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Antifouling Surfaces Enabled by Surface Grafting of Highly Hydrophilic Sulfoxide Polymer Brushes.

Biomacromolecules, 2020
Antifouling surfaces are important in a broad range of applications. An effective approach to antifouling surfaces is to covalently attach antifouling polymer brushes. This work reports the synthesis of a new class of antifouling polymer brushes based on
Xin Xu   +12 more
semanticscholar   +1 more source

Potential Explosion Hazards Associated with the Autocatalytic Thermal Decomposition of Dimethyl Sulfoxide and Its Mixtures

, 2020
Dimethyl sulfoxide (DMSO) is widely used as a solvent for chemical reactions, as a cosolvent for crop protection formulations, and in medicines for topical administration of drugs.
Qiang Yang   +7 more
semanticscholar   +1 more source

Cyclometalated Ir-Zr-MOFs as Recyclable Visible-Light Photocatalysts for Sulfide Oxidation into Sulfoxide in Water.

ACS Applied Materials and Interfaces, 2019
Aerobic photo-oxidation of sulfide into sulfoxide in water is of great interest in synthesis chemistry. In this study, three high stable Ir(III)-Zr(IV) metal-organic frameworks (Ir-Zr-MOFs), namely Zr6-Irbpy (bpy is 2,2'-bipyridine), Zr6-IrbpyOMe (bpyOMe
Lianqiang Wei, B. Ye
semanticscholar   +1 more source

The Solvent Dimethyl Sulfoxide [PDF]

open access: possibleAngewandte Chemie International Edition in English, 1967
AbstractThe dipolar aprotic solvent dimethyl sulfoxide is liquid over a wide range of temperatures, is a strong electron donor, and has a high polarity. It is therefore an excellent and selective solvent for many organic and even polymeric compounds, and can enter into H‐bonding and dipole‐dipole association. The structure of dimethyl sulfoxide, with a
D. Martin, H.-J. Niclas, A. Weise
openaire   +2 more sources

Recent Advances in the Use of Dimethyl Sulfoxide as a Synthon in Organic Chemistry

Topics in current chemistry, 2022
Hao Lu   +6 more
semanticscholar   +1 more source

Oxidation of 2-chloroethyl sulfides to sulfoxides by dimethyl sulfoxide

The Journal of Organic Chemistry, 1990
Abstract2‐Chloroethyl sulfides such as (I) are oxidized with DMSO, forming the sulfoxides (III) and (IV).
Linda L. Szafraniec   +3 more
openaire   +3 more sources

Deoxygenation of sulfoxides

Research on Chemical Intermediates, 2017
Organic sulfides are of great importance as efficient intermediates for the synthesis of a diverse range of biological, pharmaceutical and natural active molecules as well as valuable synthetic compounds. The deoxygenation of sulfoxides to their corresponding sulfides is among one of the most fundamental processes and transformations in organic ...
Mosstafa Kazemi, Lotfi Shiri
openaire   +2 more sources

ChemInform Abstract: Reaction of Arynes with Sulfoxides.

ChemInform, 2015
A S-O bond insertion reaction of sulfoxides with arynes is reported. This reaction represents a rare instance of semipolar single bond insertion in aryne chemistry. The study of mechanism indicates that a sulfur ylide triggered by aryne is the key intermediate, which further transfers its methylene group to carbonyl compounds to give epoxides and ...
Bin Wang   +5 more
openaire   +4 more sources

Aldicarb (Sulfoxide and Sulfone) [PDF]

open access: possible, 1988
Aldicarb (2-methyl-2-(methylthio) propanal O-[(methylamino) carbonyl] oxime) with the trade name Temik®, is an insecticide, nematicide, and acaricide. Estimated aldicarb production was 3.0 to 4.7 million lb (1.4 to 2.1 million kg)/yr during 1979 to 1981. It is applied both to the soil and directly to plants.
openaire   +2 more sources

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