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Upper critical solution temperature lubricants for CPVC
Journal of Vinyl Technology, 1993Abstract Chlorinated polyvinyl chloride (CPVC) is often used in injection molding for products that demand high heat resistance. However, proper control of its flow properties is difficult. To improve flow behavior some internal lubricants are usually used, but they reduce heat resistance of the products.
H. Nakamura, T. Fukuoka, T. Uesaka
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Lower and upper critical solution temperatures of binary polymeric solutions
Fluid Phase Equilibria, 2016Abstract The phase behavior of binary polymeric solutions such as lower and upper critical solution temperatures has an important role in many polymeric processes. For theoretical investigation on the prediction of these temperatures, a substantial number of data points on binary polymeric solutions were collected from literature and used to present ...
Ayoub Ejraei +4 more
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Synthesis and Properties of Upper Critical Solution Temperature Responsive Nanogels
Langmuir, 2019A random copolymer ((U/A10)165) bearing pendent ureido groups and a small amount (10 mol %) of primary amino groups exhibits an upper critical solution temperature (UCST). We prepared a diblock copolymer (PMPC20P(U/A10)165) composed of water-soluble poly(2-methacryloyloxyethyl phosphorylcholine) (PMPC) and (U/A10)165 blocks via reversible addition ...
Maho Ohshio +4 more
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Antitumor Drug Delivery Modulated by A Polymeric Micelle with an Upper Critical Solution Temperature
Angewandte Chemie - International Edition, 2015AbstractThermally sensitive polymeric nanocarriers were developed to optimize the release profile of encapsulated compounds to improve treatment efficiency. However, when referring to thermally sensitive polymeric nanocarriers, this usually means systems fabricated from lower critical solution temperature (LCST) polymers, which have been intensively ...
Fuqiang Hu, Yong-Zhong Du
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Upper critical solution temperatures in blends of chlorinated polyethylenes
Macromolecules, 1985La temperature critique est plus faible lorsque la difference des teneurs en chlore dans le melange diminue, ce qui indique une meilleure ...
Hiroyoshi Ueda, Frank E. Karasz
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Macromolecular Rapid Communications, 2021
AbstractThe synthesis of thermo‐responsive polymers from non‐responsive and water‐soluble monomers has great practical advantages but significant challenges. Herein, the authors report a novel aqueous copolymerization strategy to prepare polymers with tunable upper critical solution temperature (UCST) or lower critical solution temperature (LCST) from ...
Jianlei Lu +4 more
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AbstractThe synthesis of thermo‐responsive polymers from non‐responsive and water‐soluble monomers has great practical advantages but significant challenges. Herein, the authors report a novel aqueous copolymerization strategy to prepare polymers with tunable upper critical solution temperature (UCST) or lower critical solution temperature (LCST) from ...
Jianlei Lu +4 more
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Upper critical solution temperatures of hydrocarbon + fluorocarbon mixtures
Australian Journal of Chemistry, 1978Values of the interaction parameter ? have been calculated from upper critical solution temperature data by use of the van der Waals one- fluid model for a range of hydrocarbon+fluorocarbon mixtures. The values obtained are compared with values calculated from gas-liquid critical temperatures and mixed second virial coefficients where experimental data
CP Hicks +3 more
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Upper and lower critical solution temperatures in 1‐octanol solutions of polyethylene
British Polymer Journal, 1983AbstractCloud points of 1‐octanol solutions of four linear polyethylene samples having different molecular weights were measured visually in both regions of the upper and lower critical solution temperatures (UCST and LCST). From the (temperature, polymer weight fraction) phase diagrams drawn, the UCST and LCST were determined.
Yoichiro Muraoka +2 more
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Upper and lower critical solution temperatures in poly (ethylene glycol) solutions
Polymer, 1976Upper and lower critical solution temperatures have been determined for solutions of poly(ethylene glycol) in t-butyl acetate and water over the molecular weight range of Mη = 2.18 × 103 to ∼1020 × 103. The phase diagram for solutions of poly(ethylene glycol) (Mη = 719 × 103) in t-butyl acetate was expressed as the ‘hour glass’ type, while the phase ...
Susumu Saeki +3 more
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Journal of Polymer Science Part B: Polymer Physics, 1987
AbstractDilute solutions of polystyrene in cyclopentane are studied with four narrow‐distribution polymer fractions ranging in molecular weight from 1.6 × 105 to 1.8 × 106. Light scattering (total intensity) and viscosity measurements cover a temperature range spanning both “theta” temperatures: the limiting upper critical solution temperature (19.6°C)
Guy C. Berry +2 more
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AbstractDilute solutions of polystyrene in cyclopentane are studied with four narrow‐distribution polymer fractions ranging in molecular weight from 1.6 × 105 to 1.8 × 106. Light scattering (total intensity) and viscosity measurements cover a temperature range spanning both “theta” temperatures: the limiting upper critical solution temperature (19.6°C)
Guy C. Berry +2 more
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