Results 111 to 120 of about 392 (208)

Synthesis and One‐Electron Reduction of Donor‐Acceptor‐Stabilized SiII–EII–SiII Trimetallylenes (E = Ge, Sn, Pb)

open access: yesAngewandte Chemie, EarlyView.
The first isolable trimetallylenes (SiII)2EII (E = Ge, Sn, Pb) with pπ‐type silanylidenyl donors have been synthesized, having donor–acceptor electronic structures that give rise to near‐infrared absorption and enable access to bis(silanylidenyl)‐supported GeI and SnI radical anions upon one‐electron reduction with elemental potassium. ABSTRACT Herein,
Chaopeng Hu   +3 more
wiley   +2 more sources

N‐Alkoxysulfurdiimide Reagents for the One‐Step Modular Synthesis of Primary Sulfonimidamides

open access: yesAngewandte Chemie, EarlyView.
N‐Alkoxysulfurdiimide reagents when combined with organometallic reagents lead directly to primary sulfonimidamide products. The reactions are broad in scope, encompassing aryl, heteroaryl, and alkyl carbon substituents. The reactivity of the N‐alkoxysulfurdiimide reagents can be correlated with the electron‐withdrawing ability of the N‐substituent ...
Suzanne E. Davison   +6 more
wiley   +2 more sources

A Comparative Study of Cabernet Sauvignon Red Wine Aroma Profiles During Ageing in Medium-Toasted Oak Barrels. [PDF]

open access: yesFoods
Pichler A   +7 more
europepmc   +1 more source

An NHC‐Coordinated Silicon/Sulfur Analogue of an Acyl Carbene

open access: yesAngewandte Chemie, EarlyView.
An NHC complex of an Si/S analogue of an acyl carbene is synthesized by the reaction of a disilyne with a cyclic thiourea. The observed Si2S three‐membered ring with unsymmetrical Si─S distances and a Si─Si single bond is consistent with intramolecular coordination of the silathioacyl sulfur to the silylene center.
Takuto Toyooka   +2 more
wiley   +2 more sources

Bottlebrush Polyolefin Sulfones as Triggerable and Degradable Pressure‐Sensitive Adhesives

open access: yesAngewandte Chemie, EarlyView.
A grafting‐through alternating copolymerization strategy yields poly(norbornene sulfone) bottlebrush polymers with high molar mass. These materials function as additive‐free pressure‐sensitive adhesives. The incorporation of cleavable sulfone units enables rapid breakdown under mild alkaline conditions, providing a pathway toward sustainable, high ...
Clark Vu   +5 more
wiley   +2 more sources

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