Results 21 to 30 of about 15,769 (260)

A review of retention mechanism studies for packed column supercritical fluid chromatography

Analytical Science Advances, 2021
The packed column supercritical fluid chromatography has risen as a promising alternative separation technique to the conventional liquid chromatography and gas chromatography.
Le Si‐Hung, Takeshi Bamba
doaj   +1 more source

Inhibitory Decay and Supercritical Brain Dynamics During Sleep Deprivation

Advanced Science, EarlyView.
Sleep deprivation progressively shifts human brain dynamics from near‐critical toward supercritical states, as revealed by neuronal avalanche analysis of resting‐state fMRI. These changes track subjective sleep pressure rather than vigilance lapses and show marked network heterogeneity. A circuit model suggests that reduced inhibitory efficacy provides
Dai Zhang, Liqin Zhou, Rong Wang, Yuehua Han, Zhentao Zuo, Yanghua Tian, Ke Zhou   +6 more
wiley   +1 more source

A Strong Lewis Acidic Diethylsilylium Catalyst for Direct Sulfonamidation of Challenging Ketones

Advanced Science, EarlyView.
Low‐substitution‐order silylium ions (R2HSi+) exhibit exceptional Lewis acidic activity. We report diethylsilylium‐catalyzed reductive sulfonamidation of functionalized ketones to access β‐amino esters. The in situ generated ion pair shows enhanced reactivity, with diethylsilane serving as both reductant and precatalyst. The developed protocol proceeds
Woo Hee Kim, Muhammad Israr, You Kyoung Chung, Shinwon Ham, Joonsuk Huh, Han Yong Bae   +5 more
wiley   +1 more source

Supercritical CO2‐Induced Porous MXene Films for Electromagnetic Interference Shielding and Infrared Stealth

Advanced Science, EarlyView.
The phase transition of supercritical CO2 induces the foaming of dense MXene film without compromise inherent structure of MXene nanosheet. The foamed porous MXene film manifests remarkable EMI shielding and infrared thermal camouflage performances. Moreover, the foaming strategy is broadly adaptable and can be extended to other two‐dimensional films ...
Hui Zhao, Shuai Li, Jiabei He, Tong Gao, Jingfeng Wang, Dongxiao Kan, Wangtu Huo, Lixin Chen   +7 more
wiley   +1 more source

Comparison of the Reaction Characteristics of Different Fuels in the Supercritical Multicomponent Thermal Fluid Generation Process

Energies
Supercritical multicomponent thermal fluid technology is a new technology with obvious advantages in offshore heavy oil recovery. However, there is currently insufficient understanding of the generation characteristics of the supercritical multicomponent
Qiang Fu, Jie Tian, Yongfei Liu, Zhilin Qi, Hongmei Jiao, Shenyao Yang   +5 more
doaj   +1 more source

ZrO2 Aerogel‐Supported Pd Nanoparticles for Photothermal CO2 Reduction

Advanced Science, EarlyView.
Nanoparticle‐based aerogels are promising catalysts for photothermal reactions due to optical transparency, high surface area, and low thermal conductivity. Here, we present deposition of Pd nanoparticles on ZrO2 aerogel granules by a wet‐impregnation approach.
David Kiwic, Linard Räz, Elena Tervoort, Markus Niederberger   +3 more
wiley   +1 more source

Valence-tuned electron bridge enables high-yield multi-electron HMF oxidation over spinel catalysts

Nature Communications
The catalytic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid is a key step in the production of bio-based plastics but remains limited by sluggish multi-electron transfer kinetics across multiple reaction intermediates. In this study,
Zhong-Ting Hu, Gan He, Xiaohuan Tao, Jinshu Tian, Mingwu Tan, Ni Ouyang, Jun-Long Li, Mian Hu, Jie-Xin Wang, Yihan Zhu, Dapeng Cao, Zhiyan Pan, Yong Wang, Xiaonian Li   +13 more
doaj   +1 more source

Regeneration of Modified Bentonite Loaded with Phenol Using Supercritical Fluids

Adsorption Science & Technology, 2004
The desorption of phenol from organically modified bentonite (ODTMA–bentonite) using supercritical fluids was studied. Parameters such as pressure, temperature, supercritical fluid flow rate and co-solvent (entrainer) concentration were investigated. The
Uğur Salgın, Nuray Yıldız, Ayla Çalımlı   +2 more
doaj   +1 more source

Autonomous High‐Throughput Characterization of Liquid‐Liquid Phase Behavior

Advanced Science, EarlyView.
This study introduces an automated dual modality platform, combining asymmetric capacitance deviation and multiangle turbidimetry, for high‐throughput characterization of liquid‐liquid phase behavior across chemically diverse fluid systems. The platform enables miscibility classification, resolution of phase separation kinetics and emulsion stability ...
Tarek Eid, Maryam Ebrahimiazar, Mohammad Zargartalebi, David Sinton   +3 more
wiley   +1 more source

Decoding the N-doping mechanism for enhanced CO2 adsorption on biochar

Carbon Capture Science & Technology
The growing demand for efficient carbon capture technologies has led to the exploration of biochar as a promising material for CO2 adsorption, particularly through modifications such as nitrogen doping to enhance its performance.
Shuo Xiang, Jun-Long Li, Tie Wu, Lian-Peng Li, Mian Hu, Jun Zhao, Zhong-Ting Hu, Zhiyan Pan   +7 more
doaj   +1 more source