Results 41 to 50 of about 12,336 (293)

Homogenous FACsPbI3 Perovskite Solar Cells Enabled by a Seed‐Facilitated Cation Exchange Strategy

open access: yesAdvanced Functional Materials, EarlyView.
A novel seed‐facilitated cation exchange strategy is designed for homogenous FACsPbI3 perovskites using the biomass‐derived solvent γ‐valerolactone. Pre‐deposited 0D Cs4PbI6 seeds induce rapid nucleation and efficient cation exchange, producing a uniform FA–Cs distribution and significantly reducing defect density, enabling high‐performance and stable ...
Meng Ren   +10 more
wiley   +1 more source

Dioxygen-Triggered Oxosulfonylation/Sulfonylation of Terminal Olefins toward Keto Sulfones/Sulfones

open access: yes, 2021
A dioxygen-triggered oxosulfonylation/sulfonylation of unactivated olefins to achieve β-keto sulfones/sulfones has been developed. Interestingly, pluralistic mechanisms were found when different types of compounds were applied as substrates, and ...
Changqun Cai   +9 more
core   +1 more source

Engineering Pendant Group Chemistry to Control Hydrophilicity and Oxidative Degradation of Thioketal‐Based Biomaterials

open access: yesAdvanced Functional Materials, EarlyView.
Thioketal (TK) polymers are promising biomaterials due to their selective biodegradation by reactive oxygen species (ROS), but they respond slowly to physiologic doses of ROS. Here, the TK bond's pendant groups are modified to enhance the degradation of TK‐based implants both in vitro and in vivo.
Karina A. Bruce   +6 more
wiley   +1 more source

Synthesis and Reactions of 2-Chlorovinyl Sulfones

open access: yes, 2011
Synthesis and Reactions of 2-Chlorovinyl Sulfones Methods for the preparation of unsubstituted (E)-2-chlorovinyl sulfo-nes are reviewed. Literature data on substitution of chlorine atom in 2-chlorovinyl sulfones leading to formation of different ...
E. Ābele, J. Višņevska
core   +1 more source

Microfabricated Anisotropic Myobundles for the Scalable Production of Cardiac Tissue Grafts

open access: yesAdvanced Functional Materials, EarlyView.
Controlling the anisotropy of cardiac tissue remains an outstanding challenge in the field of cardiac tissue engineering. Here, we introduce an approach to generate anisotropic cardiac myobundles using cell‐adhesive, synthetic, electrospun fibers and stem cell‐derived cardiac fibroblasts.
Maggie E. Jewett   +15 more
wiley   +1 more source

Sustainable and versatile selective oxidation of sulfides to sulfones in deep eutectic solvent

open access: yesCurrent Research in Green and Sustainable Chemistry
Deep eutectic solvents (DES) have emerged as a promising class of solvents that offer unique properties and applications in various fields. The oxidation of sulfide with readily available oxidants remains a major challenge.
Fatemeh Armandsefat   +3 more
doaj   +1 more source

Membrane-free selective oxidation of thioethers with water over a nickel phosphide nanocube electrode

open access: yesCell Reports Physical Science, 2021
Summary: Developing a membrane-free oxidation reaction, especially using water as the oxygen source, to generate high-value chemicals with high selectivity for replacing low-value O2 over a cost-effective catalyst is significant.
Shuyan Han   +6 more
doaj   +1 more source

Development of a Synthetic Hydrogel to Foster Microvascularization of an Endometriosis Microphysiological System

open access: yesAdvanced Healthcare Materials, EarlyView.
ABSTRACT The ascent of novel alternative methods in drug development spotlights the dual needs for improved biological fidelity to in vivo, along with reproducibility, especially in regulatory applications. The need for pre‐clinical models of patient‐derived endometriosis lesions motivates the development of a vascularizable, completely synthetic ...
Lauren Pruett   +7 more
wiley   +1 more source

Regioselective synthesis of chiral dimethyl-bis(ethylenedithio)tetrathiafulvalene sulfones

open access: yesBeilstein Journal of Organic Chemistry, 2015
Enantiopure (R,R) and (S,S)-dimethyl-bis(ethylenedithio)tetrathiafulvalene monosulfones have been synthesized by the aerial oxidation of the chiral dithiolates generated from the propionitrile-protected precursors.
Flavia Pop, Narcis Avarvari
doaj   +1 more source

Aptamer‐Based Delivery Systems for VEGF and NGF Modulation in Ocular Therapies

open access: yesAdvanced Healthcare Materials, EarlyView.
Aptamer‐based delivery systems targeting NGF and VEGF hold significant potential for precise and sustained treatment of complex diseases affecting both the anterior and posterior segments of the eye. This review critically summarizes current strategies for NGF and VEGF delivery as well as VEGF sequestration, providing a clinical perspective on how ...
Nadine Best   +5 more
wiley   +1 more source

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