Results 71 to 80 of about 23,412 (269)

Methods for synthesizing diethyl carbonate from ethanol and supercritical carbon dioxide by one-pot or two-step reactions in the presence of potassium carbonate [PDF]

open access: yes, 2009
Carbon dioxide sequestration was studied by synthesizing diethyl carbonate (DEC) from ethanol and CO2 under supercritical conditions in the presence of potassium carbonate as a base. The co-reagent was ethyl iodide or a concentrated strong acid.
Thiebaud-Roux, Sophie   +3 more
core   +1 more source

Spouted bed drying parameters and adjuvant effects on polyphenol retention and antioxidant activity in mango peel powders

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Spouted bed drying of mango peels with colloidal SiO2 and corn starch produces a free‐flowing powder with reduced agglomeration, increased drying yield, and preserved antioxidant and polyphenol content. Abstract The production of polyphenol‐rich powders is a promising strategy for valorizing agro‐industrial byproducts. This study evaluated drying yield,
Guilherme Henrique Alves Pinto   +3 more
wiley   +1 more source

Electrocarboxylation in supercritical CO2 and CO2-expanded liquids [PDF]

open access: yes, 2008
In this study, the electrocarboxylation of benzyl chloride in pressurized CO2, or pressurized mixtures of dimethylformamide (DMF) and CO2, was investigated in order to synthesize phenylacetic acid.
Cognet, Patrick   +3 more
core   +1 more source

Sustainable Hydrogen Production by Glycerol and Monosaccharides Catalytic Acceptorless Dehydrogenation (AD) in Homogeneous Phase

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
Sustainable hydrogen production can be obtained from hydogen‐rich biomass‐derived organic molecules through Acceptorless Dehydrogenation (AD) reactions. Glycerol and sugars are available in large quantities from industry and can be successfully used as substrates in AD protocols, in the presence of tailored, selective, easily tunable and thermally ...
Sylwia Kostera, Luca Gonsalvi
wiley   +1 more source

Synthesis of Amides and Lactams in Supercritical Carbon Dioxide [PDF]

open access: yesThe Journal of Organic Chemistry, 2009
Supercritical carbon dioxide can be employed as an environmentally friendly alternative to conventional organic solvents for the synthesis of a variety of carboxylic amides. The addition of amines to ketenes generated in situ via the retro-ene reaction of alkynyl ethers provides amides in good yield, in many cases with ethylene or isobutylene as the ...
Mak, Xiao Yin   +4 more
openaire   +3 more sources

Learning Strategies from Nature's Blueprint to Cyclic Carbonate Synthesis

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
The development of sustainable synthetic methods for cyclic carbonates draws inspiration from nature, focusing on eco‐friendly processes and renewable resources like CO2 and biomass. This review explore various CO2 activation mechanisms, green chemistry principles, and green catalysts.
Erika Saccullo   +4 more
wiley   +1 more source

High-temperature corrosion resistance of nickel-base alloy 617 in supercritical carbon dioxide environment

open access: yesMaterials Research Express, 2020
Corrosion behavior of Inconel 617 in supercritical carbon dioxide at 650 °C and 15 MPa for 1000 h was investigated. X-ray diffraction, high-resolution transmission microscopy, and Raman spectrum were used to observe and analyze the corrosion products ...
Zhiyuan Liang, Yong Gui, Qinxin Zhao
doaj   +1 more source

Solubility of lumiracoxib in supercritical carbon dioxide

open access: yesScientific Reports
AbstractThis study aims to use a static-based solubility method for measuring the solubility of lumiracoxib at a temperature of 308–338 K and pressure of 120–400 bar for the first time. The obtained solubility data for lumiracoxib is between 4.74 × 10−5 and 3.46 × 10−4 (mole fraction) for the studied ranges of pressure and temperature.
Firas H. Albadran   +4 more
openaire   +3 more sources

Circular and Bio‐Sourced Polymers for Energy Applications: Natural Feedstocks, Recycling, and Upcycling Routes

open access: yesEcoEnergy, EarlyView.
This review provides a critical comparative analysis of circular and bio‐sourced polymers for energy storage, systematically evaluating natural feedstocks alongside recycling and upcycling strategies for battery components. Key structure–property–performance relationships and inherent trade‐offs between sustainability metrics and electrochemical ...
Priyank Sinha   +3 more
wiley   +1 more source

The realities of storing carbon dioxide - A response to CO2 storage capacity issues raised by Ehlig-Economides & Economides

open access: yes, 2010
In a recent publication, Ehlig-Economides & Economides (2010) have sought to demonstrate that carbon dioxide capture and storage (CCS) is not technically or economically feasible, based on a supposed lack of underground storage capacity. We consider
Graeme Sweeney   +11 more
core   +1 more source

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