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Photoinduced benzylic C–H thiocyanation is described. A series of alkyl thiocyanates were efficiently obtained by using Selectfluor as the oxidant. Moreover, we accomplished the one-pot isothiocyanation following the C–H thiocyanation.
Toshinori Kinoshita (3900580) +4 more
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Angewandte Chemie - International Edition, 2023 Decarboxylative halogenations of alkyl carboxylic acids are highly valuable reactions for the synthesis of stucturally diverse alkyl halides. However, many reported protocols rely on stoichiometric strong oxidants or highly electrophilic halogenating ...
Adam Noble +2 more
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Diquat Based Dyes: A New Class of Photoredox Catalysts and Their Use in Aerobic Thiocyanation [PDF]
Chemistry - A European Journal, 2023 A series of new organic donor-π-acceptor dyes incorporating a diquat moiety as a novel electron-acceptor unit have been synthesized and characterized. The analytical data were supported by DFT calculations.
René Wilhelm
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Photocatalyst-Free Regioselective C–H Thiocyanation of 4-Anilinocoumarins under Visible Light
ACS Sustainable Chemistry and Engineering, 2019 In the present study, we describe the successful development of a novel and efficient C(sp2)–H thiocyanation reaction of electron-rich heteroarenes and arenes with readily available ammonium thiocyanate under visible light exposure.
Daoshan Yang
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Electrochemical Oxidative C–H Thiocyanation or Selenocyanation of Imidazopyridines and Arenes
Synlett, 2021Peipei Sun
exaly
A review on electrophilic thiocyanation of aromatic and heteroaromatic compounds
Tetrahedron, 2020Sobhan Rezayati +2 more
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Electrochemical Thiocyanation/Cyclization Cascade to Access Thiocyanato-Containing Benzoxazines
Catalysts, 2023Aiwen Lei, Hong Yi, Shengchun Wang
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Copper‐Catalyzed Remote Direct Thiocyanation of Alkyl C(sp3)−H Bonds
Advanced Synthesis and Catalysis, 2020Zhong-Yan Cao, Hongwei Zhang
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