Fluorinated Thiophene Units Improve Photovoltaic Device Performance of Donor-Acceptor Copolymers
Qianqian Zhang +9 more
semanticscholar +1 more source
Synthesis of Dithienylcycloalkene Molecular Switches Enabled by a Bench‐Stable Ti‐Complex
Herein we report a set of cycloalkene‐bridged DTEs with ring sizes ranging from 4‐ to 7‐membered rings. The synthesis of these analogs was performed via a key McMurry coupling step, which was enabled by a practical, bench‐stable Ti(IV)‐complex. Remarkably, it is shown that the strained cyclobutene bridge outperforms other rings, even the most commonly ...
Marcell M. Bogner +4 more
wiley +1 more source
Orofacial antinociceptive effect of a novel 2-amino-thiophene derivative and its possible targets of action. [PDF]
Silva AJD +10 more
europepmc +1 more source
Pharmaceuticals Made with Hydrogen: A Sustainable and Efficient Approach Using Flow Synthesis
We demonstrate a sustainable strategy for pharmaceutical manufacturing by combining hydrogen, heterogeneous catalysis, and continuous flow synthesis. The development of novel catalysts and their application in a multi‐step synthesis of donepezil enabled a highly productive process with no intermediate purification.
Shū Kobayashi, Haruro Ishitani
wiley +1 more source
Cycloruthenated Imines: A Step into the Nanomolar Region. [PDF]
Vasil'ev AA +6 more
europepmc +1 more source
Fluorescent Diarylethenes With Polar Groups: Synthesis, Spectra, and Optical Microscopy Applications
Blinking green and flashing red: photo‐switchable and photo‐activatable probes emitting green and red light were prepared and applied as bioconjugates in super‐resolution optical microscopy. ABSTRACT The use of photoactivatable fluorescent diarylethenes (fDAEs) in biology‐related light microscopy has been restricted by the lack of probes having freely ...
Kakishi Uno +6 more
wiley +1 more source
From structure to function: tunable electrical and catalytic properties in rare Mo(vi)-thiophene-2-carboxylic acid hydrazone complexes obtained mechanochemically. [PDF]
Pavić L +4 more
europepmc +1 more source
Pd‐Catalyzed C─C Bond Borylation of Biphenylenes Leading to Tri‐Ortho‐Substituted Biaryls
Palladium‐catalyzed ring‐opening C─C borylation of 1‐substituted biphenylenes yields a range of o,o,o′‐trisubstituted biaryls with two ortho‐boryl groups via selective cleavage of the least hindered C─C bond. The resulting diborylated products are readily amenable to sequential, site‐selective postfunctionalization.
Robyn V. Presland +5 more
wiley +1 more source

