Harnessing CO<sub>2</sub> Radical Anion-Mediated Electron Transfer for Scalable Copper-Catalyzed Cross-Coupling. [PDF]
Wu S, Yang CJ, Cheng MJ, Liu W.
europepmc +1 more source
Structural Guidance in 3D Microgel‐in‐Hydrogel Systems to Improve Chondrogenesis
The Anisogel, an anisotropic microgel‐in‐hydrogel system, guides chondrogenic differentiation of human mesenchymal stromal cells (hMSCs) modulated by the alignment and size of anisometric microgels. Chondrogenic markers are upregulated in an in vitro model and guided tissue infiltration is enhanced in a semi‐orthopedic mouse model due to the physico ...
Julia Kamp +12 more
wiley +1 more source
Smiles-Truce Cascades Enable Heteroaryl Cyclopropane and Sultine Synthesis. [PDF]
Sephton T, Liu Z, Greaney MF.
europepmc +1 more source
A weakly solvating fluorinated cosolvent (1200ET) enables precise solvation‐power regulation in Li–S batteries, decoupling interfacial stabilization from sulfur redox kinetics. This approach suppresses polysulfide dissolution while preserving reaction kinetics, leading to a stable Li metal interface and high‐energy multilayer pouch cells, revealing a ...
Huidong Dai +9 more
wiley +1 more source
Covalent drug rescue of multiple p53 mutants by stabilizing vinyl sulfone fragments hints to a specific refolding mechanism for R282W. [PDF]
Stahlecker J +9 more
europepmc +1 more source
Mechanochemistry as an Emerging Tool for Organofluorine Chemistry
Fluorinated scaffolds are central across many areas of chemistry, driving the demand for efficient and sustainable synthetic methods. Mechanochemistry has emerged as a powerful alternative to conventional approaches, offering reduced environmental impact, shorter reaction times, and unique reactivity and selectivity.
Marie Caldiero +3 more
wiley +1 more source
Copper-Mediated Divergent Reactivity of Allene-Tethered Carbamates under Radical Conditions. [PDF]
Toledano-Pinedo M +7 more
europepmc +1 more source
Photothermal Degradation of Pollutants Using a Ag@ZnNP/TiO2 Composite
Sustainable treatment strategies for recalcitrant pollutants remain a critical challenge. In this study, zinc‐silver core–shell TiO2 nanocomposites (Ag@ZnNP/TiO2) were investigated as photothermal materials for the degradation of perfluorooctanoic acid (PFOA) via photothermal sulfate radical formation and fipronil.
Brooke Lawrie +2 more
wiley +1 more source
Desulfinative Cross-Coupling as a Method to Overcome Problematic Suzuki-Miyaura Reactions of Pharmaceutically Relevant Heteroaromatic Boronates. [PDF]
Blakemore DC, Shavnya A, Willis MC.
europepmc +1 more source
This article investigates the metabolism and elimination of flmodafinil and fladrafinil, two fluorinated analogs of modafinil and adrafinil listed as S6 stimulants by the World Anti‐Doping Agency. After single‐dose administration to six volunteers, the compounds and their main metabolites were studied in urine and blood.
O. Krug +6 more
wiley +1 more source

