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Nanosecond time-resolved IR study of thiobenzoylnitrene
Physical Chemistry Chemical Physics, 2012Nanosecond time-resolved infrared (TRIR) spectroscopy has been used to observe singlet thiobenzoylnitrene at 1740 cm(-1) upon photolysis of 5-phenyl-1,2,3,4-thiatriazole in acetonitrile and dichloromethane. Consistent with the experimental observations, thiobenzoylnitrene is predicted by B3LYP/6-31G* calculations to have a singlet ground state with an ...
Yonglin, Liu +2 more
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Time-resolved studies of individual molecular rotors
Journal of Physics: Condensed Matter, 2010Thioether molecular rotors show great promise as nanoscale models for exploring the fundamental limits of thermally and electrically driven molecular rotation. By using time-resolved measurements which increase the time resolution of the scanning tunneling microscope we were able to record the dynamics of individual thioether molecular rotors as a ...
April D, Jewell +5 more
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Stimulated Emission in ZnO Nanostructures: A Time-Resolved Study
The Journal of Physical Chemistry B, 2005Stimulated emission was studied using time-integrated and time-resolved photoluminescence in ZnO comb, tetrapod, and rod nanostructures. All the measurements were performed on ensembles of the nanostructures. The nanostructures were fabricated by vapor deposition (combs, tetrapods) and hydrothermal methods (rods). While stimulated emission was detected
Phillips, DL +4 more
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Stain Effects Studied by Time-Resolved Infrared Imaging
Analytical Chemistry, 2008Pattern formation in evaporating colloidal droplets is an important phenomenon that is commonly observed in several solute-solvent systems; this is also an emerging technique for obtaining fine patterning through controlled conditions of drying. After evaporation of the solvent a ring-like pattern remains on the solid substrate under the condition of ...
Innocenzi, P. +4 more
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Time-resolved studies of biexcitons in GaAs
Solid State Communications, 1989Abstract Using time-window photoluminescence spectroscopy we have unambigously observed a transition corresponding to biexcitons in GaAs. The biexciton luminescence line was found to have a superlinear dependence of luminescence intensity vs. excitation density as well as a shorter lifetime than the polariton.
T.W. Steiner +5 more
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Time Resolved Studies Of Adsorbed Species
SPIE Proceedings, 1985A time-resolved Fourier transform IR study of ethyne adsorbed on ZnNaA zeolite yields results very different from those reported for related systems. Initially two species (A and B) are formed by the interaction of C2H2 with the cations. Whereas species A (π-bonded C2H2) was found to be removed immediately on evacuation, species B (probably Zn ...
J. Howard, J. M. Nicol
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Time-resolved photoluminescence study of InSe
Solid State Communications, 1985Time-resolved photoluminescence spectra of InSe at superfluid He temperatures show that one broad luminescence feature centred at 1315meV is due to donor-acceptor pair recombination whereas other, lower energy broad bands are not. The sharp lines around 1333meV were identified as bound exciton luminescence from their transient behaviour.
J.L. Brebner, T. Steiner, M.L.W. Thewalt
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Time-resolved studies of excitonic polaritons
Journal of Luminescence, 1991Abstract The kinetic properties of the secondary emission of excitonic polaritons are reviewed, based on experiments on molecular (anthracene) and semiconductor (CdS, GaAs, InP, etc.) crystals at low temperatures. First, coherent propagation effects are considered, including group velocity renormalization, the appearance of optical precursors and ...
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Time-resolved fluorescence studies on flavins.
1989Flavins are ubiquitous in nature. They mediate in electron transfer and oxidation reactions in both bacterial, mammalian and plant systems (for a review see Muller, 1983). The natural cofactors are flavin adenine dinucleotide (FAD) and flavin mononucleotide (FMN), which occur in protein-bound form (Figure 1).
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