Zur Kenntniss der Terpene und der ätherischen Oele, Achtzehnte Abhandlung [PDF]
O. Wallach
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The discovery of a terpene synthase of insect origin that makes the apparently cryptic product nephthenol from geranylgeranyl diphosphate sheds light on hidden biosynthetic potential. Populations of the sandfly, Lutzomyia longipalpis, use the diterpene sobralene as a sex/aggregation pheromone, which is likely produced in the insect through the activity
Charles Ducker+6 more
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XL.—Experiments on the synthesis of the terpenes. Part I. (Continued). Direct synthesis of terpin from ethyl cyclohexanone-4-carboxylate [PDF]
Francis William Kay, W. H. Perkin
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Palladium‐catalyzed telomerization of isoprene with diethylamine using non‐protic solvents and phosphite ligands with large cone angle afforded telomer 3 (T–T) in up to 90% yield and 90% selectivity. Phosphite ligands with small cone angle provided telomer 4 (H‐T) with selectivity of 43% (80% yield) and 48% (23% yield) with iPr2NH.
Jordi Colavida+8 more
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XCVIII.—Studies of the terpenes and allied compounds. Nitrocamphor and its derivatives. I. Stereoisomeric chloro- and bromo-nitrocamphors. II. Pseudonitrocamphor. III. Camphoryloxime (camphonitrophenol) [PDF]
Thomas Martin Lowry
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Rewriting Alkene Frameworks: A Practical Strategy for Nitrogen Incorporation
Morandi and team developed a metal‐free method to insert nitrogen into unactivated alkenes, forming amidines and nitriles via a transient aza‐allenium intermediate. Using mild, open‐flask conditions, the process delivers high yields and broad functional group tolerance.
Ranjini Laskar, Frank Glorius
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Zur Kenntniss der Terpene und der ätherischen Oele. Ueber Isocarvoxim und die Constitution des Carvolins, nebst Bemerkungen über den Isomerisationsverlauf bei Oximen [PDF]
O. Wallach
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GA: Four‐step process for cannabidiol (CBD) detection in Cannabis sativa extracts. (1) The plant extract is obtained. (2) An electrochemical sensor detects CBD using a screen‐printed electrode. (3) Electrochemical signatures of real samples are recorded, showing current vs. potential curves.
Wanda Cimmino+13 more
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Zur Kenntniss der Terpene und der ätherischen Oele; Ueber die Umwandlung cyklischer Ketone in Alkamine und in sauerstofffreie Basen stickstoffhaltiger Ringsysteme [PDF]
O. Wallach
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Anthraquinone Sulfonates as Water‐Soluble Photocatalysts: Synthetic Applications and Perspectives
The development of photochemistry in water is rapidly advancing, and the demand for water‐soluble photocatalysts is increasing. Accordingly, anthraquinone sulfonates are interesting options for the activation of organic molecules through H‐atom transfer, proton‐coupled electron transfer, or the generation of reactive oxygen species.
Daniel Kolb+2 more
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