Results 111 to 120 of about 5,865 (290)

Nickel Catalysis Enables Access to Thiazolidines from Thioureas via Oxidative Double Isocyanide Insertion Reactions

open access: yes, 2018
An efficient synthesis of thiazolidine-2,4,5-triimine derivatives was developed via Ni-catalyzed oxidative double isocyanide insertion to thioureas under air conditions, in which thioureas play three roles as a substrate, a ligand, and overcoming ...
Yan Fang Liu (1613593)   +9 more
core   +1 more source

Solid and Solution Phase Organic Syntheses of Oligomeric Thioureas

open access: yes, 2016
In order to study supramolecular architectures built from unnatural oligomeric and polymeric structures, one must first have an efficient synthetic strategy to produce them.
Stephen E. Schneider (2988813)   +3 more
core   +1 more source

Carbon Quantum Dots Meet Perovskite Solar Cells: A Review of Multifunctional Synergies

open access: yesCarbon Energy, EarlyView.
This review highlights the multifunctional role of carbon dots in perovskite solar cells. Their applications as additives and interfacial modifiers are discussed in terms of crystallization control, defect passivation, energy‐level alignment, and environmental stability.
Yagmur Su Sayin   +3 more
wiley   +1 more source

Efficient and Durable Sulfion Oxidation Coupled With Hydrogen Production via Cu@Cu2S Heterostructured Nanowires

open access: yesCarbon Energy, EarlyView.
We present a facile and liquid‐phase approach to synthesize Cu@Cu2S core‐shell heterostructure nanowires derived from copper nanowires at room temperature for robust sulfide oxidation reaction (SOR)‐assisted H2 generation. The Cu@Cu2S core‐shell heterostructure nanowires exhibit superior SOR activity with an ultralow potential of 0.3 V (vs.
Hongling Zhang   +14 more
wiley   +1 more source

Engineering Halide Perovskites With Chalcogen‐Based Compounds: Insights Into Stability, Interfaces, and Device Integration

open access: yesCarbon Energy, EarlyView.
Chalcogen‐based compounds are explored as versatile tools to enhance the stability and performance of halide perovskites. Their roles in defect passivation, ion migration suppression, and interface engineering are analyzed, along with impacts on device efficiency.
Atanu Jana   +4 more
wiley   +1 more source

CONDENSATION PRODUCTS OF BENZYLIDENE-ACETONE WITH SUBSTITUTED THIOUREAS

open access: yes, 1956
Several 2- arylamino -4-styryl-thiazoIes, prepared by condensation of benzylidene-acetone with substi­tuted thioureas, and their mercurated products have been described.
M. K. ROUT
core   +1 more source

An Electrophilic Uridine Building Block for Post‐Synthetic RNA Modification as Exemplified for Spin Labeling

open access: yesChemistry – A European Journal, EarlyView.
An electrophilic 5‐isothiocyanatomethyl uridine building block enables modular post‐synthetic RNA labeling with primary amine‐containing probes. Positioning the functionality in the major groove minimizes structural perturbation and allows facile conjugation of sensitive tags such as TEMPO spin labels for paramagnetic relaxation enhancement studies ...
Lisa Ruetz   +4 more
wiley   +1 more source

Insertion of arynes into thioureas: A new amidine synthesis

open access: yes, 2011
Arynes, generated from trimethylsilyl phenyltriflate precursors, have been found to react with thioureas via a formal π-insertion into the C=S bond. The reaction contrasts with that of ureas, which proceeds via benzyne σ-insertion into the C-N bond, and ...
Greaney, Michael F.   +3 more
core   +1 more source

Stereochemical Control in the Matteson Reaction

open access: yesChemistry – A European Journal, EarlyView.
The Matteson homologation is a highly versatile method for the stereoselective insertion of carbenoids into boronic esters. Through iterative application of the process, complex chiral molecules can be synthesized. The stereoselectivity of the reaction is determined by a chiral diol incorporated in the boronic ester.
Hae Mo Lee, Christoph Hirschhäuser
wiley   +1 more source

Hybrid Macrocyclic Peptides — Synthetic Strategies to Diversify and Cyclize Peptide Libraries in Phage Display Selections

open access: yesChemistry – A European Journal, EarlyView.
Hybrid macrocyclic peptides unite genetically encoded peptide libraries with the structural complexity of synthetic small molecules. This Review critically analyzes phage‐compatible cyclization and diversification chemistries, highlights emerging opportunities beyond traditional cysteine‐based approaches, and outlines how future advances may enable the
Titia Rixt Oppewal, Clemens Mayer
wiley   +1 more source

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