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Diphenylantimony(III) thiocyanate: unusual thiocyanate bridging
Journal of the Chemical Society, Chemical Communications, 1991The thiocyanate group can bond via sulphur or nitrogen or bridge between two centres, but in diphenylantimony thiocyanate, unusual bridging gives antimony atoms coordinated by, respectively, two sulphur atoms, two nitrogen atoms and one atom of each type, allowing development of a curious infinite ‘triangular spiral’ structure in the solid state.
Glynis E. Forster +3 more
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Aromatic thiocyanation using supported copper(I) thiocyanate
Journal of the Chemical Society, Chemical Communications, 1989Charcoal supported copper(I) thiocyanate can be used to convert bromo- and iodo-benzenes into phenyl thiocyanates with no contamination from phenyl isothiocyanates.
James H. Clark +3 more
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Tin(II) thiocyanate and complex thiocyanates
Journal of the Chemical Society A: Inorganic, Physical, Theoretical, 1969The preparation and properties of pure tin(II) thiocyanate and of several complex thiocyanates are described. Their infrared spectra are discussed and evidence is adduced for mainly N-bonding of the thiocyanate, with extensive bridging in Sn(NCS)2. Tin(II) thiocyanate is found to form ether adducts of poor stability and to be an effective catalyst for ...
B. R. Chamberlain, W. Moser
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1987
Publisher Summary This chapter discusses about the determination of thiocyanate and thiosulfate. Several methods are used for the analytical determination of inorganic thiocyanate. These include procedures based on the formation of colored complexes, either with ferric ions or with cupric ions and pyridine, or on oxidation with bromine followed by ...
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Publisher Summary This chapter discusses about the determination of thiocyanate and thiosulfate. Several methods are used for the analytical determination of inorganic thiocyanate. These include procedures based on the formation of colored complexes, either with ferric ions or with cupric ions and pyridine, or on oxidation with bromine followed by ...
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Journal of the American Chemical Society, 1950
Charles D. Hurd, H. L. Wehrmeister
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Charles D. Hurd, H. L. Wehrmeister
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