Results 101 to 110 of about 806 (239)

MetalCenter‐Dependent Selectivity Divergence in MN4 Single‐Atom Catalysts for Aerobic HMF Oxidation

open access: yesAdvanced Science, EarlyView.
Two single‐atom catalysts with M‐N4 configurations (FeN4 and CoN4) were developed for selective HMF oxidation. FeN4 achieves 93.9% selectivity toward FFCA via superoxide anions (O2•−), while CoN4 preferentially produces FDCA through hydroxyl radicals (•OH). DFT calculations reveal that distinct adsorption energies and charge redistribution at the metal
Haoyu Wang   +6 more
wiley   +1 more source

Spontaneous Non‐Catalyzed Molecular Reactions and Interactions in the Human Body: Biomedical Implications

open access: yesAdvanced Science, EarlyView.
ABSTRACT The human body functions as a natural reactor for a vast network of chemical and biological reactions and physical interactions among small molecules, proteins, cells, and numerous other components. These reactions/interactions are essential for maintaining normal physiological functions.
Yuhao Cai, Chao Zhao
wiley   +1 more source

Toward Flexible Printed Electronics: A Spider‐Silk‐Inspired, Strong and Tough Thermoplastic Polyamide Elastomer

open access: yesAdvanced Science, EarlyView.
Inspired by spider silk, a bio‐inspired polyamide elastomer with a dynamic physical cross‐linking network is developed. Mimicking the rigid β‐sheet crystals and sacrificial hydrogen bonds of silk, the material achieves an exceptional balance of strength and toughness.
Bo Yang   +12 more
wiley   +1 more source

Epitaxial Stabilization of Ultrasmall Cu Nanoparticles With High‐Energy {110} Facets on Ti3C2 MXene for Efficient CO2‐to‐Acetate Electrocatalysis

open access: yesAdvanced Science, EarlyView.
Cu/Ti3C2 heterostructure: Cu/Ti3C2 heterostructure achieves epitaxial stabilization of high‐energy Cu(110) facets through lattice matching and electronic interaction, enabling efficient CO2 electroreduction to acetate with 42.5% Faradaic efficiency at 235 mA·cm−2. ABSTRACT The electrochemical CO2 reduction reaction (CO2RR) to multicarbon (C2+) products
Yan‐An Li   +10 more
wiley   +1 more source

Energy Efficient Transformers and Reactors : Some incentive models and case studies to show the long term profitability of such designs

open access: yes, 2012
During the coming decades energy efficiency will be a critical factor in reducing carbon emissions and fighting global warming. The power generation industry and transmission and distribution industries (T&D) contribute to a large part of energy ...
Mortensen, E.,   +8 more
core  

Substrate‐Affinitive P‐Type Azapolycyclic Photosensitizer for Chemoselective Nitrilization Under Mild Conditions

open access: yesAdvanced Science, EarlyView.
We developed a series of quinoxalinoquinoxaline (QQ) photosensitizers featuring high and tunable excited‐state reduction potentials (E(PC•+/PC*) = –1.76 to –2.05 V vs. SCE). Their hydrogen‐bonding interaction with carbonyl substrates enables selective single‐electron transfer events for selective nitrilization of 1° amides, offering a tunable ...
Seongwoo Bae, Dongwook Kim, Jinwoo Kim
wiley   +1 more source

Furfural analysis for assessing overheating in 500kV shunt reactors

open access: yes, 2003
The furfural concentration in 500kV shunt reactor oil has been investigated to assess the overheating problems that are regarded as one of the most common defects.
Wang, N, Ling, M, Fu, M, Chen, G, Xue, C
core  

Efficient Electrocatalytic Conversion of CO2 to Pure Formic Acid Solutions via Strain‐Engineered Bismuth Nanosheets

open access: yesAdvanced Science, EarlyView.
Tensile‐strained bismuth nanosheets (TS‐BiNs) achieve a formate Faradaic efficiency of 92% at −1000 mA cm−2 and enable stable production of pure formic acid (HCOOH) in a solid‐state electrolyte reactor. Theoretical calculations reveal that the introduced strain lowers the energy barrier for *OCHO intermediate formation, fundamentally enhancing the ...
Shiqi Li   +16 more
wiley   +1 more source

Reinforcing Oxygen Activation of Spinel Oxide via Mn─O Covalency Engineering for VOCs Oxidation

open access: yesAdvanced Science, EarlyView.
A MnCo spinel catalyst with weakened Mn─O covalency was synthesized via a hard‐template method. The reduced Mn─O covalency facilitates localized electron redistribution, promoting the activation of both molecular oxygen and lattice oxygen, and thereby enabling the efficient and complete oxidation of VOCs (ethyl acetate, toluene, and propane).
Gan Li   +8 more
wiley   +1 more source

Selected problems of setting protection devices for high voltage shunt reactors

open access: yes, 2015
W referacie przedstawiono trudności jakie napotyka się podczas projektowania systemu zabezpieczeń dla dławików przyłączanych bezpośrednio do sieci najwyższych napięć (NN).
Lubośny, Z.   +2 more
core  

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