The first isolable trimetallylenes (SiII)2EII (E = Ge, Sn, Pb) with pπ‐type silanylidenyl donors have been synthesized, having donor–acceptor electronic structures that give rise to near‐infrared absorption and enable access to bis(silanylidenyl)‐supported GeI and SnI radical anions upon one‐electron reduction with elemental potassium. ABSTRACT Herein,
Chaopeng Hu +3 more
wiley +2 more sources
Pathophysiological Mechanisms and Nonpharmacological Interventions in Irritable Bowel Syndrome: Current Insights and Future Directions. [PDF]
Cheung SLY, Kenway LC.
europepmc +1 more source
Correlation between microbial community and flavour formation in dry-cured squid analysed by next-generation sequencing and molecular sensory analysis. [PDF]
Zhao D, Hu J, Zhou X, Chen W.
europepmc +1 more source
N‐Alkoxysulfurdiimide Reagents for the One‐Step Modular Synthesis of Primary Sulfonimidamides
N‐Alkoxysulfurdiimide reagents when combined with organometallic reagents lead directly to primary sulfonimidamide products. The reactions are broad in scope, encompassing aryl, heteroaryl, and alkyl carbon substituents. The reactivity of the N‐alkoxysulfurdiimide reagents can be correlated with the electron‐withdrawing ability of the N‐substituent ...
Suzanne E. Davison +6 more
wiley +2 more sources
A Comparative Study of Cabernet Sauvignon Red Wine Aroma Profiles During Ageing in Medium-Toasted Oak Barrels. [PDF]
Pichler A +7 more
europepmc +1 more source
An NHC‐Coordinated Silicon/Sulfur Analogue of an Acyl Carbene
An NHC complex of an Si/S analogue of an acyl carbene is synthesized by the reaction of a disilyne with a cyclic thiourea. The observed Si2S three‐membered ring with unsymmetrical Si─S distances and a Si─Si single bond is consistent with intramolecular coordination of the silathioacyl sulfur to the silylene center.
Takuto Toyooka +2 more
wiley +2 more sources
Acylamino acid-releasing enzyme, a bifunctional protease with a potential role in aging. [PDF]
Hoernstein SNW, Miniera AA, Reski R.
europepmc +1 more source
Bottlebrush Polyolefin Sulfones as Triggerable and Degradable Pressure‐Sensitive Adhesives
A grafting‐through alternating copolymerization strategy yields poly(norbornene sulfone) bottlebrush polymers with high molar mass. These materials function as additive‐free pressure‐sensitive adhesives. The incorporation of cleavable sulfone units enables rapid breakdown under mild alkaline conditions, providing a pathway toward sustainable, high ...
Clark Vu +5 more
wiley +2 more sources
The Chemistry and Thermodynamics of Point Source CO<sub>2</sub> Capture by Liquid Chemical Absorption and Its Impact on Process Performance. [PDF]
Puxty G, Maeder M, Moore T.
europepmc +1 more source
Tracing the evolutionary pathway: on the origin of mitochondria and eukaryogenesis. [PDF]
Bravo-Arévalo JE.
europepmc +1 more source

