Results 201 to 210 of about 30,128 (251)

Direct Cyanation of Thiophenols or Thiols to Access Thiocyanates under Electrochemical Conditions.

open access: yesJournal of Organic Chemistry, 2022
A novel electrochemical cross-coupling method for the synthesis of thiocyanates via the direct cyanation of readily available thiophenols or thiols with trimethylsilyl cyanide (TMSCN) was developed. This approach was also suitable for selenols.
Cong Jiang   +4 more
semanticscholar   +2 more sources

Fluorium-Initiated Dealkylative Cyanation of Thioethers to Thiocyanates.

open access: yesJournal of Organic Chemistry, 2019
Thioethers are converted to thiocyanates via fluorium-initiated dealkylative cyanation. Selectfluor is used as the oxidant and trimethylsilyl cyanide as the cyanation reagent.
Yang Chen   +5 more
semanticscholar   +2 more sources
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Selectfluor-initiated cyanation of disulfides to thiocyanates

Journal of Chemical Research, 2020
A Selectfluor-initiated cyanation of disulfides to thiocyanates has been developed. In this process, Selectfluor was employed as the oxidant and trimethylsilyl cyanide was used as the cyanation reagent.
Chuan Chen, Shubai Li
exaly   +2 more sources

Photoinduced Synthesis of Thiocyanates through Hydrogen Atom Transfer and One-Pot Derivatization to Isothiocyanates.

Organic Letters, 2022
Photoinduced benzylic C-H thiocyanation is described. A series of alkyl thiocyanates were efficiently obtained by using Selectfluor as the oxidant. Moreover, we accomplished the one-pot isothiocyanation following the C-H thiocyanation.
Bumpei Maeda   +4 more
semanticscholar   +1 more source

Structures, bonding, and electronic properties of metal thiocyanates

Journal of Physics and Chemistry of Solids, 2021
Metal thiocyanates, such as copper(I) thiocyanate (CuSCN) and tin(II) thiocyanate [Sn(SCN)2], are emerging as novel semiconductors for electronic applications, and while other thiocyanate coordination polymers are known, their electronic structures and ...
Chayanit Wechwithayakhlung   +3 more
semanticscholar   +1 more source

Thiocyanates as attractive redox-active electrolytes for high-energy and environmentally-friendly electrochemical capacitors.

open access: yesPhysical Chemistry, Chemical Physics - PCCP, 2017
This manuscript reports on the novel insight into the development of high voltage carbon/carbon electrochemical capacitors operating in aqueous solutions of alkali metals and ammonium thiocyanates (KSCN, NaSCN, LiSCN, and NH4SCN).
B. Górska, Paulina Bujewska, K. Fic
semanticscholar   +2 more sources

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