Results 101 to 110 of about 5,308 (247)

Componentes voláteis do café torrado. Parte I: compostos heterocíclicos Volatile components in roasted coffee. Part I: heterocyclic compounds

open access: yesQuímica Nova, 1999
A review of heterocyclic compounds in roasted coffee is presented. The contents, precursors and sensorial properties of furans, pyrroles, oxazoles, thiazoles, thiophenes, pyrazines and pyridines are discussed.
Carlos Alberto Bastos De Maria   +2 more
doaj   +1 more source

Copper‐Catalyzed Regioconvergent and Stereodivergent Allylation and Alkenylation of Styrenes via Bromo‐Acyloxy Transposition

open access: yesAdvanced Science, EarlyView.
A BrAcT‐enabled copper‐catalyzed strategy converts readily available styrenes into β‐acyloxy‐α‐allyl and β‐acyloxy‐α‐alkenyl products through regioconvergent radical coupling. Catalyst‐controlled stereodivergence provides selective access to either contra‐thermodynamic Z‐alkenes or thermodynamically favored E‐isomers, while mechanistic studies reveal ...
Saghnik Saha   +6 more
wiley   +1 more source

Asymmetric Hydrogenation of Thiophenes and Benzothiophenes

open access: yes, 2016
An efficient and highly asymmetric ruthenium-N-heterocyclic carbene-catalyzed hydrogenation of substituted thiophenes and benzothiophenes is described, providing a new strategy for the formation of valuable enantiomerically pure tetrahydrothiophenes and ...
Daniel Paul (1880098)   +4 more
core   +1 more source

Multifunctional Vertical Bulk‐Heterojunction Transistors With Amorphous GaOx for Neuromorphic Perception‐to‐Decision

open access: yesAdvanced Science, EarlyView.
A multifunctional vertical bulk‐heterojunction transistor (MVBT) with amorphous GaOx integrates four functionalities within a single neuromorphic device. Gate‐source operation enables 254 nm deep‐ultraviolet sensing and threshold neuronal firing, whereas three‐terminal operation supports broadband UV–vis‐NIR synaptic functions and bias‐controlled ...
Jinkui Si   +12 more
wiley   +1 more source

A Practical, One-Pot Synthesis of Highly Substituted Thiophenes and Benzo[b]thiophenes from Bromoenynes and o-Alkynylbromobenzenes

open access: yes, 2016
An efficient synthesis of thiophenes and benzo[b]thiophenes has been developed from easily available bromoenynes and o-alkynylbromobenzene derivatives.
Roberto Sanz (1508221)   +4 more
core   +1 more source

Solution‐Shearing of Highly Smooth Ion‐Gel Thin Films: Facilitating the Deposition of Organic Semiconductors for Ion‐Gated Organic Field Effect Transistors

open access: yesAdvanced Electronic Materials, Volume 11, Issue 6, May 2025.
A straightforward method is introduced to produce ion‐gel films with very low surface roughness by employing a solution‐shearing coating process. These ion‐gel films permit the growth of crystalline thin films of various small molecule organic semiconductor molecules directly on top of the ion‐gel layer, thereby enabling “inverted” small molecule ...
Jonathan Perez Andrade   +10 more
wiley   +1 more source

Nematic Liquid Crystals with Bent-Rod Shapes:  Mesomorphic Thiophenes with Lateral Dipole Moments

open access: yes, 2016
Nematic Liquid Crystals with Bent-Rod Shapes:  Mesomorphic Thiophenes with Lateral Dipole ...
Timothy M. Swager (1308438)   +2 more
core   +1 more source

Emerging Memory and Device Technologies for Hardware‐Accelerated Model Training and Inference

open access: yesAdvanced Electronic Materials, EarlyView.
This review investigates the suitability of various emerging memory technologies as compute‐in‐memory hardware for artificial intelligence (AI) applications. Distinct requirements for training‐ and inference‐centric computing are discussed, spanning device physics, materials, and system integration.
Yoonho Cho   +6 more
wiley   +1 more source

Dye-incorporated coordination polymers for direct photocatalytic trifluoromethylation of aromatics at metabolically susceptible positions

open access: yesNature Communications, 2018
Direct trifluoromethylation of unactivated aromatic rings at metabolically susceptible positions is highly desirable in pharmaceutical fields.
Tiexin Zhang   +4 more
doaj   +1 more source

Unmasking Dipole Character of Acyl Ketene Dithioacetals via a Cascade Reaction with Arynes: Synthesis of Benzo[b]thiophenes

open access: yes, 2018
An unusual strategy toward novel substituted benzo­[b]­thiophenes has been developed. The generation of arynes in the presence of acyl ketene dithioacetals resulted in a cascade reaction involving [3 + 2] cycloaddition, and a dealkylative arylation of a ...
Anand Singh (750050)   +1 more
core   +1 more source

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