A linker‐desymmetrization‐modulator‐compensation (LDMC) strategy for constructing structurally diverse Zr‐MOFs is reported. This approach reduces linker symmetry to create defects in Zr‐clusters, which can be compensated for by modulator coordination. Using this approach, we synthesized PCN‐1005 and PCN‐1006, featuring unprecedented Zr‐clusters. In PCN‐
Rong‐Ran Liang +8 more
wiley +1 more source
Tandem mechanochemical engineering yields highly crystalline metal-organic frameworks. [PDF]
Tegudeer Z, Gao WY.
europepmc +1 more source
Azaporphyrinoid‐Based Photo‐ and Electroactive Architectures for Advanced Functional Materials
A long‐standing collaboration between the Torres and Guldi groups has yielded diverse azaporphyrinoid‐based donor‐acceptor nanohybrids with promising applications in solar energy conversion. This conspectus highlights key molecular platforms and structure‐function relationships that govern light and charge management, supporting the rational design of ...
Jorge Labella +3 more
wiley +1 more source
Effect of Fabric Topology and Axial Yarn Condition on the Compressive Properties of 3D Stepwise Rotary Braided Composites. [PDF]
Mei H +5 more
europepmc +1 more source
The topology of the S protein in the yeast-derived hepatitis B surface antigen particles.
Nathalie Sonveaux +5 more
openalex +1 more source
COFs on MOFs: Layer‐by‐Layer Synthesis of MOF@COF Nanoparticles with Synergistic Adsorption
A layer‐by‐layer strategy enables the growth of crystalline covalent organic framework (COF) shells on metal–organic framework nanoparticles, creating core–shell structures with tunable porosity. Ordered interstitial mesopores are formed during shell growth, which are connected with the COF's intrinsic micropores, thereby enhancing water sorption. This
Ana Guillem‐Navajas +11 more
wiley +1 more source
The topology optimization design and processing of 3D-printed bio-fixed bone plate applied to the mandible. [PDF]
Zhou X, Zhang G, Huang A, Zhou H.
europepmc +1 more source
Spectral Tuning of Hyperbolic Shear Polaritons in Monoclinic Gallium Oxide via Isotopic Substitution
Spectral tuning of highly directional hyperbolic shear polaritons is realized via isotopic substitution of 16O to 18O in monoclinic β$\beta$‐phase gallium oxide. A red‐shift of almost 40 cm−1 is experimentally demonstrated with near‐field imaging, corroborated by the permittivity change extracted from far‐field experiments and density functional theory.
Giulia Carini +28 more
wiley +1 more source
Topology Design of Reconfigurable Intelligent Metasurfaces Based on Equivalent Circuit Model. [PDF]
Xu J, Zhu C, Pan Y, Zhang H, Wu C, Li H.
europepmc +1 more source
Ordered three‐dimensional anodic aluminum oxide (3D‐AAO) nanoarchitectures with longitudinal and transverse pores enable architecture‐driven metamaterials. The review maps fabrication advances, including hybrid pulse anodization, and shows how 3D‐AAO templates tailor properties across magnetism, energy, catalysis, and sensing.
Marisol Martín‐González
wiley +1 more source

