1,3-Dibenzylimidazolidine-2-thione [PDF]
In the title compound, C17H18N2S, the imidazolidine ring adopts a twisted conformation. In the crystal, molecules are linked by slipped π–π interactions between the benzene rings of neighbouring molecules [centroid-to-centroid distance = 3.903 (2) Å].
Anna Mietlarek-Kropidłowska +2 more
openaire +3 more sources
Thione photochemistry. Dual pathways in aralkyl thione cyclizations [PDF]
It is shown that aralkyl thiones, which possess an oxygen atom at the δ position in the side chain, can therefore not undergo the preferred δ insertion, and insert at the γ and ε positions. Although ε insertion occurs only from the 1(π,π*) state, γ abstraction (followed by cyclization or cleavage) occurs from both 1(π,π*) and 3(n,π*) states.
S. Basu +5 more
openaire +1 more source
Synthesis of novel 3-(2-bromophenyl)-4-substituted-1H-1,2,4-triazole-5(4H)-thiones derivatives
A wide range of biological activity of 1,2,4-triazole derivatives (anti-inflammatory, antiviral, antitumor, immunostimulating, etc.) and the availability of sources for their preparation determine the prospects of using compounds of this class to create ...
A. A. Safonov , A. V. Nevmyvaka
doaj +1 more source
Platinum nanoparticles stabilized by N-heterocyclic thiones. Synthesis and catalytic activity in mono- and di-hydroboration of alkynes [PDF]
N-Heterocyclic Thiones (NHT) proved to be efficient ligands for the stabilization of small platinum nanoparticles (1.3-1.7 nm), synthesized by decomposition of [Pt(dba)2], under a H2 atmosphere, in the presence of variable sub-stoichiometric amounts of ...
Conejero, Salvador +8 more
core +1 more source
Synthesis and Reactivity of 3H-1,2-dithiole-3-thiones
3H-1,2-Dithiole-3-thiones are among the best studied classes of polysulfur-containing heterocycles due to the almost explosive recent interest in these compounds as sources of hydrogen sulfide as an endogenously produced gaseous signaling molecule.
Oleg A. Rakitin
doaj +1 more source
Dihydropyrimidine-thiones and clioquinol synergize to target beta-amyloid cellular pathologies through a metal-dependent mechanism [PDF]
The lack of therapies for neurodegenerative diseases arises from our incomplete understanding of their underlying cellular toxicities and the limited number of predictive model systems.
Barrasa, M. Inmaculada +9 more
core +1 more source
Substituted BEDT-TTF derivatives: synthesis, chirality, properties and potential applications [PDF]
The increasing availability of functionalized BEDT-TTF derivatives in both racemic and enantiopure forms opens up great opportunities for preparing multifunctional materials and chiral conducting systems in the form of crystals, thin films and polymers ...
Griffiths, JP, Wallis, JD
core +1 more source
Micellar electrokinetic capillary chromatography—Synchronous monitoring of substrate and products in the myrosinase catalysed hydrolysis of glucosinolates [PDF]
A micellar electrokinetic capillary chromatography (MECC) method has been developed for monitoring the myrosinase catalysed hydrolysis of 2-hydroxy substituted glucosinolates and the simultaneous formation of the corresponding degradation products ...
Bellostas, Natalia +2 more
core +1 more source
Synthesis and Crystal Structure of 1-(3-fluorophenyl)-3-(3,4,5-trimethoxybenzoyl)thiourea [PDF]
The title thiourea was synthesized by reaction of 3,4,5-trimethoxybenzoyl isothiocyante with 3-fluoroaniline. The 3,4,5-trimethoxybenzoyl isothiocyante was produced in situ by reaction of 3,4,5-trimethoxybenzoyl chloride with ammonium thiocyanate in dry ...
Bolte, Michael +2 more
core +2 more sources
Synthesis, Antitumor Evaluation and Molecular Docking of New Morpholine Based Heterocycles
A series of new morpholinylchalcones was prepared and then used as building blocks for constructing a series of 7-morpholino-2-thioxo-2,3-dihydropyrido[2,3-d]pyrimidin-4(1H)-ones via their reaction with 6-aminothiouracil.
Zeinab A. Muhammad +5 more
doaj +1 more source

