Results 1 to 10 of about 272,245 (165)
There are two independent molecules in the asymmetric unit of the title compound, C14H14OS, which have asymmetric S—C bonds [1.791 (5) and 1.804 (5) Å in one molecule and 1.798 (5) and 1.804&#
Hai-Yang Liu +3 more
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The Synthesis and Characterization of Selected Optically Active Sulfoxides Bearing Perfluorocumyl Moiety, Their Spontaneous Reversible Transformations into Higher-Valent Organosulfur Species–Bicyclic Hydroxysulfuranes, and Their Irreversible Transformation into Sultine [PDF]
The preparation of the novel optically active sulfoxides (-)-(S)-1,1,1,3,3,3-hexafluoro-2-[o-(p-tolylsulfinyl)phenyl]propan-2-ol 1, (-)-(S)-1,1,1,3,3,3-hexafluoro-2-[o-(methylsulfinyl)phenyl]propan-2-ol 2 and (-)-(S)-1,1,1,3,3,3-hexafluoro-2-[o-(t-butyl ...
Adrian Zajac +2 more
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Diastereoselective reduction of protein-bound methionine sulfoxide by methionine sulfoxide reductase [PDF]
Methionine sulfoxide (MetSO) in calmodulin (CaM) was previously shown to be a substrate for bovine liver peptide methionine sulfoxide reductase (pMSR, EC 1.8.4.6), which can partially recover protein structure and function of oxidized CaM in vitro. Here, we report for the first time that pMSR selectively reduces the D‐sulfoxide diastereomer of CaM ...
VÍCTOR S Sharov +2 more
exaly +3 more sources
In the review, current status of sulfoxides on the pharmaceutical market is discussed. In the first part of the article, natural sulfoxides will be described with a special focus on sulforaphane and amanitin, a mushroom toxin which has been developed as payload in antibody drug conjugates in the possible cancer treatment.
Elżbieta Wojaczyńska +1 more
openaire +2 more sources
The DmsABC Sulfoxide Reductase Supports Virulence in Non-typeable Haemophilus influenzae
Although molybdenum-containing enzymes are well-established as having a key role in bacterial respiration, it is increasingly recognized that some may also support bacterial virulence.
Rabeb Dhouib +8 more
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2,5-[C4+C2] Ringtransformation of Pyrylium Salts with α-Sulfinylacetaldehydes
A rapid synthesis of chiral sulfoxide-functionalized meta-terphenyl derivatives by a 2,5-[C4+C2] ring transformation reaction of pyrylium salts with in situ generated enantiomerically pure α-sulfinylacetaldehydes is described in this paper.
Dominik Bauer +2 more
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The purpose of the research is to study the biotransformation of fenbendazole in the body of sheep after administration of fenbendazole solid dispersion (FSD) prepared by mechanochemical technique with arabinogalactan. Materials and methods. The FSD at a
I. A. Arkhipov +3 more
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An Unexpected Reaction between Diaryliodonium Salts and DMSO
Diaryliodonium salts are useful arylating reagents that have been exploited widely. In this Communication, we demonstrate that heating diphenyliodonium triflate in the solvent DMSO leads to an unexpected arylation reaction.
Konrad Kepski, Wesley James Moran
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Summary: Trifluoroacetic acid (TFA) is among the most attractive trifluoromethylation reagents with respect to its low prices, ease of handling, and availability in large quantities.
Dehang Yin, Dengquan Su, Jian Jin
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With the development of antimicrobial agents, researchers have developed new strategies through key regulatory systems to block the expression of virulence genes without affecting bacterial growth.
Xinyi Ye +5 more
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