RESEARCHES ON THIOCYANATES AND ISOTHIOCYANATES. [PDF]
Journal of the American Chemical Society, 1906 n ...
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Designing Enzymatic Reactivity with an Expanded Palette
ChemBioChem, Volume 26, Issue 11, June 3, 2025.Innovation in biocatalysis is rapidly increasingly the diversity of catalytic reactivity that can be mediated by enzymes, addressing a key bottleneck for their widespread adoption in industrial chemical synthesis. A key approach to this is building enzymes with unnatural catalytic components that provide an expanded palette with new possibilities for ...
Reuben B. Leveson‐Gower
wiley +1 more source
Iron (III) chloride as mild and efficient reagent for the α-thiocyanation of ketones: an expedient synthesis of α-oxo thiocyanates [PDF]
, 2008 A simple and efficient method for the α-thiocyanation of ketones has been developed; anhydrous iron(III) chloride is used under mild conditions to produce α-oxo thiocyanates in good to high yields and with high selectivity.
Chary, Darshanoju N. +3 more
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Small Science, Volume 5, Issue 6, June 2025.Molecular engineering of antimony corroles with various β‐substituents and the ability to modulate the oxidation state of the metal ion is employed to demonstrate exceptional optoelectronic properties. The antimony(V) corrole with SCN substituents shows enhanced charge carrier mobility, a high dielectric constant, and a broad absorption range ...
Tanmoy Pain +7 more
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Transition Metal‐Promoted Direct CS and CSe Bond Formation from Csp3H Bonds
European Journal of Organic Chemistry, Volume 28, Issue 20, May 28, 2025.This review summarizes the significant advancements in transition metal‐catalyzed direct chalcogenylation of Csp3H bonds over the past decade (2014–2024). The discussion is organized by transition metal catalysts, with particular emphasis on mechanistic insights of these transformations.
Douglas B. Paixão +7 more
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The Conversion of Ammonium Thiocyanate into Thiourea and of Thiourea into Thiocyanate [PDF]
The Journal of Physical Chemistry, 1898 n ...
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Regioselective C‐H Thio‐ and Selenocyanation of Pyrazolo[1,5‐a]pyrimidines
Chemistry – An Asian Journal, Volume 20, Issue 9, May 2, 2025.A metal‐free, N‐chlorosuccinimide (NCS) mediated, highly efficient, and regioselective C−H thiocyanation and C−H selenocyanation of pyrazolo[1,5‐a]pyrimidines are achieved under mild reaction conditions for the synthesis of a wide variety of 3‐thiocyanato‐ and 3‐selenocyanatopyrazolo[1,5‐a]pyrimidines in good to excellent yield up to 99 %.
Paramita Pattanayak +3 more
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The first entry to 5,6-dihydroxy-3-mercaptoindole, 5-hydroxy-3-mercaptoindole and their 2-carbomethoxy derivatives by a mild thiocyanation/reduction methodology. [PDF]
, 2007 The hitherto unknown 5,6-dihydroxy-3-mercaptoindole (4a) and its 2-carbomethoxy derivative (4b), as well as the analogous 5-hydroxy 3-mercaptoindoles, have been conveniently obtained as O,S-acetyl derivatives 3a-d by thiocyanation of the corresponding ...
A. PEZZELLA +15 more
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ChemPhotoChem, Volume 9, Issue 5, May 2025.This review focuses on recent developments in heterogenization of photocatalysts into polymers, highlighting methods like photocatalyst polymerization, post‐grafting, and 3D printing. Discussion about these different approaches of heterogeneous photocatalysis (advantages and drawbacks) is provided.
Cloé Delacourt +3 more
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1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2,2,2]octane bis(tetrafluoroborate) as novel and versatile reagent for the rapid thiocyanation of indoles, azaindole, and carbazole [PDF]
, 2008 SelectfluorTM is found to catalyze efficiently the electrophilic thiocyanation of indoles and pyrrole with ammonium thiocyanate under mild and neutral conditions to produce the corresponding 3-indolyl and 2-pyrrolyl thiocyanates, respectively, in ...
Jayasudhan Reddy, Y. +2 more
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