Results 101 to 110 of about 42,284 (289)

Genome Mining Reveals a Novel Nephthenol‐Producing Diterpene Synthase from the Sandfly Lutzomyia Longipalpis

open access: yesChemBioChem, EarlyView.
The discovery of a terpene synthase of insect origin that makes the apparently cryptic product nephthenol from geranylgeranyl diphosphate sheds light on hidden biosynthetic potential. Populations of the sandfly, Lutzomyia longipalpis, use the diterpene sobralene as a sex/aggregation pheromone, which is likely produced in the insect through the activity
Charles Ducker   +6 more
wiley   +1 more source

Palladium‐Catalyzed Telomerization of Isoprene with Amines: Ligands and Solvents Working Together to Improve the Selectivity

open access: yesChemCatChem, EarlyView.
Palladium‐catalyzed telomerization of isoprene with diethylamine using non‐protic solvents and phosphite ligands with large cone angle afforded telomer 3 (T–T) in up to 90% yield and 90% selectivity. Phosphite ligands with small cone angle provided telomer 4 (H‐T) with selectivity of 43% (80% yield) and 48% (23% yield) with iPr2NH.
Jordi Colavida   +8 more
wiley   +1 more source

Rewriting Alkene Frameworks: A Practical Strategy for Nitrogen Incorporation

open access: yesChemistryEurope, EarlyView.
Morandi and team developed a metal‐free method to insert nitrogen into unactivated alkenes, forming amidines and nitriles via a transient aza‐allenium intermediate. Using mild, open‐flask conditions, the process delivers high yields and broad functional group tolerance.
Ranjini Laskar, Frank Glorius
wiley   +1 more source

Chemometrics‐Assisted Electrochemical Device for Cannabidiol Detection in Real Cannabis sativa Samples

open access: yesChemistry–Methods, EarlyView.
GA: Four‐step process for cannabidiol (CBD) detection in Cannabis sativa extracts. (1) The plant extract is obtained. (2) An electrochemical sensor detects CBD using a screen‐printed electrode. (3) Electrochemical signatures of real samples are recorded, showing current vs. potential curves.
Wanda Cimmino   +13 more
wiley   +1 more source

Anthraquinone Sulfonates as Water‐Soluble Photocatalysts: Synthetic Applications and Perspectives

open access: yesChemPhotoChem, EarlyView.
The development of photochemistry in water is rapidly advancing, and the demand for water‐soluble photocatalysts is increasing. Accordingly, anthraquinone sulfonates are interesting options for the activation of organic molecules through H‐atom transfer, proton‐coupled electron transfer, or the generation of reactive oxygen species.
Daniel Kolb   +2 more
wiley   +1 more source

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