Crystal structure of (2R*,3aR*)-2-phenylsulfonyl-2,3,3a,4,5,6-hexahydropyrrolo[1,2-b]isoxazole
Acta Crystallographica Section E: Crystallographic Communications, 2017 The title compound, C12H15NO3S, was prepared by 1,3-dipolar cycloaddition of 3,4-dihydro-2H-pyrrole 1-oxide and phenyl vinyl sulfone. In the molecule, both fused five-membered rings display a twisted conformation.
Yaiza Hernández +4 more
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(4-Nitrophenylsulfanylmethyl)triphenylstannane and (4-nitrophenylsulfonylmethyl)triphenylstannane: R22(X) rings (X is 10, 18 or 24) and C-H...p interactions [PDF]
, 2002 Peer reviewedPublisher ...
Skakle, Jan +2 more
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Advanced Materials, EarlyView.The perspective presents an integrated view of neuromorphic technologies, from device physics to real‐time applicability, while highlighting the necessity of full‐stack co‐optimization. By outlining practical hardware‐level strategies to exploit device behavior and mitigate non‐idealities, it shows pathways for building efficient, scalable, and ...
Kapil Bhardwaj +8 more
wiley +1 more source
Synthesis of ω-Methylsulfinyl- and ω-Methylsulfonylalkyl Glucosinolates
MoleculesGeneral pathways were devised to synthesize ω-methylsulfinyl- and ω-methylsulfonylalkyl glucosinolates, which represent an important class of structurally homogeneous plant specialized metabolites.
Manolis Mavratzotis +4 more
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Synthesis of New Active Sulfones in the 5-Nitroimidazole Series
Molecules, 2002 We describe here the preparation of new 5-nitroimidazoles which are known to have an efficacy against metronidazole-susceptible and -resistant Giarda, Trichomonas, and Entamoeba spp. The multi-step synthesis uses electron transfer methodology.
Patrice Vanelle +2 more
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Direct C–H-sulfonylation of 6-membered nitrogen-heteroaromatics
Tetrahedron Chem, 2022 Heterocyclic sulfones and sulfonamides represent important structural motives in medicinal chemistry and drug development. Therefore, efficient and reliable methods for their construction from simple building blocks are in high demand. Herein we report a
Marius Friedrich +6 more
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Advanced Materials, EarlyView.Micropollutants can act as molecular triggers that activate a newly designed and chemically inert Fenton‐like PKU‐24 catalyst for on‐demand singlet oxygen generation from peroxymonosulfate (PMS), enabling nearly complete peroxide utilization and selective micropollutant removal from complex real‐world wastewater.
Yu‐Hang Li +7 more
wiley +1 more source
Donor–Acceptor Pentacene Analogues With Near‐Infrared Emission and Tunable Aromaticity
Angewandte Chemie, EarlyView.Air‐ and photostable heterocyclic pentacene analogues with donor and acceptor groups flanking a para‐quinodimethane core exhibit large dipole moments, narrow bandgaps, reversible redox behavior, and NIR‐I to NIR‐II absorption and emission with pronounced solvatochromism.
Krzysztof Nowak +6 more
wiley +2 more sources
Two-Step Azidoalkenylation of Terminal Alkenes Using Iodomethyl Sulfones
Molecules, 2019 The radical azidoalkylation of alkenes that was initially developed with α-iodoesters and α-iodoketones was extended to other activated iodomethyl derivatives.
Nicolas Millius +2 more
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Combating the Stigmatization of Leprosy: How the first decade of The Star’s publication made the case for romantic relationships and the preservation of domestic life in the Carville Leprosarium [PDF]
, 2013 The stigmatization of leprosy has long been acknowledged as one of the primary obstacles to not only effectively treating leprous patients on a physical level, but also achieving their integration and acceptance into society.
Reed, Gabriela
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