Results 161 to 170 of about 7,119 (254)
A MgBr2‐catalyzed (3+2) cycloaddition between N‐thioacyl amidines and donor–acceptor cyclopropanes provides rapid access to 2‐amidino‐thiolanes in good yields and with high diastereoselectivities. The method displays broad substrate scope and offers an efficient route to sulfur‐containing amidine scaffolds of potential biological relevance.
Laurine Tual +4 more
wiley +1 more source
A general leaving group assisted strategy for synthesis of pentafluorosulfanyl allylic compounds. [PDF]
Yang HY +8 more
europepmc +1 more source
Selective benzylic alcohol oxidation using hydrogen peroxide (H2O2) is catalyzed by an array of Ti‐silica materials. Sulfolane solvent strongly interacts with the reactant and enhances rates versus acetonitrile solvent in wide pore materials, but negative transport effects dominate in smaller‐pore materials. Partially overcoated catalysts stabilize the
Dian Jing, Justin M. Notestein
wiley +1 more source
Degradation of epoxy thermosets cured by bis(arylamine)s as curing agents proceeded via cleaving carbon−oxygen and −nitrogen main chains. The present conditions were based on the use of NaOH in 1,3‐dimethyl‐2‐imidazolidinone with the assistance of Ca(OH)2 to form core organic substrates in the epoxy monomers and parent curing agents.
Yasunori Minami +3 more
wiley +1 more source
Diastereoselective synthesis of cyclopropyl sulfoxides <i>via</i> hydrosulfenation. [PDF]
Yuwen L +6 more
europepmc +1 more source
Synthetic Strategies for Activity‐Based Probes to Decode Ubiquitin‐Like Modifiers
ABSTRACT Ubiquitin‐like proteins (Ubls) such as SUMO, NEDD8, ISG15, URM1, UFM1, FAT10, ATG8/ATG12, and FUBI are essential regulators of cellular homeostasis, controlling processes from protein stability and trafficking to immune signaling and autophagy.
Saibal Chanda +5 more
wiley +1 more source
Development of Efficient Covalent Inactivators of a Fungal Aspartate Semialdehyde Dehydrogenase. [PDF]
Friday SN +14 more
europepmc +1 more source
Synthesis of the Core Tetracycle of the Spirobiflavonoid Daphnodorin C
Core spirotetracycle of daphnodorin C: Oxidative ring contraction of benzofuro[3,2‐b]chromenones affords novel 2,3′‐spirobi[benzofuran]diones, rather than the isomeric spiroketals. The first synthesis of the spirobi[benzofuran]dione core structure of the spirobiflavonoid daphnodorin C is described.
Lukas Heemann +2 more
wiley +1 more source
A series of structurally diverse exoglycals was synthesized using a modified Julia‐olefination approach from sugar‐derived precursors. These glycosidase transition‐state mimics were further diversified via CuAAC chemistry to yield triazole‐conjugated analogues.
Elisa Ospanow +2 more
wiley +1 more source

