Methyl itaconate-anthracene adducts (MIAs) facilitate the enantiomeric separation of 1,1'-bi-2-naphthols <i>via</i> thin-layer chromatography (TLC) with trends predicted by molecular dynamics simulations. [PDF]
RSC AdvSinthopweha W +3 more
europepmc +1 more source
Modulation of Local Environment for Selective Bicarbonate Conversion to Multi‐Carbon Products
Advanced Energy Materials, EarlyView.Highly porous Cu electrode partially coated with an ionomer/carbon composite enables efficient conversion of bicarbonate to multi‐carbon products. By regulating the local reaction microenvironment, this strategy overcomes selectivity and reaction‐rate limitations, achieving Faradaic efficiencies of 43% for ethylene and 60% for total multi‐carbon ...
Tai Nguyen +15 more
wiley +1 more source
Angewandte Chemie, EarlyView.Directional control within the secondary coordination sphere redefines CO2 reduction by iron porphyrins. Simply rearranging identical urea hydrogen‐bond donors modulates reactivity, revealing that optimal catalysis does not only arise from maximal intermediate stabilization, but also from directional, adaptive non‐covalent interactions that balance ...
Ashutosh Vishwakarma +7 more
wiley +2 more sources
Selective determination of 3,5-dihydroxycinnamic acid in urine samples as gluten intake biomarker: high-performance thin-layer chromatography combined with colorimetric detection. [PDF]
Anal Bioanal ChemMartínez-Aviñó A +5 more
europepmc +1 more source
Advanced Energy Materials, EarlyView.(Mo–S)1@NiFe–LDH promotes the rapid structural transition to the active oxyhydroxide phase, enabling selective seawater oxidation at industrial‐level current densities. Atomically dispersed Mo–S sites within the LDH lattice efficaciously modulate the structural flexibility to lower the thermodynamic barrier for early‐phase activation.
Jae Kwan Lee +14 more
wiley +1 more source
Divergent Synthesis of Möbius and Hückel N‐Heterocycloarenes From a Common Macrocyclic Backbone
Angewandte Chemie, EarlyView.In the divergent synthesis of Möbius and Hückel N‐heterocycloarenes from a common macrocyclic precursor, the annulation reaction dictates topology: Scholl reaction gives Möbius topology, while InCl3‐mediated alkyne annulation gives Hückel topology. The Möbius N‐heterocycloarene is unevenly contorted as revealed by crystal structure, and the Hückel N ...
Han Chen +6 more
wiley +2 more sources
Greenness and whiteness appraisal for bioanalysis of quetiapine, levodopa and carbidopa in spiked human plasma by high performance thin layer chromatography. [PDF]
BMC ChemHindam FT +4 more
europepmc +1 more source
Advanced Intelligent Discovery, EarlyView.Exosomes are emerging as powerful biomarkers for disease diagnosis and monitoring. This review highlights the integration of surface‐enhanced Raman spectroscopy with artificial intelligence to enhance molecular fingerprinting of exosomes. Machine learning and deep learning techniques improve spectral interpretation, enabling accurate classification of ...
Munevver Akdeniz +2 more
wiley +1 more source
Enhanced Formation of Dicarboxylic Acids in the Catalytic Oxidation of Polyethylene With O2 and NOx
Angewandte Chemie, EarlyView.The oxidation of polyethylene in the presence of a mixture of O2 and NOx and with Cu2+/V5+ as catalyst yields ∼51 mol% diacids, while retaining ∼80 mol% of the carbon in the oil fraction. The developed method is robust and tolerates several polymer types as well as impurities.
Tom J. Smak +3 more
wiley +2 more sources
Natural Deep Eutectic Solvents (NADESs) for the Extraction of Bioactive Compounds from Quinoa (<i>Chenopodium quinoa</i> Willd.) Leaves: A Semi-Quantitative Analysis Using High Performance Thin-Layer Chromatography. [PDF]
MoleculesTaco V +7 more
europepmc +1 more source