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New imidazole-2-thiones linked to acenaphythylenone as dual DNA intercalators and topoisomerase II inhibitors: structural optimization, docking, and apoptosis studies. [PDF]
Mohamed AH +8 more
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Thione photochemistry: cyclopropanethiol formation from arylalkyl thiones
Journal of the Chemical Society, Chemical Communications, 1976Excitation into the π*↠n band of arylalkyl thiones having an activated β position leads to the formation of cyclopropanethiols.
Axel Couture +2 more
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Five-membered Heterocyclic Thiones. Part II. Oxazole-2-thione
Canadian Journal of Chemistry, 1972Oxazole-2-thione was prepared by the condensation of glycolic aldehyde and thiocyanic acid. It was shown by i.r. spectroscopy that oxazole-2-thione, as well as its 4-methyl- and 4,5-dimethyl derivatives, existed as the thione form in solution.
G. Lacasse, J. M. Muchowski
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ChemInform Abstract: THIONE PHOTOCHEMISTRY‐ CYCLOPROPANETHIOL FORMATION FROM ARYLALKYL THIONES
Chemischer Informationsdienst, 1976AbstractDie Thioketone (I) liefern bei Belichtung in Benzol die Cyclopropylmercaptane (II).
A. COUTURE, M. HOSHINO, P. DE MAYO
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Thiones as superdipolarophiles
Tetrahedron Letters, 1989Abstract According to kinetic measurements, the 1,3-cycloadditions of diphenyldiazomethane to thioketones are much faster than those to α,β-unsaturated carbonyl compounds and nitriles previously regarded as record dipolarophiles. The primary cycloadducts are tetrasubstituted 1,3,4-thiadiazolines which extrude N 2 and furnish thiiranes via ...
Rolf Huisgen, Elke Langhals
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Synthesis of imidazoline-2-thiones and imidazolidine-2-thiones
Tetrahedron, 1963Abstract 1-Aryl (or alkyl)-4,5-( d -glucopyrano)imidazolidine-2-thiones are obtained by condensation of 2-amino-2-deoxy- d -glucose with aryl (or alkyl) isothiocyanates. 1-Aryl-4- d - arabino tetrahydroxybutylimidazoline-2-thiones are prepared by reaction of N-arylamino-1-deoxy- d -fructoses with potassium thiocyanate.
J. Fernández-Bolaños +3 more
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HETEROCYCLIC THIONE S-IMIDES AND S-OXIDES. PREPARATION FROM THIONES
Phosphorus and Sulfur and the Related Elements, 1983Abstract Some six-membered heterocyclic thione S-imides and the corresponding thione S-oxides (sulfines) were prepared from the corresponding thiones. Their stability is briefly discussed.
Takao Saito +3 more
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