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Stress and strain during supercritical drying

Journal of Sol-Gel Science and Technology, 2018
Supercritical drying avoids capillary forces, but damaging stresses can be generated during solvent exchange, pressurization, and depressurization. Each of those steps has been analyzed, so the duration of the process can be minimized without risk to the sample.
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Drying of silica aerogel with supercritical carbon dioxide

Journal of Non-Crystalline Solids, 1995
For applications of monolithic silica aerogels, drying without cracking is an important issue. By extracting alcohol with supercritical CO2, crack-free aerogels can be obtained at 35°C and 85 bar. This opens the possibility for a large-scale aerogel drying process.
M.J. van Bommel, A.B. de Haan
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Stress development during supercritical drying

Journal of Non-Crystalline Solids, 1992
Although supercritical drying eliminates the capillary stresses that cause damage during conventional drying, there are other sources of stress and strain that can destroy aerogels. During heating in the autoclave, expansion of the pore liquid causes dilatation of the gel network.
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Supercritical CO2 Drying of Red Bell Pepper

Food and Bioprocess Technology, 2020
Supercritical CO2 food drying technique was investigated on red bell pepper with a lab-scale reactor equipped with CO2 recirculation. Box–Behnken design was used as experimental design to analyze the impact of temperature (313–333 K), pressure (10–14 MPa), CO2 flow rate (80–220 kg/h), and treatment time (6 and 16 h) on the final water activity.
Zambon A.   +5 more
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Preparation of silica-based aerogels by supercritical drying

Russian Journal of Physical Chemistry B, 2014
A technique to improve the environmental friendliness of the preparation of aerogels has been proposed; an experimental setup for supercritical drying of aerogels has been designed. The results of the examination of the aerogels prepared by the proposed technique have been described.
N. V. Men’shutina   +2 more
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Drying of Coals by Using Supercritical Carbon Dioxide

Industrial & Engineering Chemistry Research, 1998
Drying of three types of coals (Witbank coal, Taiheiyo coal, and Brau coal) was carried out by using supercritical carbon dioxide at 313.2 K and 14.8 MPa. Further, other adsorbent samples (wet zeolite and wet activated carbon) were adopted for comparison.
Yoshio Iwai   +4 more
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Supercritical drying with zeolite for the preparation of silica aerogels

Journal of Non-Crystalline Solids, 1998
Adding zeolite during supercritical drying (SCD) process (methanol) when preparing silica aerogel was effective to make an aerogel with less shrinkage and without cracking. Silica aerogels prepared by adding zeolite had higher densities, despite less shrinkage, than those prepared without zeolite.
S. Yoda, S. Ohshima, F. Ikazaki
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Carotenoids microencapsulation by spray drying method and supercritical micronization

Food Research International, 2017
Carotenoids are used as natural food colourants in the food industry. As unstable natural pigments they need protection. This protection can involve the microencapsulation process. There are numerous techniques that can be used for carotenoid protection, but two of them -spray drying and supercritical micronization - are currently the most commonly ...
openaire   +2 more sources

Stress formation during heating in supercritical drying

Journal of Non-Crystalline Solids, 2001
Silica aerogel preparation is analyzed and two different supercritical drying techniques, autoclave drying of the solvent and drying following carbon dioxide exchange of the solvent, are compared in terms of stress formation during the heating step. The model used is a partial differential equation that relates stress to thermal expansion and flow of ...
Betul Unlusu   +2 more
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Building dry powder formulations using supercritical CO2 spray drying

Current Opinion in Green and Sustainable Chemistry, 2017
This short review covers the most recent literature on the bottom-up assembling of composite dry powder formulations using supercritical carbon dioxide (scCO2)-based technologies for pulmonary delivery. Special attention is given to the integration of scCO2–assisted spray drying (SASD) with different technologies, namely living polymerization, layer-by-
openaire   +1 more source

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