Results 261 to 270 of about 32,232 (288)
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Journal of Applied Polymer Science, 2000
The sulfonation of polymers and the pervaporation behavior of asymmetric polymeric membranes are described in this study. We confirmed that the sulfonic acid group was successively introduced into the polymer chain by FTIR and 1H-NMR characterization.
I. S. Byun, J. W. Seo, I. C. Kim
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The sulfonation of polymers and the pervaporation behavior of asymmetric polymeric membranes are described in this study. We confirmed that the sulfonic acid group was successively introduced into the polymer chain by FTIR and 1H-NMR characterization.
I. S. Byun, J. W. Seo, I. C. Kim
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Revisit to the sulfonation of pyrroles: is the sulfonation position correct?
Tetrahedron Letters, 2000Abstract Sulfonation of pyrrole and its 1-methyl derivatives with a sulfur trioxide–pyridine complex was found to give 3-sulfonated pyrroles, but not 2-sulfonates as described in textbooks. The replacement of 1-methyl-2-tri-n-butylstannylpyrrole with trimethylsilyl chlorosulfonate, followed by quenching with aq.
Akira Mizuno+6 more
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Israel Journal of Chemistry, 1974
AbstractThe sulfonation of polyamides (Nylons‐3,6,11 and 6,6) was investigated using fuming sulfuric acid and solutions of SO3 in CCl4. The sulfonated polymers were soluble in water and insoluble in ethanol. Acid hydrolysis of the polymers and quantitative determination of the amino acids in the hydrolysate showed the presence of α‐sulfo amino acids ...
Albert Zilkha, Jacob Vaya
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AbstractThe sulfonation of polyamides (Nylons‐3,6,11 and 6,6) was investigated using fuming sulfuric acid and solutions of SO3 in CCl4. The sulfonated polymers were soluble in water and insoluble in ethanol. Acid hydrolysis of the polymers and quantitative determination of the amino acids in the hydrolysate showed the presence of α‐sulfo amino acids ...
Albert Zilkha, Jacob Vaya
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The metabolism of the surfactants dodecyl sulfonate and hexadecyl sulfonate in the rat
Toxicology and Applied Pharmacology, 1978Abstract When [1-14C]dodecyl sulfonate and [1-14C]hexadecyl sulfonate were administered orally and ip to free-ranging rats and iv to anesthetized rats, the major route of excretion of radioactivity was urinary. Small amounts only of parent surfactant appeared in the feces of animals dosed orally with [1-14C]dodecyl sulfonate, but large amounts of [1 ...
Douglas Howes+3 more
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Journal of Membrane Science, 2018
Abstract Composite cation exchange membranes (C-CEMs) based on mainchain sulfonated polyether sulfone (SPES) and polyvinyl pyrrolidone (PVP) have been prepared and the effects of hydrophilicity on C-CEM properties investigated in a previous work. In this study, membrane properties were optimized by investigating the effects of degrees of sulfonation (
Lin Guo, Jianyou Wang, Jinli Zhao
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Abstract Composite cation exchange membranes (C-CEMs) based on mainchain sulfonated polyether sulfone (SPES) and polyvinyl pyrrolidone (PVP) have been prepared and the effects of hydrophilicity on C-CEM properties investigated in a previous work. In this study, membrane properties were optimized by investigating the effects of degrees of sulfonation (
Lin Guo, Jianyou Wang, Jinli Zhao
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The polysulfonylamines bis(methylsulfonamido) sulfone and bis(trifluoromethylsulfonamido) sulfone
Acta Crystallographica Section C Crystal Structure Communications, 2003Bis(methylsulfonamido) sulfone, C(2)H(8)N(2)O(6)S(3) or SO(2)(NHSO(2)CH(3))(2), was synthesized from imidobis(sulfonyl chloride), HN(SO(2)Cl)(2), and bis(trimethylsilyl)methane, CH(2)[Si(CH(3))(3)](2), in chlorotrimethylsilane solution. In the solid state, there are two independent molecules linked by two N-H...O hydrogen bridges into infinite chains ...
Zdirad Žák, Jan Taraba
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1977
Sulfones are compounds in which the sulfur atom is bonded to two carbon atoms and two terminal oxygens in a tetrahedral arrangement, which is easily deformable.1 The sulfonyl moiety probably is a hydrid of the forms shown below ...
Thomas C. Klingler+2 more
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Sulfones are compounds in which the sulfur atom is bonded to two carbon atoms and two terminal oxygens in a tetrahedral arrangement, which is easily deformable.1 The sulfonyl moiety probably is a hydrid of the forms shown below ...
Thomas C. Klingler+2 more
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Journal of the American Oil Chemists' Society, 1952
SummaryPatent and technical literature contain a wide variety of references to sulfation and sulfonation. Many of these relate to methods specific for individual compounds or substituted functional groups, or to involved methods undesirable for commercial plant operation.
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SummaryPatent and technical literature contain a wide variety of references to sulfation and sulfonation. Many of these relate to methods specific for individual compounds or substituted functional groups, or to involved methods undesirable for commercial plant operation.
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Sulfonic Esters of Carbohydrates
1953Publisher Summary This chapter discusses sulfonic esters of carbohydrates. Of the various ways in which sulfonic esters may be synthesized, only two––the use of metallic salts of sulfonic acids and the use of suljonyl halides–– have so far achieved importance in carbohydrate chemistry.
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