Results 101 to 110 of about 20,671 (253)

Lattice‐Strained Cu2O‐Ni/NiO Heterostructure Enables Selective Electrocatalytic C–C Coupling of Alcohols to Cinnamaldehyde in Aqueous Medium

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This study achieved the selective oxidation C–C coupling of PhCH2OH with EtOH to form cinnamaldehyde (CAL) on a designed Cu2O‐Ni/NiO heterojunction catalyst. By employing a salt precipitation strategy to balance the pH and cation concentration, an 86% conversion rate of PhCH2OH and a 67% high selectivity for CAL were realized.
Tian Cheng   +10 more
wiley   +1 more source

Enhanced Urea Oxidation Reaction by Mn‐Doped Nickel Hydroxide From Wastewater

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Mn incorporation modifies the hydroxide structure and modulates the electronic properties of the Ni centers, promoting the formation of catalytically active NiOOH species. Mn dopants induce a favorable electronic effect but do not directly participate in the UOR mechanism, enhancing the overall urea oxidation rate and resulting in increased hydrogen ...
Filippo Bano   +8 more
wiley   +1 more source

Numerical Analysis of Two-Phase Multi-Material Flow Field in Hydrothermal Jet Drilling

open access: yesShiyou jixie, 2019
Hydrothermal jet drilling is a new type of drilling method suitable for deep hard formation. It generates high-temperature and high-pressure jet to break rock through supercritical oxidation reaction in downhole reactor.
崔柳   +4 more
doaj  

Chemical Recycling of Polyolefins Waste Materials Using Supercritical Water. [PDF]

open access: yesPolymers (Basel), 2022
Čolnik M   +3 more
europepmc   +1 more source

Asymmetric Synthesis of Tertiary α‐Aryl Stereocentres in Tetrahydro‐4H‐pyran‐4‐ones Using Pd‐Catalyzed Decarboxylative Asymmetric Protonation

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
The Pd‐catalyzed decarboxylative asymmetric protonation (DAP) has been developed for sterically hindered tetrahydro‐4H‐pyran‐4‐one derived α‐aryl‐β‐keto esters. A substrate scope of nine examples of DAP showed that substrates containing a di‐ortho methoxy substitution pattern on the aryl ring gave rise to the highest enantioselectivities of up to 85 ...
Fionn McNeill   +5 more
wiley   +1 more source

Experiment on Heat Transfer Characteristics of Supercritical Nitrogen in Vertical Tube for Open Rack Vaporizer

open access: yesZhileng xuebao, 2020
Open rack vaporizers are basic load vaporizers that are widely used in LNG terminals. However, there are few experimental studies on the fluid flow and heat transfer behaviors of supercritical natural gas.
Cheng He, Ju Yonglin, Fu Yunzhun
doaj  

Coated and Immobilized Polysaccharides‐Based Stationary Phases for Planar Metallocenes Enantioseparation in Liquid Chromatography

open access: yesELECTROPHORESIS, EarlyView.
This study examined 21 new ferrocene and ruthenocene derivatives, including those with planar and central chirality. Their stereochemical behavior was examined using UV‐detected normal‐phase liquid chromatography. Under fixed conditions, eight polysaccharide‐based chiral stationary phases were tested using n‐heptane combined with either 2‐propanol or ...
Florine Wartelle   +4 more
wiley   +1 more source

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