Results 91 to 100 of about 106,522 (343)

Photoinduced Selective Construction of Densely Functionalized Spirocyclic Ethers With Carbyne Equivalents

open access: yesAngewandte Chemie, EarlyView.
A reactivity programmed cascade between carbyne equivalents and allylic benzoates was developed that sequentially orchestrates all three reactivity modes of carbyne equivalents, enabling the rapid installation of three σ‐bonds at a single carbon center and providing efficient, scalable access to structurally diverse spirocyclic ethers. ABSTRACT Carbyne
Jianke Su   +5 more
wiley   +2 more sources

Advanced Corneal Hydrogels: From Passive Replacement to Active Regeneration and Intelligent Interaction

open access: yesAdvanced Science, EarlyView.
This review charts the evolution of corneal hydrogels from passive replacements to active and intelligent systems, evaluating natural and synthetic materials while addressing design challenges such as transparency and strength. Advanced applications such as scarless wound healing, three‐dimensional bioprinting, and smart wearables are highlighted to ...
Xinwei Wang   +9 more
wiley   +1 more source

Sequence‐Modulated Active Tripeptide Condensates for Tandem Catalysis

open access: yesAngewandte Chemie, EarlyView.
Sequence‐modulated tripeptide coacervates mimic biomolecular condensates with controllable, enzyme‐regulated phase separation. They co‐sequester hydrophobic active species and hydrophilic enzymes, enabling tandem catalysis in aqueous media. Incorporated into artificial cells, they function as adaptive sub‐organelles, orchestrating compartmentalized ...
Hao Han   +7 more
wiley   +2 more sources

Bis(3-nitrophenyl) sulfone

open access: yesActa Crystallographica Section E, 2008
The asymmetric unit of the title compound, C12H8N2O6S, an important diphenyl sulfone derivative, contains one half-molecule; a mirror plane passes through the SO2 group. The dihedral angle between the two symmetry-related benzene rings is 40.10 (13)
Wei Yao   +4 more
doaj   +1 more source

Anion Exchange Membranes: Enhancement by Addition of Unfunctionalized Triptycene Poly(Ether Sulfone)s.

open access: yesACS Applied Materials and Interfaces, 2017
Anion exchange membrane fuel cells are a clean and efficient promising future energy source. However, the development of stable high-performance membranes remains a major challenge.
Yoonseob Kim, L. Moh, T. Swager
semanticscholar   +1 more source

Microstructures in phase inversion membranes. Part II. The role of a polymeric additive [PDF]

open access: yes, 1992
Membranes were prepared from a casting solution of a water-soluble polymer, poly (vinyl pyrrolidone) (PVP), and a membrane forming polymer, poly (ether sulfone), in 1-methyl-2-pyrrolidone (NMP) as solvent by immersing them in mixtures of water and NMP ...
Boom, R.M.   +3 more
core   +2 more sources

Modular Generation of Alkyl Selenyl Radicals for the Synthesis of Alkyl Selenides via a Mechanochemical Approach

open access: yesAdvanced Science, EarlyView.
We present a mechanochemical, radical‐mediated hydroselenation of alkenes under ambient conditions. This method modularly generates alkyl selenyl radicals from elemental selenium and alkyl (pseudo)halides, utilizing PhSiH3 and H2O as hydrogen atom donors, with the water likely originating from the air and/or trace water present in the reagents ...
Xiaochun He   +8 more
wiley   +1 more source

From Covalent Traps to Fluorescent Beacons: The Expanding Arsenal of Chemical Probes for Studying Ubiquitin and Ubiquitin‐Like Proteins

open access: yesAngewandte Chemie, EarlyView.
A large variety of chemistry‐based ubiquitin probes have been developed. ABSTRACT Ubiquitin (Ub) and ubiquitin‐like proteins (Ubls) orchestrate diverse cellular processes through reversible post‐translational modification of target proteins. Their conjugation is governed by a cascade of E1 activating, E2 conjugating, and E3 ligating enzymes, while ...
Saibal Chanda, Wenshe Ray Liu
wiley   +2 more sources

Sulfur source-mediated transcriptional regulation of the rhlABC genes involved in biosurfactants production by Pseudomonas sp. strain AK6U

open access: yesFrontiers in Microbiology, 2014
Despite the nutritional significance of sulfur, its influence on biosurfactants production has not been sufficiently studied. We investigated the expression of key biosurfactants production genes, rhlABC, in cultures of Pseudomonas sp.
Wael eIsmail   +3 more
doaj   +1 more source

AFM study of oxygen reduction products on HOPG in the LiPF6–DMSO electrolyte [PDF]

open access: yes, 2013
Ex situ atomic force microscopy (AFM) has been used to study the morphology of oxygen reduction products in the LiPF6–dimethyl sulfoxide (DMSO) electrolyte, i.e. Li2O2 on a highly oriented pyrolytic graphite (HOPG) surface.
Calvo, Ernesto Julio   +3 more
core   +1 more source

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