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Sulfone-Modified Covalent Organic Frameworks Enabling Efficient Photocatalytic Hydrogen Peroxide Generation via One-Step Two-Electron O2 Reduction.

Angewandte Chemie, 2023
Photocatalytic oxygen reduction reaction (ORR) offers a promising hydrogen peroxide (H2O2) synthetic strategy, especially the one-step two-electron (2e-) ORR route holds great potential in achieving highly efficient and selectivity.
Yu Luo   +8 more
semanticscholar   +1 more source

The vinyl sulfone motif as a structural unit for novel drug design and discovery

Expert Opinion on Drug Discovery, 2023
Introduction Vinyl sulfones are a special sulfur-containing structural unit that have attracted considerable attention, owing to their important role in serving as key structural motifs of various biologically active compounds as well as serving as ...
You‐Cai Xiao, Fener Chen
semanticscholar   +1 more source

Recent applications of vinyl sulfone motif in drug design and discovery.

European journal of medicinal chemistry, 2022
Vinyl sulfone with electrophilic character is not only a versatile building block for various organic transformations but also is a key structural unit in a large number of biologically active molecules.
R. Ahmadi, S. Emami
semanticscholar   +1 more source

Sulfoxide and Sulfone Synthesis via Electrochemical Oxidation of Sulfides.

Journal of Organic Chemistry, 2021
The oxidation of diaryl sulfides and aryl alkyl sulfides to the corresponding sulfoxides and sulfones under electrochemical conditions is reported. Sulfoxides are selectively obtained in good yield under a constant current of 5 mA for 10 h in DMF, while ...
Jin Kyu Park, Sunwoo Lee
semanticscholar   +1 more source

Structural Effects of Solvents on Li-Ion-Hopping Conduction in Highly Concentrated LiBF4/Sulfone Solutions.

Journal of Physical Chemistry B, 2021
Li-ion-hopping conduction is known to occur in certain highly concentrated electrolytes, and this conduction mode is effective for achieving lithium batteries with high rate capabilities.
Yosuke Ugata   +5 more
semanticscholar   +1 more source

Lithium Nitrate Regulated Sulfone Electrolytes for Lithium Metal Batteries.

Angewandte Chemie, 2020
The electrolytes in lithium metal batteries have to be compatible with both lithium metal anodes and high voltage cathodes, which can be regulated by manipulating the solvation structure.
Jiale Fu   +6 more
semanticscholar   +1 more source

Transition Metal‐Catalyzed Cross‐Couplings of Benzylic Sulfone Derivatives

The chemical record, 2021
In recent years, the use of organosulfones as a new class of cross‐coupling partner in transition‐metal catalyzed reactions has undergone significant advancement.
Masakazu Nambo, C. Crudden
semanticscholar   +1 more source

Vinyl sulfones

Acta Crystallographica Section C Crystal Structure Communications, 2008
Four neutral vinyl sulfones, two of which are paired with phosphonate groups, are described. The compounds are diisopropyl (2-phenylethenylsulfonylmethyl)phosphonate, C(15)H(23)O(5)PS, (I), diisopropyl {[2-(7-methoxy-1,3-benzodioxol-5-yl)ethenylsulfonyl]methylsulfonylmethyl}phosphonate, C(18)H(27)O(10)PS(2), (II), bis(trans-2-phenylethenyl) sulfone, C ...
Jessica H, Wong   +3 more
openaire   +2 more sources

Iron-Catalyzed Fluoroalkylation of Arylborates with Sulfone Reagents: Beyond the Limitation of Reduction Potential.

Angewandte Chemie, 2021
Iron-catalyzed alkyl-aryl coupling reaction between sulfones and arylboron compounds has remained a challenge. We report the first iron-catalyzed radical difluoroalkylation of arylborates with N-heteroaryl sulfones. The coordination between iron catalyst
Zhiqiang Wei, W. Miao, C. Ni, Jinbo Hu
semanticscholar   +1 more source

Sulfone-based high-voltage electrolytes for high energy density rechargeable lithium batteries: Progress and perspective

, 2020
Further enhancement in the energy density of rechargeable lithium batteries calls for high-voltage cathode materials and stable anodes, as well as matched high-voltage electrolytes without compromising the overall property of batteries.
Wen-Ya Wu   +3 more
semanticscholar   +1 more source

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