Results 1 to 10 of about 272,245 (165)

Dibenzyl sulfoxide [PDF]

open access: yesActa Crystallographica Section E, 2011
There are two independent molecules in the asymmetric unit of the title compound, C14H14OS, which have asymmetric S—C bonds [1.791 (5) and 1.804 (5) Å in one molecule and 1.798 (5) and 1.804&#
Hai-Yang Liu   +3 more
doaj   +3 more sources

The Synthesis and Characterization of Selected Optically Active Sulfoxides Bearing Perfluorocumyl Moiety, Their Spontaneous Reversible Transformations into Higher-Valent Organosulfur Species–Bicyclic Hydroxysulfuranes, and Their Irreversible Transformation into Sultine [PDF]

open access: yesMolecules
The preparation of the novel optically active sulfoxides (-)-(S)-1,1,1,3,3,3-hexafluoro-2-[o-(p-tolylsulfinyl)phenyl]propan-2-ol 1, (-)-(S)-1,1,1,3,3,3-hexafluoro-2-[o-(methylsulfinyl)phenyl]propan-2-ol 2 and (-)-(S)-1,1,1,3,3,3-hexafluoro-2-[o-(t-butyl ...
Adrian Zajac   +2 more
doaj   +2 more sources

Diastereoselective reduction of protein-bound methionine sulfoxide by methionine sulfoxide reductase [PDF]

open access: yesFEBS Letters, 1999
Methionine sulfoxide (MetSO) in calmodulin (CaM) was previously shown to be a substrate for bovine liver peptide methionine sulfoxide reductase (pMSR, EC 1.8.4.6), which can partially recover protein structure and function of oxidized CaM in vitro. Here, we report for the first time that pMSR selectively reduces the D‐sulfoxide diastereomer of CaM ...
VÍCTOR S Sharov   +2 more
exaly   +3 more sources

Sulfoxides in medicine

open access: yesCurrent Opinion in Chemical Biology, 2023
In the review, current status of sulfoxides on the pharmaceutical market is discussed. In the first part of the article, natural sulfoxides will be described with a special focus on sulforaphane and amanitin, a mushroom toxin which has been developed as payload in antibody drug conjugates in the possible cancer treatment.
Elżbieta Wojaczyńska   +1 more
openaire   +2 more sources

The DmsABC Sulfoxide Reductase Supports Virulence in Non-typeable Haemophilus influenzae

open access: yesFrontiers in Microbiology, 2021
Although molybdenum-containing enzymes are well-established as having a key role in bacterial respiration, it is increasingly recognized that some may also support bacterial virulence.
Rabeb Dhouib   +8 more
doaj   +1 more source

2,5-[C4+C2] Ringtransformation of Pyrylium Salts with α-Sulfinylacetaldehydes

open access: yesMolecules, 2023
A rapid synthesis of chiral sulfoxide-functionalized meta-terphenyl derivatives by a 2,5-[C4+C2] ring transformation reaction of pyrylium salts with in situ generated enantiomerically pure α-sulfinylacetaldehydes is described in this paper.
Dominik Bauer   +2 more
doaj   +1 more source

Biotransformation of fenbendazole in sheep after administration of fenbendazole solid dispersion prepared by mechanochemical technique with arabinogalactane

open access: yesРоссийский паразитологический журнал, 2023
The purpose of the research is to study the biotransformation of fenbendazole in the body of sheep after administration of fenbendazole solid dispersion (FSD) prepared by mechanochemical technique with arabinogalactan. Materials and methods. The FSD at a
I. A. Arkhipov   +3 more
doaj   +1 more source

An Unexpected Reaction between Diaryliodonium Salts and DMSO

open access: yesOrganics, 2022
Diaryliodonium salts are useful arylating reagents that have been exploited widely. In this Communication, we demonstrate that heating diphenyliodonium triflate in the solvent DMSO leads to an unexpected arylation reaction.
Konrad Kepski, Wesley James Moran
doaj   +1 more source

Photoredox Catalytic Trifluoromethylation and Perfluoroalkylation of Arenes Using Trifluoroacetic and Related Carboxylic Acids

open access: yesCell Reports Physical Science, 2020
Summary: Trifluoroacetic acid (TFA) is among the most attractive trifluoromethylation reagents with respect to its low prices, ease of handling, and availability in large quantities.
Dehang Yin, Dengquan Su, Jian Jin
doaj   +1 more source

Design, Synthesis, and Biological Evaluation of Phenyloxadiazole Sulfoxide Derivatives as Potent Pseudomonas aeruginosa Biofilm Inhibitors

open access: yesMolecules, 2023
With the development of antimicrobial agents, researchers have developed new strategies through key regulatory systems to block the expression of virulence genes without affecting bacterial growth.
Xinyi Ye   +5 more
doaj   +1 more source

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