Results 211 to 220 of about 76,098 (279)

Energy Landscapes in Chemical Reactions and Transport

open access: yesChemPhysChem, Volume 26, Issue 6, March 15, 2025.
Kinetics/dynamics of chemical reactivity and transport of chemical species in a solid are both determined by the energy landscape in which they take place. Discussing common grounds but also distinct differences may help in advancing the understanding in both fields.
Karl‐Michael Weitzel
wiley   +1 more source

Mixed‐Impurity Co‐Poisoning of NH3‐SCR Catalysts: Poisoning Mechanisms, Antagonistic Effects, and Anti‐Inactivation Strategies

open access: yesEcoEnergy, EarlyView.
This review summarizes the synergistic effects of mixed impurities on ammonia‐selective catalytic reduction (NH3‐SCR) catalysts, including the poisoning mechanism of the catalyst caused by mixed impurities, the antagonistic effects between the impurities, and the research on the anti‐poisoning strategies for the catalyst in recent years.
Hongyan Xue   +3 more
wiley   +1 more source

Anion‐Regulated Ionic Liquid–Polymer Electrolytes for High‐Performance and Safe Lithium Metal Batteries

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A PVDF‐HFP/poly(ionic liquid) dual‐matrix solid electrolyte plasticized with Pyr13TFSI exhibits enhanced ionic conductivity, thermal stability, and interfacial compatibility. The optimized morphology and Li+ solvation structure facilitate fast ion transport and robust cycling, highlighting its promise for safe, high‐performance lithium metal batteries.
Kangsheng Huang   +9 more
wiley   +1 more source

Perovskite Li3/8Sr7/16Ta3/4Zr1/4O3 Surface Coating Enables Stable Cycling of Li‐Rich Mn‐Based Cathodes at High Voltage

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The LSTZ coating significantly enhances the electrochemical performance of Li‐rich Mn‐based cathodes, achieving high ICE (79.5%) and outstanding long‐term cycling stability (178.5 mAh g−1 with 94.4% retention after 120 cycles at 25 °C; 209.7 mAh g−1 with 95.7% retention after 300 cycles at 45 °C).
Yuyao Ma   +4 more
wiley   +1 more source

Multifunctional Phosphorus Doping: Integrating Enhanced Ionic/Electronic Transport and Interface Optimization for Silicon Oxycarbide Anodes

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Phosphorus doping introduced additional electrons into silicon oxycarbide (SiOC) materials, facilitating fast ion/electron transport. It also induced the formation of more stable and Li‐ion conductive interfaces, contributing to the improvement of electrochemical performance.
Yingying Shen   +9 more
wiley   +1 more source

Ag‐Induced Phase and Defect Engineering of Co‐Evaporated Sb2Se3 Thin Films for Enhanced Photovoltaic Performance

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The sequential formation of Ag2Se and AgSbSe2 phases at the Sb2Se3/Mo interface upon Ag incorporation in co‐evaporated Sb2Se3 solar cells promotes grain growth and defect passivation. These newly formed intermediate phases enhance crystallinity and suppress recombination, leading to significant improvements in open‐circuit voltage, fill factor, and ...
Van‐Quy Hoang   +16 more
wiley   +1 more source

Organotrifluoroborate‐Driven Phase Stabilization and Defect Suppression for Wide‐Bandgap Perovskites

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A multifunctional additive, trifluoro(pyrrolidin‐1‐ium‐1‐ylmethyl) borate (PyMe‐BF3), leverages B‐F coordination and N‐H hydrogen bonding to passivate undercoordinated Pb2+, fill halide vacancies, and suppress phase segregation. Its preferential enrichment at the buried interface targets the defect‐rich region, enabling simultaneous wide‐bandgap ...
Suzhen Liu   +11 more
wiley   +1 more source

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