Results 21 to 30 of about 3,017 (175)

Near‐Infrared‐Light‐Driven Photochemistry and Photocatalysis: Mechanisms, Recent Applications, and Opportunities in Organic Synthesis and Biology

open access: yesAngewandte Chemie, EarlyView.
This minireview highlights recent advances in catalyst development and mechanistic strategies that enable photochemical and photocatalytic reactivity under 700–1000 nm NIR light, emphasizing how long‐wavelength excitation expands opportunities in both synthetic chemistry and biology.
Santosh K. Pagire   +3 more
wiley   +2 more sources

Intoxication with carbamate insecticides and toxicological risk to animals

open access: yesЖивотновъдни науки, 2022
Carbamate biocidal compounds (carbamic acid derivatives – aryl and alkyl esters) were discovered in the early 1950s. Shortly afterwards, along with organophosphorus insecticides (ORPs), they began to be widely used in the form of carbamate insecticides (
Metodi Petrichev
doaj  

Hydroxycobalamin catalyzes the oxidation of diethyldithiocarbamate and increases its cytotoxicity independently of copper ions

open access: yesRedox Biology, 2019
It is known that some metals (Cu, Zn, Cd, Au) markedly increase the toxic effect of thiocarbamates. It was shown in the present study that hydroxycobalamin (a form of vitamin B12, HOCbl), which incorporates cobalt, significantly enhances the cytotoxicity
M.E. Solovieva   +5 more
doaj   +1 more source

Agricultural exposures to carbamate herbicides and fungicides and central nervous system tumour incidence in the cohort AGRICAN

open access: yesEnvironment International, 2019
Background: Pesticides exposures could be implicated in the excess of Central Nervous System (CNS) tumors observed in farmers, but evidence concerning individual pesticides remains limited.
Clément Piel   +41 more
doaj   +1 more source

The trouble with ODE : polymerization during nanocrystal synthesis [PDF]

open access: yes, 2019
1-Octadecene is a widely used solvent for high temperature nanocrystal synthesis (120-320 degrees C). Here, we show that 1-octadecene spontaneously polymerizes under these conditions, and the resulting poly(1-octadecene) has a comparable solubility and ...
Bennett, Ellie   +4 more
core   +2 more sources

From Covalent Traps to Fluorescent Beacons: The Expanding Arsenal of Chemical Probes for Studying Ubiquitin and Ubiquitin‐Like Proteins

open access: yesAngewandte Chemie, Volume 138, Issue 13, 23 March 2026.
A large variety of chemistry‐based ubiquitin probes have been developed. ABSTRACT Ubiquitin (Ub) and ubiquitin‐like proteins (Ubls) orchestrate diverse cellular processes through reversible post‐translational modification of target proteins. Their conjugation is governed by a cascade of E1 activating, E2 conjugating, and E3 ligating enzymes, while ...
Saibal Chanda, Wenshe Ray Liu
wiley   +2 more sources

Genotoxicity and Cytotoxicity Exerted by Pesticides in Different Biotic Matrices-An Overview of More Than a Decade of Experimental Evaluation [PDF]

open access: yes, 2014
Agrochemicals represent one of the most important sources of environmental pollution. Although attempts to reduce agrochemical use through organic agricultural practices and the use of other technologies to control pests continue, the problem is still
Larramendy, Marcelo Luis   +3 more
core   +2 more sources

Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis [PDF]

open access: yes, 2016
The presence of both κ2-chelating and μ2,κ2-tridentate bridging dithiocarbamate ligands in centrosymmetric {Hg[S2CN(iPr)CH2CH2OH]2}2 (1) leads to globular aggregates that are linked into a three-dimensional architecture via hydroxyl-O–H···O(hydroxy ...
Jotani, Mukesh M.   +2 more
core   +1 more source

N-(4-Bromophenyl)methoxycarbothioamide [PDF]

open access: yes, 2018
The synthesis, spectroscopic and crystallographic characterisation of the title compound, O-methyl-N-4-bromophenyl thiocarbamate, MeOC(=S)N(H)PhBr-4 (1), are described.
Tiekink, Edward R. T. *   +1 more
core   +2 more sources

Synthesis of Secondary Amides from Thiocarbamates [PDF]

open access: yesOrganic Letters, 2018
The synthesis of secondary amides from readily accessible and bench-stable substituted S-phenyl thiocarbamates and Grignard reactants is reported. Oxidative workup allows recycling of the thiolate leaving group as diphenyl disulfide. Diphenyl disulfide can be transformed into S-phenyl benzenethiosulfonate, a reactant required for thiocarbamate ...
Pieter Mampuys   +3 more
openaire   +2 more sources

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