Iridium-Catalyzed Silylation of Five-Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl-Imidazoline Ligand. [PDF]
The steric effects of substituents on five-membered rings are less pronounced than those on six-membered rings because of the difference in bond angles. Thus, the regioselectivities of reactions of five-membered heteroarenes that occur with selectivities
Hartwig, John F +3 more
core +1 more source
Electronic Correlations in Oligo-acene and -thiophene Organic Molecular Crystals [PDF]
From first principles calculations we determine the Coulomb interaction between two holes on oligo-acene and -thiophene molecules in a crystal, as a function of the oligomer length.
Alberto F. Morpurgo +6 more
core +5 more sources
Synthesis of Some Thienopyrimidine Derivatives
Thioxothienopyrimidinones, alkylthio- and arylalkylthiothienopyrimidinones, thienopyrimidinones, thienopyrimidines a thienopyrimidinedione and a thienotriazolo- pyrimidinone were prepared from 2-amino-3-carboethoxy-4,5-disubstituted thiophenes and 2 ...
Hassan M. Al-Hazimi +2 more
doaj +1 more source
This is the first study investigating the nuclear factor (erythroid‐derived 2)‐like 2 (NRF2) activity of compounds containing a new scaffold, tetrahydrobenzo[b]thiophene.
Kit‐Kay Mak +8 more
doaj +1 more source
Light absorption spectra in oligothiophene molecules [PDF]
Para el dictado de clases, se pueden utilizar diferentes herramientas que nos brindan las nuevas tecnologías; herramientas que nos están modificando los procesos de enseñanza-aprendizaje.
Gala, Fabrizio, Zollo, Giuseppe
core +4 more sources
The preparation of ketene dithioacetals and thiophenes from chloropyridines containing an active methylene group [PDF]
The base catalysed reaction of carbon disulphide with the active methylene groups of chloropyridines 4 and 7, followed by alkylation with reagents which also contain active methylene groups, lead to ketene dithioacetals.
Bremner, David H. +2 more
core +3 more sources
Carbon−Phosphorus Bond Activation of Tri(2-thienyl)phosphine at Dirhenium and Dimanganese Centers [PDF]
Reaction of [Re2(CO)9(NCMe)] with tri(2-thienyl)phosphine (PTh3) in refluxing cyclohexane affords three substituted dirhenium complexes: [Re2(CO)9(PTh3)] (1), [Re2(CO)8(NCMe)(PTh3)] (2), and [Re2(CO)8(PTh3)2] (3).
Begum, Noorjahan +12 more
core +2 more sources
D-π-D chromophores based on dithieno[3,2-b:2′,3'-d]thiophene (DTT) : potential application in the fabrication of solar cell [PDF]
In this work, four stable dithieno[3,2-b:2′,3'-d]thiophene-based π-extended molecules were designed and synthesized via a Pd-catalysed Sonogashira coupling reaction.
Akther, Tahmina +11 more
core +2 more sources
Palladium-catalyzed 2,5-diheteroarylation of 2,5-dibromothiophene derivatives
Conditions allowing the one pot 2,5-diheteroarylation of 2,5-dibromothiophene derivatives in the presence of palladium catalysts are reported.
Fatma Belkessam +4 more
doaj +1 more source
The Panel on Food Additives and Flavourings (FAF) was requested to consider the JECFA evaluations of 28 flavouring substances in the Flavouring Group Evaluation 76 (FGE.76Rev2). Twenty‐one of these substances have been considered in FGE.76Rev1.
EFSA Panel on Food Additives and Flavourings (FAF) +26 more
doaj +1 more source

