Results 51 to 60 of about 7,119 (254)

Harnessing Li‐Ion Binding Energy for Solvation‐Guided Electrolyte Additive Design and Robust Solid Electrolyte Interphase Reinforcement

Advanced Science, EarlyView.
A solvation‐guided design strategy for electrolyte additives is established, identifying Li‐ion binding energy as a crucial determinant for effective interface reinforcement. ABSTRACT The rational design of electrolyte systems is essential for stabilizing the electrode−electrolyte interface to enhance the electrochemical performance of lithium‐ion ...
Jooeun Byun, Ho Yeon Jang, Myung‐Jun Kwak, Chae Rim Lee, Chihyun Hwang, Seoin Back, Hyun‐seung Kim   +6 more
wiley   +1 more source

Synthesis of ω-Methylsulfinyl- and ω-Methylsulfonylalkyl Glucosinolates

Molecules
General pathways were devised to synthesize ω-methylsulfinyl- and ω-methylsulfonylalkyl glucosinolates, which represent an important class of structurally homogeneous plant specialized metabolites.
Manolis Mavratzotis, Stéphanie Cassel, Gina Rosalinda De Nicola, Sabine Montaut, Patrick Rollin   +4 more
doaj   +1 more source

Two-Step Azidoalkenylation of Terminal Alkenes Using Iodomethyl Sulfones

Molecules, 2019
The radical azidoalkylation of alkenes that was initially developed with α-iodoesters and α-iodoketones was extended to other activated iodomethyl derivatives.
Nicolas Millius, Guillaume Lapointe, Philippe Renaud   +2 more
doaj   +1 more source

Comparative Insights and Overlooked Factors of Interphase Chemistry in Alkali Metal‐Ion Batteries

Advanced Energy Materials, EarlyView.
This review presents a comparative analysis of Li‐, Na‐, and K‐ion batteries, focusing on the critical role of electrode–electrolyte interphases. It especially highlights overlooked aspects such as SEI/CEI misconceptions, binder effects, and self‐discharge relevance, emphasizing the limitations of current understanding and offering strategies for ...
Changhee Lee, Zachary T. Gossage, Shinichi Kumakura, Shinichi Komaba   +3 more
wiley   +1 more source

Tailoring High‐Valent Iron‐Oxo Species Redox via Extended π‐Fe3d–O2p Orbital Overlapping Toward Chemical‐Efficient Water Purification

Angewandte Chemie, EarlyView.
We address the long‐standing challenge of reactivity–selectivity trade‐off by precisely tuning the redox properties of Fe(IV), rather than simply accelerating its formation, to enable chemically efficient and low‐emission water treatment. ABSTRACT High‐valent iron oxo species (Fe(IV)) are attractive for wastewater treatment because of their high ...
Hongyu Zhou, Junwen Chen, Jiuyi Wang, Xinhao Wang, Qiming Zhang, Shiying Ren, Xuning Li, Li Gao, Shaobin Wang, Xiaoguang Duan   +9 more
wiley   +2 more sources

Desulfurization of Dibenzothiophene and Oxidized Dibenzothiophene Ring Systems

Molecules, 2010
Lithium, used in conjunction with sodium metal, produces a high yield of biphenyl when reacted with dibenzothiophene, dibenzothiophene sulfoxide or dibenzothiophene sulfone.
Diego P. Morales, Alexander S. Taylor, Steven C. Farmer   +2 more
doaj   +1 more source

Chiral Molecular Configuration‐Mediated Crystallization of Perovskites for High‐Performance Solar Cells

Advanced Energy Materials, EarlyView.
In this work, we propose a chiral stereo‐anchoring strategy to modulate the colloidal evolution and crystallization behavior of FAPbI3 perovskites via stereochemical molecular design, which effectively regulates nucleation kinetics and promotes ordered crystal growth.
Runkang Wang, Yujie Zhu, Jiaxue You, Yunfan Wang, Jiarong Wu, Jinghao Ge, Pengda Tong, Shilong Jia, Xiaogang Wang, Yiran Tao, Hao‐Chung Kuo, Adel Najar, Lu Zhang, Yuanhao Gong, Shengzhong (Frank) Liu   +14 more
wiley   +1 more source

Flavin Catalysts in Organic Synthesis

Angewandte Chemie, EarlyView.
Flavins and their congeners are potent catalysts for organic synthesis inspired by enzymatic transformations. In addition to catalysis in the flavin ground state via covalent intermediates, the excited singlet and triplet states unlock applications including photooxidation, photoreduction, and energy transfer via sensitization.
Jan Freudenberg, Golo Storch
wiley   +2 more sources

Synthesis and Promising in Vitro Antiproliferative Activity of Sulfones of a 5-Nitrothiazole Series

Molecules, 2012
 The synthesis in water of new sulfone derivatives under microwave irradiation is described. This eco-friendly process leads to the expected products in good yields by reaction of various substituted sulfinates (commercially available or ...
Nadine Azas, Patrice Vanelle, Pascal Rathelot, Maxime D. Crozet, Anita Cohen   +4 more
doaj   +1 more source

Multiscale Design of Anion Exchange Membrane‐Based Seawater Electrolysis for Sustainable Hydrogen Production

Advanced Energy Materials, EarlyView.
Direct seawater electrolysis using anion exchange membranes is emerging as a promising route for sustainable hydrogen production. This review summarizes multiscale design strategies from seawater chemistry and OER–ClER selectivity to catalysts, membranes, MEAs, cells, stacks, and system integration, providing a roadmap toward selective, durable, and ...
Chiho Kim, Geunhee Yuk, Jong‐Hyeok Park, Shin‐woo Myeong, Jun Seok Ha, Won Tae Hong, Jung Kyu Kim, Sung Mook Choi   +7 more
wiley   +1 more source