Solvent‐Free Thermal Defect Engineering in Molecular Frameworks With Volatile Linkers
Thermal removal of neutral volatile linkers enables precise and solvent‐free generation of metal vacancies in MOFs. This strategy affords redox‐stable, coordinatively unsaturated FeII sites with tunable spin, ligand coordination, and catalytic behavior. The approach offers a general route to design defect‐functional materials through local coordination
Sonia Martínez‐Giménez +9 more
wiley +1 more source
Multifactor analysis and dominant factor identification for coal seam gas drainage borehole instability. [PDF]
Wang W, Yang W, Zhang Z, Shi W.
europepmc +1 more source
Flexoelectrically Induced Polar Topology in Twisted SrTiO3 Membranes
Twisted SrTiO3 bilayers host polar vortices of flexoelectric origin, revealed through combined experiment and theory. By reconstructing polarization from the toroidal moment of strain gradients, the work establishes a 3D chiral state with broken inversion and mirror symmetries.
Isabel Tenreiro +13 more
wiley +1 more source
Physical, Rheological and Microstructural Properties of Asphalt Modified by Low-Molecular-Weight Polyolefin. [PDF]
He J, Leng B, Chen M, Guo S, Yu J.
europepmc +1 more source
Adaptive Twisting Metamaterials
This work introduces torque‐controlled twisting metamaterials as a transformative platform for adaptive crashworthiness. By combining multiscale predictive modeling with experimental validation on additively manufactured gyroids, it demonstrates tunable stiffness, collapse stress, and energy absorption.
Mattia Utzeri +6 more
wiley +1 more source
Peridynamics-Based Finite Element Analysis of Sealing Failure at Casing-Cement Sheath Interfaces in Ultra-Deep Wells. [PDF]
Zhai S +5 more
europepmc +1 more source
Asymmetry of the Ferroelectric Phase Transition in BaTiO3
Phase transitions are typically assumed to behave identically in forward and reverse. This work shows that in the ferroelectric material barium titanate this is not true: heating drives an abrupt, first‐order jump, while cooling gives a smooth, continuous change.
Asaf Hershkovitz +14 more
wiley +1 more source
First-principles study of X<sub>2</sub>TlAgCl<sub>6</sub> (X = K, Rb, Cs) double perovskites for high-performance optoelectronic and thermoelectric devices. [PDF]
Shah SH +4 more
europepmc +1 more source
The graphic illustrates the design of a hybrid bilayer composed of a liquid crystal hydrogel (LCH) and a liquid crystal network (LCN). The figure highlights the magnetic alignment of the chromonic hydrogel and the thermal‐responsive actuation of the LCN along with the LCH when both layers are aligned or misaligned, enabling programmable, light‐driven ...
Ramón Santiago Herrera Restrepo +13 more
wiley +1 more source

