Results 71 to 80 of about 470 (176)
Citation: 'thiocyanates' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.T06353 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
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A simple and efficient method for the α-thiocyanation of ketones has been developed; anhydrous iron(III) chloride is used under mild conditions to produce α-oxo thiocyanates in good to high yields and with high selectivity.
Chary, Darshanoju N. +3 more
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The hitherto unknown 5,6-dihydroxy-3-mercaptoindole (4a) and its 2-carbomethoxy derivative (4b), as well as the analogous 5-hydroxy 3-mercaptoindoles, have been conveniently obtained as O,S-acetyl derivatives 3a-d by thiocyanation of the corresponding ...
A. PEZZELLA +15 more
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Preparations of Organic Thiocyanates by the Use of Potassium Thiocyanate
有機ハロゲン化合物とチオシアン酸カリウムとの反応を各種の有機溶媒中で行ない, ジメチルホルムアミド, ジエチルホルムアミド, ジメチルスルホキシド, テトラメチレンスルホキシドなどを溶媒として用いた場合にとくに好収率でチオシアン酸エステルが生成することをみとめた。この反応は上記溶媒の触媒作用によって促進されるものであり,ハロゲン化アルキルと溶媒とのオニウム型中間体を経由して反応が進行するものと考えられる。ジメチルホルムアミドあるいはジメチルスルホキシドを反応溶媒としてハロゲン化アルキル, ジハロゲノアルカン, ハロゲン化ベンジル, 塩化キシリレンとチオシアン酸カリウムとの反応により,相当するチオシアン酸エステルを合成した。一方 ...
Shigeo Yoneda +2 more
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SelectfluorTM is found to catalyze efficiently the electrophilic thiocyanation of indoles and pyrrole with ammonium thiocyanate under mild and neutral conditions to produce the corresponding 3-indolyl and 2-pyrrolyl thiocyanates, respectively, in ...
Jayasudhan Reddy, Y. +2 more
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Surface thiocyanation of plasticized poly(vinyl chloride) and its effect on bacterial adhesion
Thiocyanates, especially bis-alkylthiocyanates are highly effective in killing a number of bacterial strains and are reported to be potent biocides at ppm concentrations. In order to examine whether a covalently bound and immobilized thiocyanate group on
Jayakrishnan, A., James, Nirmala R.
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Metal thiocyanates were some of the first pseudohalide compounds to be discovered and adopt a diverse range of structures. This review describes the structures, properties, and syntheses of the known binary and ternary metal thiocyanates. It provides a categorization of their diverse structures and connects them to the structures of atomic inorganic ...
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A new, efficient and mild approach for the oxidative dehydrogenation of dihydropyrimidinones and thiocyanation of aromatic compounds using 1,1,2,2-tetrahydroperoxy-1,2-diphenylethane (THPDPE) as a terminal oxidant was developed.
Naserifar, Shirin +5 more
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Thiocyanation of BODIPY dyes and their conversion to thioalkylated derivatives
A high-yielding method for the direct thiocyanation of BODIPY dyes is described. In 1,3-dimethyl BODIPYs, the thiocyanato group adds at position 2, whereas the insertion occurs at position 5 in 3-amino BODIPYs. The transformation of the thiocyanato group
Verbelen, Bram +5 more
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