1 more source

Temperature-Controlled Mechanochemistry Unlocks The Nickel-Catalyzed Suzuki-Miyaura-Type Coupling of Aryl Sulfamates at Different Scales.

Angewandte Chemie, 2022
Several mechanochemically heated processes have been published in recent years. However, precise control over the mechanochemical catalysed coupling reactions remained elusive.
Javier F. Reynes, Felipe García
semanticscholar   +1 more source

Hexafluoroisopropyl Sulfamate: A Useful Reagent for the Synthesis of Sulfamates and Sulfamides.

Organic Letters, 2021
Sulfamates and sulfamides are most often synthesized from alcohols and amines with sulfamoyl chloride, which is an unstable reagent. We have identified hexafluoroisopropyl sulfamate (HFIPS) as a bench-stable solid that reacts readily with a wide variety ...
Matthew A. Sguazzin   +2 more
semanticscholar   +1 more source

Preparation of Sulfamates and Sulfamides Using a Selective Sulfamoylation Agent.

Organic Letters, 2021
Sulfamates and sulfamides are prevalent in biological molecules, but their universal synthetic methods are limited. We herein report a sulfamoylation agent with high solubility and shelf stability.
Hai-Ming Wang   +4 more
semanticscholar   +1 more source

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