Results 21 to 30 of about 15,552 (245)

Constraining the rise of oxygen with oxygen isotopes

open access: yesNature Communications, 2019
The loss of anomalous sulfur isotope compositions from sedimentary rocks has been considered a symptom of permanent atmospheric oxygenation. Here the authors show sulfur and oxygen isotope evidence from 
B. A. Killingsworth   +5 more
doaj   +1 more source

The Biogeochemical Sulfur Cycle of Marine Sediments

open access: yesFrontiers in Microbiology, 2019
Microbial dissimilatory sulfate reduction to sulfide is a predominant terminal pathway of organic matter mineralization in the anoxic seabed. Chemical or microbial oxidation of the produced sulfide establishes a complex network of pathways in the sulfur ...
Bo Barker Jørgensen   +2 more
doaj   +1 more source

Analysis of Sulfur Isotope Composition of Gypsum Samples by Elemental Analyzer-Isotope Mass Spectrometry

open access: yesYankuang ceshi, 2020
BACKGROUND The conventional method for the measurement of sulfur isotopes in sulfate includes mainly barite conversion coupled with dual-inlet SO2 methods. These methods are facile and reliable.
GAO Jian-fei   +4 more
doaj   +1 more source

Multiple-sulfur isotope effects during photolysis of carbonyl sulfide [PDF]

open access: yesAtmospheric Chemistry and Physics, 2011
Laboratory experiments were carried out to determine sulfur isotope effects during ultraviolet photolysis of carbonyl sulfide (OCS) to carbon monoxide (CO) and elemental sulfur (S<sup>0</sup>).
Y. Lin, M. S. Sim, S. Ono
doaj   +1 more source

Organosulfur Aerosols Likely Carried Sulfur MIF Signatures in the Early Earth’s Atmosphere

open access: yesGeochemistry, Geophysics, Geosystems, 2023
Signatures of mass‐independent fractionation (MIF) of sulfur in Archean sulfide and sulfate minerals are widely thought to record an anoxic early Earth’s atmosphere.
Harry Oduro   +3 more
doaj   +1 more source

Influence of Phosphorus and Cell Geometry on the Fractionation of Sulfur Isotopes by Several Species of Desulfovibrio during Microbial Sulfate Reduction

open access: yesFrontiers in Microbiology, 2017
We investigated the influence of organic substrates and phosphate concentration on the rates of dissimilatory microbial sulfate reduction and the 34S/32S isotopic fractionation produced by several Desulfovibrio species.
Shikma Zaarur   +3 more
doaj   +1 more source

Sulfur isotopes in coal constrain the evolution of the Phanerozoic sulfur cycle [PDF]

open access: yesProceedings of the National Academy of Sciences, 2013
Sulfate is the second most abundant anion (behind chloride) in modern seawater, and its cycling is intimately coupled to the cycling of organic matter and oxygen at the Earth’s surface. For example, the reduction of sulfide by microbes oxidizes vast amounts of organic carbon and the subsequent reaction of sulfide with iron produces pyrite whose burial ...
Canfield, D.E.
openaire   +3 more sources

Ultrafast Thermal Shock Synthesis of CuNiSnLa Medium‐Entropy Metallic Glass for Sustainable Nitrogen Fixation via Plasma‐Coupled Electrocatalysis

open access: yesAdvanced Functional Materials, EarlyView.
This work introduces an ultrafast thermal shock strategy to synthesize a CuNiSnLa medium‐entropy metallic glass (MEMG). The rapid heating and cooling process generates a robust, highly active catalyst for electrocatalytic nitrate reduction to ammonia (NRA).
Hongbo Chen   +7 more
wiley   +1 more source

Sulfur‐Free Ultrahigh‐Refractive‐Index Polymers Enabled by Densely Packed Oxygen‐Bridged Dibenzofuran‐Cardo Architectures

open access: yesAdvanced Functional Materials, EarlyView.
A new class of sulfur‐free, oxygen‐bridged dibenzofuran‐based polymers is developed for ultrahigh‐refractive‐index applications. The rigid π‐extended architecture and enhanced molecular polarizability enable exceptional optical performance, combining refractive indices up to 1.848 with high Abbe numbers and full visible transparency. This work offers a
Hend A. Hegazy   +5 more
wiley   +1 more source

A Critical Look at the Combined Use of Sulfur and Oxygen Isotopes to Study Microbial Metabolisms in Methane-Rich Environments

open access: yesFrontiers in Microbiology, 2018
Separating the contributions of anaerobic oxidation of methane and organoclastic sulfate reduction in the overall sedimentary sulfur cycle of marine sediments has benefited from advances in isotope biogeochemistry.
Gilad Antler   +3 more
doaj   +1 more source

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