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Matrix-isolation vibrational circular dichroism (VCD) spectroscopy of chiral 1-phenyl-1-propanol
Physical Chemistry Chemical Physics, 2023As the effect of self-aggregation of the title compound was not particularly strong in solution phase VCD spectra, we use matrix-isolation VCD spectroscopy to reveal the very subtle spectral features of dimers and higher aggregates.
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Absolute configurations of endoperoxides determined by vibrational circular dichroism (VCD)
Tetrahedron Letters, 2006Abstract Diastereomeric mixture on the peroxide portion of an endoperoxide acetylmajapolene A (1) was efficiently separated by HPLC on a chiral column, submitting to vibrational circular dichroism (VCD) investigation. The ab initio theoretical VCD and IR calculations of 1a and 1b were performed by density functional theory (DFT) using the B3PW91/6 ...
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